Inexpensive metal-free organic redox flow battery (ORBAT) for grid-scale storage
Abstract
A flow battery includes a positive electrode, a positive electrode electrolyte, a negative electrode, a negative electrode electrolyte, and a polymer electrolyte membrane interposed between the positive electrode and the negative electrode. The positive electrode electrolyte includes water and a first redox couple. The first redox couple includes a first organic compound which includes a first moiety in conjugation with a second moiety. The first organic compound is reduced during discharge while during charging the reduction product of the first organic compound is oxidized to the first organic compound. The negative electrode electrolyte includes water and a second redox couple. The second couple includes a second organic compound including a first moiety in conjugation with a second moiety. The reduction product of the second organic compound is oxidized to the second organic compound during discharge.
- Inventors:
- Issue Date:
- Research Org.:
- Univ. of Southern California, Los Angeles, CA (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- OSTI Identifier:
- 1986953
- Patent Number(s):
- 11532830
- Application Number:
- 16/785,715
- Assignee:
- University of Southern California (Los Angeles, CA)
- DOE Contract Number:
- AR0000353
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 02/10/2020
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Narayan, Sri, Prakash, Surya G. K., Yang, Bo, Hoober-Burkhardt, Lena, and Krishnamoorthy, Sankarganesh. Inexpensive metal-free organic redox flow battery (ORBAT) for grid-scale storage. United States: N. p., 2022.
Web.
Narayan, Sri, Prakash, Surya G. K., Yang, Bo, Hoober-Burkhardt, Lena, & Krishnamoorthy, Sankarganesh. Inexpensive metal-free organic redox flow battery (ORBAT) for grid-scale storage. United States.
Narayan, Sri, Prakash, Surya G. K., Yang, Bo, Hoober-Burkhardt, Lena, and Krishnamoorthy, Sankarganesh. Tue .
"Inexpensive metal-free organic redox flow battery (ORBAT) for grid-scale storage". United States. https://www.osti.gov/servlets/purl/1986953.
@article{osti_1986953,
title = {Inexpensive metal-free organic redox flow battery (ORBAT) for grid-scale storage},
author = {Narayan, Sri and Prakash, Surya G. K. and Yang, Bo and Hoober-Burkhardt, Lena and Krishnamoorthy, Sankarganesh},
abstractNote = {A flow battery includes a positive electrode, a positive electrode electrolyte, a negative electrode, a negative electrode electrolyte, and a polymer electrolyte membrane interposed between the positive electrode and the negative electrode. The positive electrode electrolyte includes water and a first redox couple. The first redox couple includes a first organic compound which includes a first moiety in conjugation with a second moiety. The first organic compound is reduced during discharge while during charging the reduction product of the first organic compound is oxidized to the first organic compound. The negative electrode electrolyte includes water and a second redox couple. The second couple includes a second organic compound including a first moiety in conjugation with a second moiety. The reduction product of the second organic compound is oxidized to the second organic compound during discharge.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Dec 20 00:00:00 EST 2022},
month = {Tue Dec 20 00:00:00 EST 2022}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
A study of tiron in aqueous solutions for redox flow battery application
journal, January 2010
- Xu, Yan; Wen, Yue-Hua; Cheng, Jie
- Electrochimica Acta, Vol. 55, Issue 3, p. 715-720
Investigation into the use of quinone compounds-for battery cathodes
journal, May 1972
- Alt, H.; Binder, H.; Köhling, A.
- Electrochimica Acta, Vol. 17, Issue 5
Adaptations of alpha2- and beta-cells of rat and mouse pancreatic islets to starvation, to refeeding after starvation, and to obesity.
journal, January 1980
- Matschinsky, F. M.; Rujanavech, C.; Pagliara, A.
- Journal of Clinical Investigation, Vol. 65, Issue 1
Methods for use of a photobiofuel cell in production of hydrogen and other materials
patent-application, August 2007
- Gust, JR., John Devens; Moore, Ana L.; Moore, Thomas A.
- US Patent Application 10/558598; 20070184309
Self-Assembled Surfactant Structures
patent-application, November 2011
- Brozell, Adrian
- US Patent Application 13/113930; 20110284456
Reduction Potentials Of Quinones. II. The Potentials Of Certain Derivatives Of Benzoquinone, Naphthoquinone And Anthraquinone
journal, August 1924
- Conant, James B.; Fieser, Louis F.
- Journal of the American Chemical Society, Vol. 46, Issue 8, p. 1858-1881
Cyclic voltammetric study of quinone—hydroquinone organic system in aqueous magnesium perchlorate electrolyte
journal, June 1993
- Bhatt, D. P.; Anbuchezian, M.; Balasubramanian, R.
- Journal of Power Sources, Vol. 45, Issue 2
Battery electrode, secondary battery, and method of manufacturing same
patent, February 2004
- Fujiwara, Masaki; Harada, Gaku; Okada, Shinako
- US Patent Document 6,686,089
Intermittent fasting up-regulates Fsp27/Cidec gene expression in white adipose tissue
journal, March 2012
- Karbowska, Joanna; Kochan, Zdzislaw
- Nutrition, Vol. 28, Issue 3
Method of Generating Electricity Using a Polyhydric Phenol-Oxygen Fuel Cell
patent, March 1966
- Klass, Donald L.; Hutchings, Le Roi E.
- US Patent Document 3,238,066
Electrochemical Reaction Mechanism of Tiron in Acidic Aqueous Solution
journal, November 2011
- Xu, Yan; Wen, Yue Hua; Cheng, Jie
- Advanced Materials Research, Vol. 396-398
Differential effects of high-fat diets varying in fatty acid composition on the efficiency of lean and fat tissue deposition during weight recovery after low food intake
journal, February 1995
- Dulloo, Abdul G.; Mensi, Noury; Seydoux, Josiane
- Metabolism, Vol. 44, Issue 2
Method and Apparatus of Generating Electric Power
patent-application, June 2007
- Shimomura, Tatsuo; Komatsu, Makoto; Adachi, Masanori
- US Patent Application 11/556883; 20070134520
Benzoquinone-Hydroquinone Couple for Flow Battery
journal, January 2013
- Nawar, Saraf; Huskinson, Brian; Aziz, Michael
- MRS Proceedings, Vol. 1491
Fuel cell using quinones to oxidize hydroxylic compounds
patent, March 1986
- Hertl, William; Schaeffler, Robert
- US Patent Document 4,578,323
Small Organic Molecule Based Flow Battery
patent-application, February 2016
- Huskinson, Brian; Marshak, Michael; Aziz, Michael J.
- US Patent Application 14/823546; 20160043423
Materials For Use With Aqueous Redox Flow Batteries and Related Methods and Systems
patent-application, August 2015
- Brushett, Fikile Richard; Jansen, Andrew Norbert; Vaughey, John Thomas
- US Patent Document 14/625417; 20150236543
Novel organic redox flow batteries using soluble quinonoid compounds as positive materials
conference, September 2009
- Xu, Yan; Wen, Yuehua; Cheng, Jie
- 2009 World Non-Grid-Connected Wind Power and Energy Conference
Streptozotocin is equally diabetogenic whether administered to fed or fasted mice
journal, June 2013
- Chaudhry, Zunaira Z.; Morris, David L.; Moss, Dan R.
- Laboratory Animals, Vol. 47, Issue 4
Organic Non-Aqueous Cation-Based Redox Flow Batteries
patent-application, August 2013
- Jansen, Andrew N.; Vaughey, John T.; Chen, Zonghai
- US Patent Application 13/407409; 20130224538
High Solubility Iron Hexacyanides
patent-application, February 2014
- Esswein, Arthur J.; Goeltz, John; Amadeo, Desiree
- US Patent Application 13/887461; 20140051003
Secondary Battery, Power Supply System Using Same and Usage of Power Supply System
patent-application, January 2009
- Inatomi, Yuu; Hojo, Nobuhiko; Kuranuki, Masaaki
- US Patent Application 11/915456; 20090017379
Anthraquinone with tailored structure for a nonaqueous metal–organic redox flow battery
journal, January 2012
- Wang, Wei; Xu, Wu; Cosimbescu, Lelia
- Chemical Communications, Vol. 48, Issue 53, p. 6669-6671
Small Organic Molecule Based Flow Battery
patent-application, August 2015
- Huskinson, Brian; Marshak, Michael; Aziz, Michael J.
- US Patent Application 14/431175; 20150243991
Aqueous Redox Flow Batteries Comprising Metal Ligand Coordination Compounds
patent-application, January 2014
- Esswein, Arthur J.; Goeltz, John; King, Evan R.
- US Patent Application 13/795878; 20140030572
Weight Management, Longevity and Health Paradigm
patent-application, February 2005
- Johnson, James
- US Patent Application 10/844535; 20050031671
Phenanthrenequinone compound, electrode active material, and power storage device
patent, December 2012
- Ohtsuka, Yu; Yoshida, Junichi; Nokami, Toshiki
- US Patent Document 8,338,027
Reversal of type 2 diabetes: normalisation of beta cell function in association with decreased pancreas and liver triacylglycerol
journal, June 2011
- Lim, E. L.; Hollingsworth, K. G.; Aribisala, B. S.
- Diabetologia, Vol. 54, Issue 10
Electrochemical Pump
patent-application, December 2009
- Evans, Christine E.; Payne, Forrest W.; Koval, Carl A.
- US Patent Application 12/546,826; 2009/0308752 Al
Effect of intermittent fasting and refeeding on insulin action in healthy men
journal, December 2005
- Halberg, Nils; Henriksen, Morten; Söderhamn, Nathalie
- Journal of Applied Physiology, Vol. 99, Issue 6