Alloy based electrochemical catalyst for conversion of carbon dioxide to hydrocarbons

Rondinone, Adam J.; Hensley, Dale K.; Jin, Seonah

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Title: Alloy based electrochemical catalyst for conversion of carbon dioxide to hydrocarbons

Abstract

An electrocatalyst comprising (i) carbon nanospikes and (ii) copper alloy nanoparticles containing copper and at least one noble metal and residing on and/or between the carbon nanospikes. Also disclosed herein is a method of producing the electrocatalyst. Also described herein is a method for converting carbon dioxide into hydrocarbons by use of the above-described electrocatalyst. The method for producing hydrocarbons more specifically involves contacting the electrocatalyst with an aqueous solution of a bicarbonate salt while the aqueous solution is in contact with a source of carbon dioxide, and electrically powering the electrocatalyst as a cathode at negative potential condition while the cathode is in electrical communication with a counter electrode electrically powered as an anode, to convert the carbon dioxide into hydrocarbons containing at least four carbon atoms and composed of only carbon and hydrogen.

Inventors:: Rondinone, Adam J.; Hensley, Dale K.; Jin, Seonah

Issue Date:: 2022-12-06

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1986905

Patent Number(s):: 11519087

Application Number:: 17/488,884

Assignee:: UT-Battelle LLC (Oak Ridge, TN)

DOE Contract Number:: AC05-00OR22725

Resource Type:: Patent

Resource Relation:: Patent File Date: 09/29/2021

Country of Publication:: United States

Language:: English

Citation Formats


                    Rondinone, Adam J., Hensley, Dale K., and Jin, Seonah. Alloy based electrochemical catalyst for conversion of carbon dioxide to hydrocarbons.  United States: N. p., 2022. 
        Web.

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                    Rondinone, Adam J., Hensley, Dale K., & Jin, Seonah. Alloy based electrochemical catalyst for conversion of carbon dioxide to hydrocarbons.  United States.

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                    Rondinone, Adam J., Hensley, Dale K., and Jin, Seonah. Tue .  
        "Alloy based electrochemical catalyst for conversion of carbon dioxide to hydrocarbons".  United States.  https://www.osti.gov/servlets/purl/1986905.

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@article{osti_1986905,

  title        = {Alloy based electrochemical catalyst for conversion of carbon dioxide to hydrocarbons},

  author       = {Rondinone, Adam J. and Hensley, Dale K. and Jin, Seonah},

  abstractNote = {An electrocatalyst comprising (i) carbon nanospikes and (ii) copper alloy nanoparticles containing copper and at least one noble metal and residing on and/or between the carbon nanospikes. Also disclosed herein is a method of producing the electrocatalyst. Also described herein is a method for converting carbon dioxide into hydrocarbons by use of the above-described electrocatalyst. The method for producing hydrocarbons more specifically involves contacting the electrocatalyst with an aqueous solution of a bicarbonate salt while the aqueous solution is in contact with a source of carbon dioxide, and electrically powering the electrocatalyst as a cathode at negative potential condition while the cathode is in electrical communication with a counter electrode electrically powered as an anode, to convert the carbon dioxide into hydrocarbons containing at least four carbon atoms and composed of only carbon and hydrogen.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2022},

  month        = {12}

}

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Title: Alloy based electrochemical catalyst for conversion of carbon dioxide to hydrocarbons

Abstract

Citation Formats

Electrocatalyst for Electrochemical Conversion of Carbon Dioxide patent-application, October 2013

High-Entropy Alloys as Catalysts for the CO 2 and CO Reduction Reactions: Experimental Realization journal, February 2020

Synthesis, Characterization, and Application of Metal Nanoparticles Supported on Nitrogen-Doped Carbon: Catalysis beyond Electrochemistry journal, September 2016

Porous Metal Dendrites as Gas Diffusion Electrodes for High Efficiency Aqueous Reduction of CO2 to Hydrocarbons patent-application, February 2013

Synthesis and size control of copper nanoparticles and their catalytic application journal, December 2015

CO 2 Electroreduction to Hydrocarbons on Carbon-Supported Cu Nanoparticles journal, September 2014

Conversion of carbon dioxide to organic products patent, November 2012

Fe and Pt carbon nanotubes for the electrocatalytic conversion of carbon dioxide to oxygenates journal, May 2009

Electrocatalyst for the oxidation of methane and an electrocatalytic process patent, September 1991

Preparation of asymmetrically distributed bimetal ceria (CeO2) and copper (Cu) nanoparticles in nitrogen-doped activated carbon micro/nanofibers for the removal of nitric oxide (NO) by reduction journal, December 2014

Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst journal, September 2014

Electrochemical Method for Synthesizing Metal-Containing Particles and Other Objects patent-application, September 2014

Electrochemical Catalyst for Conversion of CO2 to Ethanol patent-application, November 2017

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Theoretical insight into the electrocatalytic reduction of CO 2 with different metal ratios and reaction mechanisms on palladium–copper alloys journal, January 2019

Synthesis of Copper Nanostructures by Electrodeposition journal, May 2008

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Facile one-step electrochemical fabrication of a non-enzymatic glucose-selective glassy carbon electrode modified with copper nanoparticles and graphene journal, April 2012

Controlled Electrodeposition of Nanoparticles patent-application, May 2010

Reducing Carbon Dioxide To Products patent-application, May 2011

Novel Nitrogen-Doped Copper Nanocatalysts for Carbon Dioxide Reduction Reaction patent-application, October 2019

Electrocatalyst patent, December 1997

Materials and Methods for Electrochemical Reduction of Carbon Dioxide patent-application, March 2018

Copper Nanoparticles: Synthetic Strategies, Properties and Multifunctional Application journal, April 2014

Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media journal, August 1994

Biofuel cell electrocatalysts utilizing enzyme-carbon nanotube adducts patent, October 2014

Vehicle Electrocatalyzer for Recycling Carbone Dioxide to Fuel Hydrocarbons patent-application, June 2012

Electrochemical Catalyst for Conversion of CO2 to Ethanol patent-application, May 2019

Electrochemical Conversion of CO2 into Aqueous-ph Organic Molecules Employing a Ni-nanoparticle- Glassy Carbon Electrode journal, December 2014

Electrocatalyst for Electrochemical Conversion of Carbon Dioxide
patent-application, October 2013

High-Entropy Alloys as Catalysts for the CO ₂ and CO Reduction Reactions: Experimental Realization
journal, February 2020

Synthesis, Characterization, and Application of Metal Nanoparticles Supported on Nitrogen-Doped Carbon: Catalysis beyond Electrochemistry
journal, September 2016

Porous Metal Dendrites as Gas Diffusion Electrodes for High Efficiency Aqueous Reduction of CO₂ to Hydrocarbons
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Synthesis and size control of copper nanoparticles and their catalytic application
journal, December 2015

CO ₂ Electroreduction to Hydrocarbons on Carbon-Supported Cu Nanoparticles
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Conversion of carbon dioxide to organic products
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Fe and Pt carbon nanotubes for the electrocatalytic conversion of carbon dioxide to oxygenates
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Electrocatalyst for the oxidation of methane and an electrocatalytic process
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Preparation of asymmetrically distributed bimetal ceria (CeO2) and copper (Cu) nanoparticles in nitrogen-doped activated carbon micro/nanofibers for the removal of nitric oxide (NO) by reduction
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