Selective, adsorbate-induced spin state changes in transition metal-based metal-organic frameworks
Abstract
An adsorbate-selective metal organic framework includes a transition metal; and a plurality of organic molecules coordinated to the transition metal so as to preserve open coordination sites for selectively adsorbing molecules that have low-lying π* orbitals. The transition metal has a lowest energy spin state in the presence of the selectively adsorbed molecules that are strongly bonding to the transition metal through π-donating interactions which is different than the lowest energy spin state in the absence of these adsorbed molecules. The transition metal has also a lowest energy spin state in the presence of non-selected molecules that are weakly bonding to the transition metal through σ- and/or π-accepting and/or donating interactions.
- Inventors:
- Issue Date:
- Research Org.:
- Univ. of California, Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1986889
- Patent Number(s):
- 11517878
- Application Number:
- 16/089,199
- Assignee:
- The Regents of the University of California (Oakland, CA)
- DOE Contract Number:
- SC0001015
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 03/31/2017
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Long, Jeffrey R., Keitz, Benjamin K., and Reed, Douglas. Selective, adsorbate-induced spin state changes in transition metal-based metal-organic frameworks. United States: N. p., 2022.
Web.
Long, Jeffrey R., Keitz, Benjamin K., & Reed, Douglas. Selective, adsorbate-induced spin state changes in transition metal-based metal-organic frameworks. United States.
Long, Jeffrey R., Keitz, Benjamin K., and Reed, Douglas. Tue .
"Selective, adsorbate-induced spin state changes in transition metal-based metal-organic frameworks". United States. https://www.osti.gov/servlets/purl/1986889.
@article{osti_1986889,
title = {Selective, adsorbate-induced spin state changes in transition metal-based metal-organic frameworks},
author = {Long, Jeffrey R. and Keitz, Benjamin K. and Reed, Douglas},
abstractNote = {An adsorbate-selective metal organic framework includes a transition metal; and a plurality of organic molecules coordinated to the transition metal so as to preserve open coordination sites for selectively adsorbing molecules that have low-lying π* orbitals. The transition metal has a lowest energy spin state in the presence of the selectively adsorbed molecules that are strongly bonding to the transition metal through π-donating interactions which is different than the lowest energy spin state in the absence of these adsorbed molecules. The transition metal has also a lowest energy spin state in the presence of non-selected molecules that are weakly bonding to the transition metal through σ- and/or π-accepting and/or donating interactions.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2022},
month = {12}
}
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Works referenced in this record:
Self-Accelerating CO Sorption in a Soft Nanoporous Crystal
journal, December 2013
- Sato, H.; Kosaka, W.; Matsuda, R.
- Science, Vol. 343, Issue 6167
Multistep N 2 Breathing in the Metal−Organic Framework Co(1,4-benzenedipyrazolate)
journal, October 2010
- Salles, Fabrice; Maurin, Guillaume; Serre, Christian
- Journal of the American Chemical Society, Vol. 132, Issue 39
Functional Porous Coordination Polymers
journal, April 2004
- Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro
- Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2334-2375
Methane Storage in Metal–Organic Frameworks: Current Records, Surprise Findings, and Challenges
journal, July 2013
- Peng, Yang; Krungleviciute, Vaiva; Eryazici, Ibrahim
- Journal of the American Chemical Society, Vol. 135, Issue 32, p. 11887-11894
Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal−Organic Framework Functionalized with Ethylenediamine
journal, July 2009
- Demessence, Aude; D’Alessandro, Deanna M.; Foo, Maw Lin
- Journal of the American Chemical Society, Vol. 131, Issue 25, p. 8784-8786
Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide
journal, January 2009
- Dietzel, Pascal D. C.; Besikiotis, Vasileios; Blom, Richard
- Journal of Materials Chemistry, Vol. 19, Issue 39, p. 7362-7370
Drastic Enhancement of Catalytic Activity via Post-oxidation of a Porous Mn II Triazolate Framework
journal, July 2014
- Liao, Pei-Qin; Li, Xu-Yu; Bai, Jie
- Chemistry - A European Journal, Vol. 20, Issue 36
A Five-Coordinate Heme Dioxygen Adduct Isolated within a Metal–Organic Framework
journal, November 2014
- Anderson, John S.; Gallagher, Audrey T.; Mason, Jarad A.
- Journal of the American Chemical Society, Vol. 136, Issue 47
Highly controlled acetylene accommodation in a metal–organic microporous material
journal, July 2005
- Matsuda, Ryotaro; Kitaura, Ryo; Kitagawa, Susumu
- Nature, Vol. 436, Issue 7048
Hydrocarbon Separations in Metal–Organic Frameworks
journal, September 2013
- Herm, Zoey R.; Bloch, Eric D.; Long, Jeffrey R.
- Chemistry of Materials, Vol. 26, Issue 1
Metal−Organic Frameworks as Adsorbents for Hydrogen Purification and Precombustion Carbon Dioxide Capture
journal, April 2011
- Herm, Zoey R.; Swisher, Joseph A.; Smit, Berend
- Journal of the American Chemical Society, Vol. 133, Issue 15
Single-Crystal to Single-Crystal Structural Transformation and Photomagnetic Properties of a Porous Iron(II) Spin-Crossover Framework
journal, March 2008
- Neville, Suzanne M.; Halder, Gregory J.; Chapman, Karena W.
- Journal of the American Chemical Society, Vol. 130, Issue 9
Reversible CO Binding Enables Tunable CO/H 2 and CO/N 2 Separations in Metal–Organic Frameworks with Exposed Divalent Metal Cations
journal, July 2014
- Bloch, Eric D.; Hudson, Matthew R.; Mason, Jarad A.
- Journal of the American Chemical Society, Vol. 136, Issue 30
Improved Purge Step in Pressure Swing Adsorption for CO Purification
journal, July 2005
- Miyajima, Hideki; Kodama, Akio; Goto, Motonobu
- Adsorption, Vol. 11, Issue S1
Metal−Organic Frameworks with Functional Pores for Recognition of Small Molecules
journal, August 2010
- Chen, Banglin; Xiang, Shengchang; Qian, Guodong
- Accounts of Chemical Research, Vol. 43, Issue 8
CO2/CH4, CH4/H2 and CO2/CH4/H2 separations at high pressures using Mg2(dobdc)
journal, March 2012
- Herm, Zoey R.; Krishna, Rajamani; Long, Jeffrey R.
- Microporous and Mesoporous Materials, Vol. 151
Adsorbent for Selective Adsorption of Carbon Monoxide and Process for Preparation Thereof
patent-application, August 2010
- Cho, Soon Haeng; Bhat, Sodankoor Garadi Thirumaleshwara; Han, Sang Sup
- US Patent Application 12/602841; 20100204043
Evaluating metal–organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption
journal, January 2011
- Mason, Jarad A.; Sumida, Kenji; Herm, Zoey R.
- Energy & Environmental Science, Vol. 4, Issue 8, p. 3030-3040
Bidirectional Chemo-Switching of Spin State in a Microporous Framework
journal, June 2009
- Ohba, Masaaki; Yoneda, Ko; Agustí, Gloria
- Angewandte Chemie International Edition, Vol. 48, Issue 26
Separation of Binary Mixtures of CO and H 2 by Permeation Through Polymeric Films
journal, October 1972
- McCandless, F. P.
- Industrial & Engineering Chemistry Process Design and Development, Vol. 11, Issue 4
Metal–Organic Frameworks for Separations
journal, September 2011
- Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai
- Chemical Reviews, Vol. 112, Issue 2, p. 869-932
Evaluating metal–organic frameworks for natural gas storage
journal, January 2014
- Mason, Jarad A.; Veenstra, Mike; Long, Jeffrey R.
- Chemical Science, Vol. 5, Issue 1, p. 32-51
A spin transition mechanism for cooperative adsorption in metal–organic frameworks
journal, September 2017
- Reed, Douglas A.; Keitz, Benjamin K.; Oktawiec, Julia
- Nature, Vol. 550, Issue 7674
Reversible CO Scavenging via Adsorbate-Dependent Spin State Transitions in an Iron(II)–Triazolate Metal–Organic Framework
journal, April 2016
- Reed, Douglas A.; Xiao, Dianne J.; Gonzalez, Miguel I.
- Journal of the American Chemical Society, Vol. 138, Issue 17
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999
- Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
- Nature, Vol. 402, Issue 6759, p. 276-279
Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011
- Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
- Chemical Reviews, Vol. 112, Issue 2, p. 724-781
Scorpionate-Type Coordination in MFU-4 l Metal-Organic Frameworks: Small-Molecule Binding and Activation upon the Thermally Activated Formation of Open Metal Sites
journal, May 2014
- Denysenko, Dmytro; Grzywa, Maciej; Jelic, Jelena
- Angewandte Chemie International Edition, Vol. 53, Issue 23
Hybrid porous solids past, present, future
journal, January 2008
- Férey, Gérard
- Chem. Soc. Rev., Vol. 37, Issue 1, p. 191-214
High thermal and chemical stability in pyrazolate-bridged metal–organic frameworks with exposed metal sites
journal, January 2011
- Colombo, Valentina; Galli, Simona; Choi, Hye Jin
- Chemical Science, Vol. 2, Issue 7, p. 1311-1319
Guest-Dependent Spin Crossover in a Nanoporous Molecular Framework Material
journal, November 2002
- Halder, G. J.
- Science, Vol. 298, Issue 5599
Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
journal, March 2015
- McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian
- Nature, Vol. 519, Issue 7543
Developments in CO separation
journal, December 1995
- Dutta, N. N.; Patil, G. S.
- Gas Separation & Purification, Vol. 9, Issue 4
Dynamic Interplay between Spin-Crossover and Host−Guest Function in a Nanoporous Metal−Organic Framework Material
journal, August 2009
- Southon, Peter D.; Liu, Lang; Fellows, Elizabeth A.
- Journal of the American Chemical Society, Vol. 131, Issue 31
Industrial applications of metal–organic frameworks
journal, January 2009
- Czaja, Alexander U.; Trukhan, Natalia; Müller, Ulrich
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1284-1293
Metal-Organic Framework Adsorbents for Composite Gas Separation
patent-application, March 2014
- Long, Jeffrey R.; Herm, Zoey R.; Swisher, Joseph A.
- US Patent Document 13/965098; 20140061540
Selective Binding of O 2 over N 2 in a Redox–Active Metal–Organic Framework with Open Iron(II) Coordination Sites
journal, September 2011
- Bloch, Eric D.; Murray, Leslie J.; Queen, Wendy L.
- Journal of the American Chemical Society, Vol. 133, Issue 37
Cooperative Spin Crossover Behavior in Cyanide-Bridged Fe(II)−M(II) Bimetallic 3D Hofmann-like Networks (M = Ni, Pd, and Pt)
journal, July 2001
- Niel, Virginie; Martinez-Agudo, José María; Muñoz, M. Carmen
- Inorganic Chemistry, Vol. 40, Issue 16
The CO Poisoning Effect in PEMFCs Operational at Temperatures up to 200°C
journal, January 2003
- Li, Qingfeng; He, Ronghuan; Gao, Ji-An
- Journal of The Electrochemical Society, Vol. 150, Issue 12
Carbon monoxide poisoning of proton exchange membrane fuel cells
journal, January 2001
- Baschuk, J. J.; Li, Xianguo
- International Journal of Energy Research, Vol. 25, Issue 8
Hydrogen Storage in Microporous Metal-Organic Frameworks with Exposed Metal Sites
journal, August 2008
- Dincă, Mircea; Long, Jeffrey R.
- Angewandte Chemie International Edition, Vol. 47, Issue 36, p. 6766-6779
Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature
journal, December 2005
- Millward, Andrew R.; Yaghi, Omar M.
- Journal of the American Chemical Society, Vol. 127, Issue 51, p. 17998-17999
Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
journal, August 2008
- Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
- Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871
Gas Storage in Nanoporous Materials
journal, June 2008
- Morris, Russell E.; Wheatley, Paul S.
- Angewandte Chemie International Edition, Vol. 47, Issue 27
Design of a Metal–Organic Framework with Enhanced Back Bonding for Separation of N 2 and CH 4
journal, December 2013
- Lee, Kyuho; Isley, William C.; Dzubak, Allison L.
- Journal of the American Chemical Society, Vol. 136, Issue 2
Single-Crystal-to-Single-Crystal Metalation of a Metal–Organic Framework: A Route toward Structurally Well-Defined Catalysts
journal, February 2015
- Gonzalez, Miguel I.; Bloch, Eric D.; Mason, Jarad A.
- Inorganic Chemistry, Vol. 54, Issue 6
Adsorption of carbon monoxide on activated carbon impregnated with metal halide
journal, February 1996
- Tamon, Hajime; Kitamura, Kenji; Okazaki, Morio
- AIChE Journal, Vol. 42, Issue 2
New Iron(II) Spin Crossover Coordination Polymers [Fe(μ-atrz)3]X2·2H2O (X = ClO4¯, BF4¯) and [Fe(μ-atrz)(μ-pyz)(NCS)2]·4H2O with an Interesting Solvent Effect
journal, March 2012
- Chuang, Yu-Chun; Liu, Chi-Tsun; Sheu, Chou-Fu
- Inorganic Chemistry, Vol. 51, Issue 8
Introduction to Metal–Organic Frameworks
journal, September 2011
- Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M.
- Chemical Reviews, Vol. 112, Issue 2, p. 673-674