Methods for synthesizing vanadium oxide nanobelts and applications as cathode materials for batteries
Abstract
In general, the present disclosure is directed to methods for synthesizing vanadium oxide nanobelts, as well as the corresponding chemical composition of the vanadium oxide nanobelts. Also described are materials which can incorporate the vanadium oxide nanobelts, such as including the vanadium oxide nanobelts as a cathode material for use in energy storage applications (e.g., batteries). The vanadium oxide nanobelts described herein display structural characteristics that may provide improved diffusion and/or charge transfer between ions. Thus, batteries incorporating implementations of the current disclosure may demonstrate improved properties such as higher capacity retention over charge discharge cycling.
- Inventors:
- Issue Date:
- Research Org.:
- Univ. of South Carolina, Columbia, SC (United States)
- Sponsoring Org.:
- USDOE; National Science Foundation (NSF)
- OSTI Identifier:
- 1986883
- Patent Number(s):
- 11522180
- Application Number:
- 16/894,249
- Assignee:
- University of South Carolina (Columbia, SC)
- DOE Contract Number:
- AR0000492; CBET-1801284; DMR-1464112
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 06/05/2020
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Huang, Kevin, and Zhu, Kaiyue. Methods for synthesizing vanadium oxide nanobelts and applications as cathode materials for batteries. United States: N. p., 2022.
Web.
Huang, Kevin, & Zhu, Kaiyue. Methods for synthesizing vanadium oxide nanobelts and applications as cathode materials for batteries. United States.
Huang, Kevin, and Zhu, Kaiyue. Tue .
"Methods for synthesizing vanadium oxide nanobelts and applications as cathode materials for batteries". United States. https://www.osti.gov/servlets/purl/1986883.
@article{osti_1986883,
title = {Methods for synthesizing vanadium oxide nanobelts and applications as cathode materials for batteries},
author = {Huang, Kevin and Zhu, Kaiyue},
abstractNote = {In general, the present disclosure is directed to methods for synthesizing vanadium oxide nanobelts, as well as the corresponding chemical composition of the vanadium oxide nanobelts. Also described are materials which can incorporate the vanadium oxide nanobelts, such as including the vanadium oxide nanobelts as a cathode material for use in energy storage applications (e.g., batteries). The vanadium oxide nanobelts described herein display structural characteristics that may provide improved diffusion and/or charge transfer between ions. Thus, batteries incorporating implementations of the current disclosure may demonstrate improved properties such as higher capacity retention over charge discharge cycling.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2022},
month = {12}
}
Works referenced in this record:
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
K 2 V 6 O 16 ·2.7H 2 O nanorod cathode: an advanced intercalation system for high energy aqueous rechargeable Zn-ion batteries
journal, January 2018
- Sambandam, Balaji; Soundharrajan, Vaiyapuri; Kim, Sungjin
- Journal of Materials Chemistry A, Vol. 6, Issue 32
Li + intercalated V 2 O 5 · n H 2 O with enlarged layer spacing and fast ion diffusion as an aqueous zinc-ion battery cathode
journal, January 2018
- Yang, Yongqiang; Tang, Yan; Fang, Guozhao
- Energy & Environmental Science, Vol. 11, Issue 11
Cation-Deficient Spinel ZnMn 2 O 4 Cathode in Zn(CF 3 SO 3 ) 2 Electrolyte for Rechargeable Aqueous Zn-Ion Battery
journal, September 2016
- Zhang, Ning; Cheng, Fangyi; Liu, Yongchang
- Journal of the American Chemical Society, Vol. 138, Issue 39
A Brief Review on Multivalent Intercalation Batteries with Aqueous Electrolytes
journal, February 2016
- Guduru, Ramesh; Icaza, Juan
- Nanomaterials, Vol. 6, Issue 3
Mechanistic Insight into the Electrochemical Performance of Zn/VO 2 Batteries with an Aqueous ZnSO 4 Electrolyte
journal, April 2019
- Li, Zhaolong; Ganapathy, Swapna; Xu, Yaolin
- Advanced Energy Materials, Vol. 9, Issue 22
Evaluation of Multivalent Cation Insertion in Single- and Double-Layered Polymorphs of V 2 O 5
journal, July 2017
- Parija, Abhishek; Prendergast, David; Banerjee, Sarbajit
- ACS Applied Materials & Interfaces, Vol. 9, Issue 28
Recent Advances in Zn-Ion Batteries
journal, August 2018
- Song, Ming; Tan, Hua; Chao, Dongliang
- Advanced Functional Materials, Vol. 28, Issue 41
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Pseudocapacitive oxide materials for high-rate electrochemical energy storage
journal, January 2014
- Augustyn, Veronica; Simon, Patrice; Dunn, Bruce
- Energy & Environmental Science, Vol. 7, Issue 5
Hydrated Layered Vanadium Oxide as a Highly Reversible Cathode for Rechargeable Aqueous Zinc Batteries
journal, January 2019
- Zhang, Ning; Jia, Ming; Dong, Yang
- Advanced Functional Materials, Vol. 29, Issue 10
Zn/MnO 2 Battery Chemistry With H + and Zn 2+ Coinsertion
journal, July 2017
- Sun, Wei; Wang, Fei; Hou, Singyuk
- Journal of the American Chemical Society, Vol. 139, Issue 29
Reversible aqueous zinc/manganese oxide energy storage from conversion reactions
journal, April 2016
- Pan, Huilin; Shao, Yuyan; Yan, Pengfei
- Nature Energy, Vol. 1, Issue 5
Long-life and deeply rechargeable aqueous Zn anodes enabled by a multifunctional brightener-inspired interphase
journal, January 2019
- Zhao, Zhiming; Zhao, Jingwen; Hu, Zhenglin
- Energy & Environmental Science, Vol. 12, Issue 6
Opportunities and challenges for a sustainable energy future
journal, August 2012
- Chu, Steven; Majumdar, Arun
- Nature, Vol. 488, Issue 7411, p. 294-303
Electrochemical Zinc-Ion Intercalation Properties and Crystal Structures of ZnMo 6 S 8 and Zn 2 Mo 6 S 8 Chevrel Phases in Aqueous Electrolytes
journal, March 2016
- Chae, Munseok S.; Heo, Jongwook W.; Lim, Sung-Chul
- Inorganic Chemistry, Vol. 55, Issue 7
Water-Lubricated Intercalation in V 2 O 5 ·nH 2 O for High-Capacity and High-Rate Aqueous Rechargeable Zinc Batteries
journal, November 2017
- Yan, Mengyu; He, Pan; Chen, Ying
- Advanced Materials, Vol. 30, Issue 1
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Method of Preparing a Vanadium Oxide Compound and Use Thereof in Electrochemical Cells
patent-application, January 2016
- Nair, Vivek; Srinivasan, Madhavi; Cheah, Yan Ling
- US Patent Application 14/761,581; 2016/0006028 Al
Electrochemical Zinc Intercalation in Lithium Vanadium Oxide: A High-Capacity Zinc-Ion Battery Cathode
journal, February 2017
- Alfaruqi, Muhammad H.; Mathew, Vinod; Song, Jinju
- Chemistry of Materials, Vol. 29, Issue 4
High power lithium ion battery materials by computational design
journal, July 2011
- Adams, Stefan; Rao, R. Prasada
- physica status solidi (a), Vol. 208, Issue 8
Highly reversible zinc metal anode for aqueous batteries
journal, April 2018
- Wang, Fei; Borodin, Oleg; Gao, Tao
- Nature Materials, Vol. 17, Issue 6
H 2 V 3 O 8 Nanowire/Graphene Electrodes for Aqueous Rechargeable Zinc Ion Batteries with High Rate Capability and Large Capacity
journal, March 2018
- Pang, Qiang; Sun, Congli; Yu, Yanhao
- Advanced Energy Materials, Vol. 8, Issue 19
High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance
journal, April 2013
- Augustyn, Veronica; Come, Jérémy; Lowe, Michael A.
- Nature Materials, Vol. 12, Issue 6
First-principles calculations of the electronic structure and spectra of strongly correlated systems: the LDA + U method
journal, January 1997
- Anisimov, Vladimir I.; Aryasetiawan, F.; Lichtenstein, A. I.
- Journal of Physics: Condensed Matter, Vol. 9, Issue 4, p. 767-808
A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode
journal, August 2016
- Kundu, Dipan; Adams, Brian D.; Duffort, Victor
- Nature Energy, Vol. 1, Issue 10
Behavior of Molybdenum Nitrides as Materials for Electrochemical Capacitors
journal, January 1998
- Liu, T. -C.
- Journal of The Electrochemical Society, Vol. 145, Issue 6
An Aqueous Zinc-Ion Battery Based on Copper Hexacyanoferrate
journal, December 2014
- Trócoli, Rafael; La Mantia, Fabio
- ChemSusChem, Vol. 8, Issue 3
Unraveling the role of structural water in bilayer V 2 O 5 during Zn 2+ -intercalation: insights from DFT calculations
journal, January 2019
- Wu, Tao; Zhu, Kaiyue; Qin, Changyong
- Journal of Materials Chemistry A, Vol. 7, Issue 10
Aqueous vs. nonaqueous Zn-ion batteries: consequences of the desolvation penalty at the interface
journal, January 2018
- Kundu, Dipan; Hosseini Vajargah, Shahrzad; Wan, Liwen
- Energy & Environmental Science, Vol. 11, Issue 4
Inhomogeneous Electron Gas
journal, November 1964
- Hohenberg, P.; Kohn, W.
- Physical Review, Vol. 136, Issue 3B, p. B864-B871
Highly Stable Aqueous Zinc-Ion Storage Using a Layered Calcium Vanadium Oxide Bronze Cathode
journal, February 2018
- Xia, Chuan; Guo, Jing; Li, Peng
- Angewandte Chemie International Edition, Vol. 57, Issue 15
Layered Mg x V 2 O 5 · n H 2 O as Cathode Material for High-Performance Aqueous Zinc Ion Batteries
journal, September 2018
- Ming, Fangwang; Liang, Hanfeng; Lei, Yongjiu
- ACS Energy Letters, Vol. 3, Issue 10
Pseudocapacitive Contributions to Electrochemical Energy Storage in TiO2 (Anatase) Nanoparticles
journal, October 2007
- Wang, John; Polleux, Julien; Lim, James
- The Journal of Physical Chemistry C, Vol. 111, Issue 40, p. 14925-14931
XPS and UPS study of Na deposition on thin film V2O5
journal, December 2005
- Wu, Qi-Hui; Thißen, A.; Jaegermann, W.
- Applied Surface Science, Vol. 252, Issue 5
Towards greener and more sustainable batteries for electrical energy storage
journal, November 2014
- Larcher, D.; Tarascon, J-M.
- Nature Chemistry, Vol. 7, Issue 1
Aqueous rechargeable zinc/sodium vanadate batteries with enhanced performance from simultaneous insertion of dual carriers
journal, April 2018
- Wan, Fang; Zhang, Linlin; Dai, Xi
- Nature Communications, Vol. 9, Issue 1
Aqueous batteries as grid scale energy storage solutions
journal, February 2017
- Posada, Jorge Omar Gil; Rennie, Anthony J. R.; Villar, Sofia Perez
- Renewable and Sustainable Energy Reviews, Vol. 68
The role and utilization of pseudocapacitance for energy storage by supercapacitors
journal, May 1997
- Conway, B. E.; Birss, V.; Wojtowicz, J.
- Journal of Power Sources, Vol. 66, Issue 1-2
Suppressed Activation Energy for Interfacial Charge Transfer of a Prussian Blue Analog Thin Film Electrode with Hydrated Ions (Li + , Na + , and Mg 2+ )
journal, May 2013
- Mizuno, Yoshifumi; Okubo, Masashi; Hosono, Eiji
- The Journal of Physical Chemistry C, Vol. 117, Issue 21
Structural water engaged disordered vanadium oxide nanosheets for high capacity aqueous potassium-ion storage
journal, May 2017
- Charles, Daniel Scott; Feygenson, Mikhail; Page, Katharine
- Nature Communications, Vol. 8, Issue 1
Recent Advances in Aqueous Zinc-Ion Batteries
journal, September 2018
- Fang, Guozhao; Zhou, Jiang; Pan, Anqiang
- ACS Energy Letters, Vol. 3, Issue 10
Effect of the damping function in dispersion corrected density functional theory
journal, March 2011
- Grimme, Stefan; Ehrlich, Stephan; Goerigk, Lars
- Journal of Computational Chemistry, Vol. 32, Issue 7
Layered VS 2 Nanosheet-Based Aqueous Zn Ion Battery Cathode
journal, January 2017
- He, Pan; Yan, Mengyu; Zhang, Guobin
- Advanced Energy Materials, Vol. 7, Issue 11
Quantitative investigation on the effect of hydrogenation on the performance of MnO 2 /H-TiO 2 composite electrodes for supercapacitors
journal, January 2015
- Cao, X. Y.; Xing, X.; Zhang, N.
- Journal of Materials Chemistry A, Vol. 3, Issue 7
Highly Durable Na 2 V 6 O 16 ·1.63H 2 O Nanowire Cathode for Aqueous Zinc-Ion Battery
journal, February 2018
- Hu, Ping; Zhu, Ting; Wang, Xuanpeng
- Nano Letters, Vol. 18, Issue 3
Preparation of Cathode Active Material by Hydrothermal Reaction
patent-application, June 2008
- Takeuchi, Esther S.; Lamothe, Veronica; Leising, Randolph
- US Patent Application 10/894305; 20080138707
Mechanistic Insights of Zn 2+ Storage in Sodium Vanadates
journal, August 2018
- Guo, Xun; Fang, Guozhao; Zhang, Wenyu
- Advanced Energy Materials, Vol. 8, Issue 27
Zn/V 2 O 5 Aqueous Hybrid-Ion Battery with High Voltage Platform and Long Cycle Life
journal, December 2017
- Hu, Ping; Yan, Mengyu; Zhu, Ting
- ACS Applied Materials & Interfaces, Vol. 9, Issue 49
Aqueous Rechargeable Li and Na Ion Batteries
journal, September 2014
- Kim, Haegyeom; Hong, Jihyun; Park, Kyu-Young
- Chemical Reviews, Vol. 114, Issue 23
Self-Consistent Equations Including Exchange and Correlation Effects
journal, November 1965
- Kohn, W.; Sham, L. J.
- Physical Review, Vol. 140, Issue 4A, p. A1133-A1138
Present and Future Perspective on Electrode Materials for Rechargeable Zinc-Ion Batteries
journal, September 2018
- Konarov, Aishuak; Voronina, Natalia; Jo, Jae Hyeon
- ACS Energy Letters, Vol. 3, Issue 10
Improved initial guess for minimum energy path calculations
journal, June 2014
- Smidstrup, Søren; Pedersen, Andreas; Stokbro, Kurt
- The Journal of Chemical Physics, Vol. 140, Issue 21
Recent Progress of Rechargeable Batteries Using Mild Aqueous Electrolytes
journal, September 2018
- Huang, Jianhang; Guo, Zhaowei; Ma, Yuanyuan
- Small Methods, Vol. 3, Issue 1
Na 2 V 6 O 16 ·3H 2 O Barnesite Nanorod: An Open Door to Display a Stable and High Energy for Aqueous Rechargeable Zn-Ion Batteries as Cathodes
journal, March 2018
- Soundharrajan, Vaiyapuri; Sambandam, Balaji; Kim, Sungjin
- Nano Letters, Vol. 18, Issue 4
Design and Tailoring of the Nanotubular Arrayed Architecture of Hydrous RuO 2 for Next Generation Supercapacitors
journal, December 2006
- Hu, Chi-Chang; Chang, Kuo-Hsin; Lin, Ming-Champ
- Nano Letters, Vol. 6, Issue 12
Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities
journal, September 2017
- Zhang, Ning; Cheng, Fangyi; Liu, Junxiang
- Nature Communications, Vol. 8, Issue 1
Rechargeable Aqueous Zinc-Ion Battery Based on Porous Framework Zinc Pyrovanadate Intercalation Cathode
journal, December 2017
- Xia, Chuan; Guo, Jing; Lei, Yongjiu
- Advanced Materials, Vol. 30, Issue 5
A reduced graphene oxide/Co3O4 composite for supercapacitor electrode
journal, March 2013
- Xiang, Chengcheng; Li, Ming; Zhi, Mingjia
- Journal of Power Sources, Vol. 226
High-Performance Aqueous Zinc-Ion Battery Based on Layered H 2 V 3 O 8 Nanowire Cathode
journal, November 2017
- He, Pan; Quan, Yueli; Xu, Xu
- Small, Vol. 13, Issue 47
Energetic Zinc Ion Chemistry: The Rechargeable Zinc Ion Battery
journal, December 2011
- Xu, Chengjun; Li, Baohua; Du, Hongda
- Angewandte Chemie International Edition, Vol. 51, Issue 4
Towards High-Voltage Aqueous Metal-Ion Batteries Beyond 1.5 V: The Zinc/Zinc Hexacyanoferrate System
journal, September 2014
- Zhang, Leyuan; Chen, Liang; Zhou, Xufeng
- Advanced Energy Materials, Vol. 5, Issue 2
Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011
- Dunn, B.; Kamath, H.; Tarascon, J. -M.
- Science, Vol. 334, Issue 6058
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
Zinc-ion batteries: Materials, mechanisms, and applications
journal, January 2019
- Ming, Jun; Guo, Jing; Xia, Chuan
- Materials Science and Engineering: R: Reports, Vol. 135
Electrochemical Energy Storage for Green Grid
journal, May 2011
- Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W.
- Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613