DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Methods for synthesizing vanadium oxide nanobelts and applications as cathode materials for batteries

Abstract

In general, the present disclosure is directed to methods for synthesizing vanadium oxide nanobelts, as well as the corresponding chemical composition of the vanadium oxide nanobelts. Also described are materials which can incorporate the vanadium oxide nanobelts, such as including the vanadium oxide nanobelts as a cathode material for use in energy storage applications (e.g., batteries). The vanadium oxide nanobelts described herein display structural characteristics that may provide improved diffusion and/or charge transfer between ions. Thus, batteries incorporating implementations of the current disclosure may demonstrate improved properties such as higher capacity retention over charge discharge cycling.

Inventors:
;
Issue Date:
Research Org.:
Univ. of South Carolina, Columbia, SC (United States)
Sponsoring Org.:
USDOE; National Science Foundation (NSF)
OSTI Identifier:
1986883
Patent Number(s):
11522180
Application Number:
16/894,249
Assignee:
University of South Carolina (Columbia, SC)
DOE Contract Number:  
AR0000492; CBET-1801284; DMR-1464112
Resource Type:
Patent
Resource Relation:
Patent File Date: 06/05/2020
Country of Publication:
United States
Language:
English

Citation Formats

Huang, Kevin, and Zhu, Kaiyue. Methods for synthesizing vanadium oxide nanobelts and applications as cathode materials for batteries. United States: N. p., 2022. Web.
Huang, Kevin, & Zhu, Kaiyue. Methods for synthesizing vanadium oxide nanobelts and applications as cathode materials for batteries. United States.
Huang, Kevin, and Zhu, Kaiyue. Tue . "Methods for synthesizing vanadium oxide nanobelts and applications as cathode materials for batteries". United States. https://www.osti.gov/servlets/purl/1986883.
@article{osti_1986883,
title = {Methods for synthesizing vanadium oxide nanobelts and applications as cathode materials for batteries},
author = {Huang, Kevin and Zhu, Kaiyue},
abstractNote = {In general, the present disclosure is directed to methods for synthesizing vanadium oxide nanobelts, as well as the corresponding chemical composition of the vanadium oxide nanobelts. Also described are materials which can incorporate the vanadium oxide nanobelts, such as including the vanadium oxide nanobelts as a cathode material for use in energy storage applications (e.g., batteries). The vanadium oxide nanobelts described herein display structural characteristics that may provide improved diffusion and/or charge transfer between ions. Thus, batteries incorporating implementations of the current disclosure may demonstrate improved properties such as higher capacity retention over charge discharge cycling.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2022},
month = {12}
}

Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996


K 2 V 6 O 16 ·2.7H 2 O nanorod cathode: an advanced intercalation system for high energy aqueous rechargeable Zn-ion batteries
journal, January 2018


Li + intercalated V 2 O 5 · n H 2 O with enlarged layer spacing and fast ion diffusion as an aqueous zinc-ion battery cathode
journal, January 2018


Cation-Deficient Spinel ZnMn 2 O 4 Cathode in Zn(CF 3 SO 3 ) 2 Electrolyte for Rechargeable Aqueous Zn-Ion Battery
journal, September 2016


A Brief Review on Multivalent Intercalation Batteries with Aqueous Electrolytes
journal, February 2016


Mechanistic Insight into the Electrochemical Performance of Zn/VO 2 Batteries with an Aqueous ZnSO 4 Electrolyte
journal, April 2019


Evaluation of Multivalent Cation Insertion in Single- and Double-Layered Polymorphs of V 2 O 5
journal, July 2017


Recent Advances in Zn-Ion Batteries
journal, August 2018


Projector augmented-wave method
journal, December 1994


Pseudocapacitive oxide materials for high-rate electrochemical energy storage
journal, January 2014


Hydrated Layered Vanadium Oxide as a Highly Reversible Cathode for Rechargeable Aqueous Zinc Batteries
journal, January 2019


Zn/MnO 2 Battery Chemistry With H + and Zn 2+ Coinsertion
journal, July 2017


Reversible aqueous zinc/manganese oxide energy storage from conversion reactions
journal, April 2016


Long-life and deeply rechargeable aqueous Zn anodes enabled by a multifunctional brightener-inspired interphase
journal, January 2019


Opportunities and challenges for a sustainable energy future
journal, August 2012


Issues and challenges facing rechargeable lithium batteries
journal, November 2001


Method of Preparing a Vanadium Oxide Compound and Use Thereof in Electrochemical Cells
patent-application, January 2016


Electrochemical Zinc Intercalation in Lithium Vanadium Oxide: A High-Capacity Zinc-Ion Battery Cathode
journal, February 2017


High power lithium ion battery materials by computational design
journal, July 2011


Highly reversible zinc metal anode for aqueous batteries
journal, April 2018


High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance
journal, April 2013


First-principles calculations of the electronic structure and spectra of strongly correlated systems: the LDA + U method
journal, January 1997


A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode
journal, August 2016


Behavior of Molybdenum Nitrides as Materials for Electrochemical Capacitors
journal, January 1998


An Aqueous Zinc-Ion Battery Based on Copper Hexacyanoferrate
journal, December 2014


Unraveling the role of structural water in bilayer V 2 O 5 during Zn 2+ -intercalation: insights from DFT calculations
journal, January 2019


Aqueous vs. nonaqueous Zn-ion batteries: consequences of the desolvation penalty at the interface
journal, January 2018


Inhomogeneous Electron Gas
journal, November 1964


Highly Stable Aqueous Zinc-Ion Storage Using a Layered Calcium Vanadium Oxide Bronze Cathode
journal, February 2018


Layered Mg x V 2 O 5 · n H 2 O as Cathode Material for High-Performance Aqueous Zinc Ion Batteries
journal, September 2018


Pseudocapacitive Contributions to Electrochemical Energy Storage in TiO2 (Anatase) Nanoparticles
journal, October 2007


XPS and UPS study of Na deposition on thin film V2O5
journal, December 2005


Towards greener and more sustainable batteries for electrical energy storage
journal, November 2014


Aqueous batteries as grid scale energy storage solutions
journal, February 2017


The role and utilization of pseudocapacitance for energy storage by supercapacitors
journal, May 1997


Suppressed Activation Energy for Interfacial Charge Transfer of a Prussian Blue Analog Thin Film Electrode with Hydrated Ions (Li + , Na + , and Mg 2+ )
journal, May 2013


Structural water engaged disordered vanadium oxide nanosheets for high capacity aqueous potassium-ion storage
journal, May 2017


Recent Advances in Aqueous Zinc-Ion Batteries
journal, September 2018


Effect of the damping function in dispersion corrected density functional theory
journal, March 2011


Layered VS 2 Nanosheet-Based Aqueous Zn Ion Battery Cathode
journal, January 2017


Highly Durable Na 2 V 6 O 16 ·1.63H 2 O Nanowire Cathode for Aqueous Zinc-Ion Battery
journal, February 2018


Preparation of Cathode Active Material by Hydrothermal Reaction
patent-application, June 2008


Mechanistic Insights of Zn 2+ Storage in Sodium Vanadates
journal, August 2018


Zn/V 2 O 5 Aqueous Hybrid-Ion Battery with High Voltage Platform and Long Cycle Life
journal, December 2017


Aqueous Rechargeable Li and Na Ion Batteries
journal, September 2014


Self-Consistent Equations Including Exchange and Correlation Effects
journal, November 1965


Present and Future Perspective on Electrode Materials for Rechargeable Zinc-Ion Batteries
journal, September 2018


Improved initial guess for minimum energy path calculations
journal, June 2014


Recent Progress of Rechargeable Batteries Using Mild Aqueous Electrolytes
journal, September 2018


Design and Tailoring of the Nanotubular Arrayed Architecture of Hydrous RuO 2 for Next Generation Supercapacitors
journal, December 2006


Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities
journal, September 2017


Rechargeable Aqueous Zinc-Ion Battery Based on Porous Framework Zinc Pyrovanadate Intercalation Cathode
journal, December 2017


A reduced graphene oxide/Co3O4 composite for supercapacitor electrode
journal, March 2013


Energetic Zinc Ion Chemistry: The Rechargeable Zinc Ion Battery
journal, December 2011


Towards High-Voltage Aqueous Metal-Ion Batteries Beyond 1.5 V: The Zinc/Zinc Hexacyanoferrate System
journal, September 2014


Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011


Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996


Zinc-ion batteries: Materials, mechanisms, and applications
journal, January 2019


Electrochemical Energy Storage for Green Grid
journal, May 2011