DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: In-situ polymerization to protect lithium metal electrodes

Abstract

An electrode including an electrode active material including lithium (Li) and a polymer layer coating at least a portion of the electrode active material is provided. The polymer layer includes a polymerization product of a monomer having Formula I: where R1 and R2 are independently an aryl or a branched or unbranched C1-C10 alkyl and X1 and X2 are independently chlorine (Cl), bromine (Br), or iodine (I).

Inventors:
;
Issue Date:
Research Org.:
GM Global Technology Operations LLC, Detroit, MI (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1986872
Patent Number(s):
11515538
Application Number:
16/599,714
Assignee:
GM Global Technology Operations LLC (Detroit, MI)
DOE Contract Number:  
EE0007787
Resource Type:
Patent
Resource Relation:
Patent File Date: 10/11/2019
Country of Publication:
United States
Language:
English

Citation Formats

Li, Binsong, and Xiao, Xingcheng. In-situ polymerization to protect lithium metal electrodes. United States: N. p., 2022. Web.
Li, Binsong, & Xiao, Xingcheng. In-situ polymerization to protect lithium metal electrodes. United States.
Li, Binsong, and Xiao, Xingcheng. Tue . "In-situ polymerization to protect lithium metal electrodes". United States. https://www.osti.gov/servlets/purl/1986872.
@article{osti_1986872,
title = {In-situ polymerization to protect lithium metal electrodes},
author = {Li, Binsong and Xiao, Xingcheng},
abstractNote = {An electrode including an electrode active material including lithium (Li) and a polymer layer coating at least a portion of the electrode active material is provided. The polymer layer includes a polymerization product of a monomer having Formula I: where R1 and R2 are independently an aryl or a branched or unbranched C1-C10 alkyl and X1 and X2 are independently chlorine (Cl), bromine (Br), or iodine (I).},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2022},
month = {11}
}

Works referenced in this record:

Passivation of sulfide, oxide, and oxysulfide glass electrolyte films for lithium metal batteries
patent-application, October 2018


Negative electrode for lithium-based batteries
patent, February 2019


Microporous and hierarchical porous carbon
patent, August 2019


High Energy Density Alkali Metal Batteries Incorporating Solid Electrolytes
patent-application, October 2018


Coated porous separators and coated electrodes for lithium batteries
patent-application, February 2015


Electrolyte and electrode structure
patent-application, June 2016


Nonaqueous Electrolyte and Nonaqueous Secondary Battery
patent-application, November 2016


Negative Electrode for Secondary Lithium Metal Battery and Method of Making
patent-application, June 2020


Ionically-conductive reinforced glass ceramic separators/solid electrolytes
patent-application, December 2018


Coated separator and one-step method for preparing the same
patent, May 2017


Lithium-based battery separator and method for making the same
patent, November 2018


Polymerization Process for Forming Polymeric Ultrathin Conformal Coatings on Electrode materials
patent-application, November 2017


Method of Chemical Protection of Metal Surface
patent-application, March 2008


Particle reactor for atomic layer deposition (ALD) and chemical vapor deposition (CVD) processes
patent, February 2018


Electrolyte for Lithium Secondary Battery and Lithium Secondary Battery Including the Same
patent-application, December 2019


Protective Negative Electrode for Lithium Metal Battery and Lithium Metal Battery Comprising Same
patent-application, April 2019


Electrode for Non-Aqueous Electrolyte Battery and Non-Aqueous Electrolyte Battery
patent-application, January 2022


Methods for making coated porous separators and coated electrodes for lithium batteries
patent-application, February 2015


Gel electrolytes and precursors thereof
patent, June 2019


Primer Surface Coating For High-Performance Silicon-Based Electrodes
patent-application, September 2017


Sulfur based active material for a positive electrode
patent, September 2016


Flexible membranes and coated electrodes for lithium based batteries
patent, August 2017


Electrolyte additives for lithium sulfur rechargeable batteries
patent, October 2015


Porous interlayer for a lithium-sulfur battery
patent, November 2018


Method for preparing a coated lithium battery component
patent-application, December 2015


Coating for separator or cathode of lithium—sulfur or silicon—sulfur battery
patent, March 2015


High Performance Battery Anodes with Polymeric Coatings
patent-application, March 2017


Porous interlayer for a lithium-sulfur battery
patent, June 2016


Protected electrode structures
patent, December 2020


Voltage-Responsive Coating for Lithium-Sulfur Battery
patent-application, April 2016


Protected Electrode Structures
patent-application, May 2021


Single lithium ion conductor as binder in lithium-sulfur or silicon-sulfur battery
patent, January 2017


Methods for making hollow carbon materials and active materials for electrodes
patent, April 2016


Forming sulfur-based positive electrode active materials
patent, May 2018


Electrolyte and negative electrode structure
patent-application, June 2016


Forming electrode active materials
patent, February 2018


Multifunction battery separator
patent, February 2016


Electrolyte structure for metal batteries
patent, March 2018


Multilayer Siloxane Coatings for Silicon Negative Electrode Materials for Lithium Ion Batteries
patent-application, February 2021


Making a pouch format cell and attaching a tab to an electrode
patent-application, July 2017


Electrolyte for Lithium Cell
patent-application, February 2016


Adaptive Multipath Fabric for Balanced Performance and High Availability
patent-application, September 2019


Electrolyte and negative electrode structure
patent, June 2019


Electrolytes and methods for using the same
patent-application, June 2017