Poly(aryl piperidinium) polymers including those with stable cationic pendant groups for use as anion exchange membranes and ionomers
Abstract
Poly(aryl piperidinium) polymers with pendant cationic groups are provided which have an alkaline-stable cation, piperidinium, introduced into a rigid aromatic polymer backbone free of ether bonds. Hydroxide exchange membranes or hydroxide exchange ionomers formed from these polymers exhibit superior chemical stability, hydroxide conductivity, decreased water uptake, good solubility in selected solvents, and improved mechanical properties in an ambient dry state as compared to conventional hydroxide exchange membranes or ionomers. Hydroxide exchange membrane fuel cells comprising the poly(aryl piperidinium) polymers with pendant cationic groups exhibit enhanced performance and durability at relatively high temperatures.
- Inventors:
- Issue Date:
- Research Org.:
- Univ. of Delaware, Newark, DE (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1986864
- Patent Number(s):
- 11512156
- Application Number:
- 16/651,622
- Assignee:
- University of Delaware (Newark, DE)
- DOE Contract Number:
- EE0006964
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 09/28/2018
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Yan, Yushan, Hu, Keda, Wang, Junhua, Wang, Lan, Xu, Bingjun, and Zhao, Yun. Poly(aryl piperidinium) polymers including those with stable cationic pendant groups for use as anion exchange membranes and ionomers. United States: N. p., 2022.
Web.
Yan, Yushan, Hu, Keda, Wang, Junhua, Wang, Lan, Xu, Bingjun, & Zhao, Yun. Poly(aryl piperidinium) polymers including those with stable cationic pendant groups for use as anion exchange membranes and ionomers. United States.
Yan, Yushan, Hu, Keda, Wang, Junhua, Wang, Lan, Xu, Bingjun, and Zhao, Yun. Tue .
"Poly(aryl piperidinium) polymers including those with stable cationic pendant groups for use as anion exchange membranes and ionomers". United States. https://www.osti.gov/servlets/purl/1986864.
@article{osti_1986864,
title = {Poly(aryl piperidinium) polymers including those with stable cationic pendant groups for use as anion exchange membranes and ionomers},
author = {Yan, Yushan and Hu, Keda and Wang, Junhua and Wang, Lan and Xu, Bingjun and Zhao, Yun},
abstractNote = {Poly(aryl piperidinium) polymers with pendant cationic groups are provided which have an alkaline-stable cation, piperidinium, introduced into a rigid aromatic polymer backbone free of ether bonds. Hydroxide exchange membranes or hydroxide exchange ionomers formed from these polymers exhibit superior chemical stability, hydroxide conductivity, decreased water uptake, good solubility in selected solvents, and improved mechanical properties in an ambient dry state as compared to conventional hydroxide exchange membranes or ionomers. Hydroxide exchange membrane fuel cells comprising the poly(aryl piperidinium) polymers with pendant cationic groups exhibit enhanced performance and durability at relatively high temperatures.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Nov 29 00:00:00 EST 2022},
month = {Tue Nov 29 00:00:00 EST 2022}
}
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Works referenced in this record:
Functionalizing Polystyrene with N -Alicyclic Piperidine-Based Cations via Friedel–Crafts Alkylation for Highly Alkali-Stable Anion-Exchange Membranes
journal, June 2020
- Olsson, Joel S.; Pham, Thanh Huong; Jannasch, Patric
- Macromolecules, Vol. 53, Issue 12
Water-insoluble anion exchanger materials
patent, August 2018
- Meier-Haack, Jochen
- US Patent Document 10,046,319
Anion Exchange Polymers and Anion Exchange Membranes Incorporating Same
patent-application, September 2017
- Bahar, Bamdad; Bae, Chulsung
- US Patent Application 15/448734; 20170252707
Nitroxide radical polymers – a versatile material class for high-tech applications
journal, January 2018
- Hansen, Kai-Anders; Blinco, James P.
- Polymer Chemistry, Vol. 9, Issue 13
Diamine compounds, methods of making same, method of use of same and intermediates
patent, February 1999
- Puckett, Wallace E.; Zollinger, Mark L.
- US Patent Document 5,869,655
Separating membrane of polyion complex
patent, February 1995
- Tsuyumoto, Michio; Sugimoto, Masahiko; Maeda, Yasushi
- US Patent Document 5,393,432
Anion Exchange Membranes and Polymers for Use in Same
patent-application, July 2017
- Bae, Chulsung; Mohanty, Angela Dee
- US Patent Application 15/326538; 20170203289
Certain Azoniaspironortropine Derivatives
patent, November 1969
- Pfleger, Robert; Bertholdt, Heinz; Schulz, Wolfram
- US Patent Document 3480626
Poly(aryl Piperidinium) Polymers for Use as Hydroxide Exchange Membranes and Ionomers
patent-application, January 2019
- Yan, Yushan; Xu, Bingjun; Wang, Junhua
- US Patent Application 16/146887; 20190036143