PDO or BMTZ ligand for supported coordinated PT hydrosilylation catalysts

Tait, Steven L.; Chen, Linxiao

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Title: PDO or BMTZ ligand for supported coordinated PT hydrosilylation catalysts

Abstract

The invention describes single-site metal catalysts such as Pt single-site centers on powdered oxide supports with a 1,10-phenanthroline-5,6-dione (PDO) or bis-pyrimidyltetrazine (BMTZ) ligand on powdered MgO, Al₂O₃, or CeO₂.

Inventors:: Tait, Steven L.; Chen, Linxiao

Issue Date:: 2022-11-01

Research Org.:: Indiana Univ., Bloomington, IN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

OSTI Identifier:: 1986771

Patent Number(s):: 11484872

Application Number:: 17/012,215

Assignee:: The Trustees of Indiana University (Bloomington, IL)

DOE Contract Number:: SC0016367

Resource Type:: Patent

Resource Relation:: Patent File Date: 09/04/2020

Country of Publication:: United States

Language:: English

Citation Formats


                    Tait, Steven L., and Chen, Linxiao. PDO or BMTZ ligand for supported coordinated PT hydrosilylation catalysts.  United States: N. p., 2022. 
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                    Tait, Steven L., & Chen, Linxiao. PDO or BMTZ ligand for supported coordinated PT hydrosilylation catalysts.  United States.

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                    Tait, Steven L., and Chen, Linxiao. Tue .  
        "PDO or BMTZ ligand for supported coordinated PT hydrosilylation catalysts".  United States.  https://www.osti.gov/servlets/purl/1986771.

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@article{osti_1986771,

  title        = {PDO or BMTZ ligand for supported coordinated PT hydrosilylation catalysts},

  author       = {Tait, Steven L. and Chen, Linxiao},

  abstractNote = {The invention describes single-site metal catalysts such as Pt single-site centers on powdered oxide supports with a 1,10-phenanthroline-5,6-dione (PDO) or bis-pyrimidyltetrazine (BMTZ) ligand on powdered MgO, Al2O3, or CeO2.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2022},

  month        = {11}

}

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Title: PDO or BMTZ ligand for supported coordinated PT hydrosilylation catalysts

Abstract

Citation Formats

Platinum(II) Complexes with Thioether-Functionalized Benzimidazolin-2-ylidene Ligands: Synthesis, Structural Characterization, and Application in Hydroelementation Reactions journal, December 2013

Multi‐electron Reduction Capacity and Multiple Binding Pockets in Metal–Organic Redox Assembly at Surfaces journal, March 2019

Rhenium-mediated dehydrogenative silylation and highly regioselective hydrosilylation of nitrile substituted olefins journal, January 2014

The New Tetrafunctional π Acceptor Ligand 3,6-Bis(2′-pyrimidyl)-1,2,4,5-tetrazine (bmtz): Diruthenium Complexes of bmtz and of its 1,4-Dihydro Form journal, January 1995

Fluorosilicones as High Temperature Elastomers journal, November 1971

Asymmetric hydrogenation, transfer hydrogenation and hydrosilylation of ketones catalyzed by iron complexes journal, January 2009

Propylene Hydrogenation and Propane Dehydrogenation by a Single-Site Zn 2+ on Silica Catalyst journal, March 2014

Dense organic catalytic membranes for fine chemical synthesis journal, February 2000

Single-site SBA-15 supported zirconium catalysts. Synthesis, characterization and toward cyanosilylation reaction journal, January 2015

Isolated, well-defined organovanadium( iii ) on silica: single-site catalyst for hydrogenation of alkenes and alkynes journal, January 2017

Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view journal, July 2011

Platinum nanoparticles in suspension are as efficient as Karstedt's complex for alkene hydrosilylation journal, January 2015

Single-Site Cobalt Catalysts at New Zr 8 (μ 2 -O) 8 (μ 2 -OH) 4 Metal-Organic Framework Nodes for Highly Active Hydrogenation of Alkenes, Imines, Carbonyls, and Heterocycles journal, September 2016

“A posteriori” modification of carbosilane dendrimers and dendrons: their activation in core and branch positions journal, January 2005

Preparation and Molecular and Electronic Structures of Iron(0) Dinitrogen and Silane Complexes and Their Application to Catalytic Hydrogenation and Hydrosilation journal, October 2004

Chemical Substituent Effects on Morphological Transitions in Styrene−Butadiene−Styrene Triblock Copolymer Grafted with Polyhedral Oligomeric Silsesquioxanes journal, March 2006

Peroxide-Catalyzed Addition of Trichlorosilane to 1-Octene journal, January 1947

Silicone waxes—synthesis via hydrosilylation in homo- and heterogeneous systems journal, September 2006

In Situ Determination of the Active Catalyst in Hydrosilylation Reactions Using Highly Reactive Pt(0) Catalyst Precursors journal, April 1999

Poly(vinylsilane): a precursor to silicon carbide. 1. Preparation and characterization journal, May 1991

Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium journal, January 2014

Regioselective Synthesis of Multifunctional Hybrid Polysiloxanes Achieved by Pt−Nanocluster Catalysis journal, April 2005

Synthesis and photocrosslinking of benzyl acrylate substituted polydimethylsiloxanes journal, October 2000

Ir-catalyzed hydrosilylation reaction of allyl acetate with octakis(dimethylsiloxy)octasilsesquioxane and related hydrosilanes journal, February 2014

A Strategy for the Synthesis of Well-Defined Iron Catalysts and Application to Regioselective Diene Hydrosilylation journal, September 2010

Use of functionalized PEG with 4-aminobenzoic acid stabilized platinum nanoparticles as an efficient catalyst for the hydrosilylation of alkenes journal, March 2013

Chiral Bis(pyridylimino)isoindoles: A Highly Modular Class of Pincer Ligands for Enantioselective Catalysis journal, June 2008

Cyanoethylation of Trichlorosilane. II. α-Addition journal, March 1956

Fabrication, characterization, and stability of supported single-atom catalysts journal, January 2017

Selective and Efficient Platinum(0)-Carbene Complexes As Hydrosilylation Catalysts journal, October 2002

Metal–Ligand Complexation through Redox Assembly at Surfaces Characterized by Vibrational Spectroscopy journal, June 2017

The Addition of Silicon Hydrides to Olefinic Double Bonds. Part II. The Use of Group VIII Metal Catalysts journal, February 1957

Alkene Hydrosilylation on Oxide‐Supported Pt‐Ligand Single‐Site Catalysts journal, May 2019

Two- and Three-Electron Oxidation of Single-Site Vanadium Centers at Surfaces by Ligand Design journal, June 2015

First Titanium-Catalyzed a nti -1,4-Hydrosilylation of Dienes journal, November 2005

New fluorinated polysiloxanes containing an ester function in the spacer. I. Synthesis and characterization journal, July 1994

Platinum(II)-bis-(N-heterocyclic carbene) complexes: synthesis, structure and catalytic activity in the hydrosilylation of alkenes journal, August 2011

Catalytic Hydrosilylation of Alkenes by a Ruthenium Silylene Complex. Evidence for a New Hydrosilylation Mechanism journal, November 2003

Redox-active on-surface polymerization of single-site divalent cations from pure metals by a ketone-functionalized phenanthroline journal, February 2015

Diethyl sulfide stabilization of platinum-complex catalysts for hydrosilylation of olefins journal, July 2011

Redox-Active On-Surface Assembly of Metal–Organic Chains with Single-Site Pt(II) journal, July 2014

Expanded ring N-heterocyclic carbene complexes of zero valent platinum dvtms (divinyltetramethyldisiloxane): Highly efficient hydrosilylation catalysts journal, January 2011

Novel liquid crystalline resins based on MQ siloxanes journal, November 2006

Comparative single atom heterogeneous catalysts (SAHCs) on different platforms: a theoretical approach journal, January 2017

Rational Design of a Well-Defined Soluble Calcium Hydride Complex journal, May 2006

New Bis(dialkynyldisiloxane)triplatinum(0) Cluster: Synthesis, Structure, and Catalytic Activity in Olefin-Hydrosilylation Reactions journal, September 2012

Palladium- and platinum-catalyzed coupling reactions of allyloxy aromatics with hydridosilanes and hydridosiloxanes: Novel liquid crystalline/organosilane materials journal, December 1994

Redox Isomeric Surface Structures Are Preferred over Odd-Electron Pt 1+ journal, September 2018

A Facile Preparation and Polymerization of 1,1-Difunctionalized Disiloxanes journal, July 1996

Effect of triarylphosphane ligands on the rhodium-catalyzed hydrosilylation of alkene: Rhodium-catalyzed hydrosilylation of styrene journal, January 2014

Synthesis and structural characterization of a new polysiloxane with second-order nonlinear optical effect journal, January 2004

Thermally initiated cationic polymerization and properties of epoxy siloxane journal, January 2006

Synthesis of platinum single-site centers through metal-ligand self-assembly on powdered metal oxide supports journal, September 2018

Platinum Catalysis Revisited—Unraveling Principles of Catalytic Olefin Hydrosilylation journal, January 2016

Catalytically Active Single-Atom Sites Fabricated from Silver Particles journal, March 2012

Platinum Oxide (PtO 2 ): A Potent Hydrosilylation Catalyst journal, June 2002

Discovering Partially Charged Single-Atom Pt for Enhanced Anti-Markovnikov Alkene Hydrosilylation journal, May 2018

One-Pot Pyrolysis to N-Doped Graphene with High-Density Pt Single Atomic Sites as Heterogeneous Catalyst for Alkene Hydrosilylation journal, September 2018

Highly Active and Selective Platinum(0)-Carbene Complexes. Efficient, Catalytic Hydrosilylation of Functionalised Olefins journal, October 2004

A Stable Single-Site Palladium Catalyst for Hydrogenations journal, July 2015

Platinum(II) Complexes with Thioether-Functionalized Benzimidazolin-2-ylidene Ligands: Synthesis, Structural Characterization, and Application in Hydroelementation Reactions
journal, December 2013

Multi‐electron Reduction Capacity and Multiple Binding Pockets in Metal–Organic Redox Assembly at Surfaces
journal, March 2019

Rhenium-mediated dehydrogenative silylation and highly regioselective hydrosilylation of nitrile substituted olefins
journal, January 2014

The New Tetrafunctional π Acceptor Ligand 3,6-Bis(2′-pyrimidyl)-1,2,4,5-tetrazine (bmtz): Diruthenium Complexes of bmtz and of its 1,4-Dihydro Form
journal, January 1995

Fluorosilicones as High Temperature Elastomers
journal, November 1971

Asymmetric hydrogenation, transfer hydrogenation and hydrosilylation of ketones catalyzed by iron complexes
journal, January 2009

Propylene Hydrogenation and Propane Dehydrogenation by a Single-Site Zn ²⁺ on Silica Catalyst
journal, March 2014

Dense organic catalytic membranes for fine chemical synthesis
journal, February 2000

Single-site SBA-15 supported zirconium catalysts. Synthesis, characterization and toward cyanosilylation reaction
journal, January 2015

Isolated, well-defined organovanadium( iii ) on silica: single-site catalyst for hydrogenation of alkenes and alkynes
journal, January 2017

Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view
journal, July 2011

Platinum nanoparticles in suspension are as efficient as Karstedt's complex for alkene hydrosilylation
journal, January 2015

Single-Site Cobalt Catalysts at New Zr ₈ (μ ₂ -O) ₈ (μ ₂ -OH) ₄ Metal-Organic Framework Nodes for Highly Active Hydrogenation of Alkenes, Imines, Carbonyls, and Heterocycles
journal, September 2016

“A posteriori” modification of carbosilane dendrimers and dendrons: their activation in core and branch positions
journal, January 2005

Preparation and Molecular and Electronic Structures of Iron(0) Dinitrogen and Silane Complexes and Their Application to Catalytic Hydrogenation and Hydrosilation
journal, October 2004

Chemical Substituent Effects on Morphological Transitions in Styrene−Butadiene−Styrene Triblock Copolymer Grafted with Polyhedral Oligomeric Silsesquioxanes
journal, March 2006

Peroxide-Catalyzed Addition of Trichlorosilane to 1-Octene
journal, January 1947

Silicone waxes—synthesis via hydrosilylation in homo- and heterogeneous systems
journal, September 2006

In Situ Determination of the Active Catalyst in Hydrosilylation Reactions Using Highly Reactive Pt(0) Catalyst Precursors
journal, April 1999

Poly(vinylsilane): a precursor to silicon carbide. 1. Preparation and characterization
journal, May 1991

Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium
journal, January 2014

Regioselective Synthesis of Multifunctional Hybrid Polysiloxanes Achieved by Pt−Nanocluster Catalysis
journal, April 2005

Synthesis and photocrosslinking of benzyl acrylate substituted polydimethylsiloxanes
journal, October 2000

Ir-catalyzed hydrosilylation reaction of allyl acetate with octakis(dimethylsiloxy)octasilsesquioxane and related hydrosilanes
journal, February 2014

A Strategy for the Synthesis of Well-Defined Iron Catalysts and Application to Regioselective Diene Hydrosilylation
journal, September 2010

Use of functionalized PEG with 4-aminobenzoic acid stabilized platinum nanoparticles as an efficient catalyst for the hydrosilylation of alkenes
journal, March 2013

Chiral Bis(pyridylimino)isoindoles: A Highly Modular Class of Pincer Ligands for Enantioselective Catalysis
journal, June 2008

Cyanoethylation of Trichlorosilane. II. α-Addition
journal, March 1956

Fabrication, characterization, and stability of supported single-atom catalysts
journal, January 2017

Selective and Efficient Platinum(0)-Carbene Complexes As Hydrosilylation Catalysts
journal, October 2002

Metal–Ligand Complexation through Redox Assembly at Surfaces Characterized by Vibrational Spectroscopy
journal, June 2017

The Addition of Silicon Hydrides to Olefinic Double Bonds. Part II. The Use of Group VIII Metal Catalysts
journal, February 1957

Alkene Hydrosilylation on Oxide‐Supported Pt‐Ligand Single‐Site Catalysts
journal, May 2019

Two- and Three-Electron Oxidation of Single-Site Vanadium Centers at Surfaces by Ligand Design
journal, June 2015

First Titanium-Catalyzed a nti -1,4-Hydrosilylation of Dienes
journal, November 2005

New fluorinated polysiloxanes containing an ester function in the spacer. I. Synthesis and characterization
journal, July 1994

Platinum(II)-bis-(N-heterocyclic carbene) complexes: synthesis, structure and catalytic activity in the hydrosilylation of alkenes
journal, August 2011

Catalytic Hydrosilylation of Alkenes by a Ruthenium Silylene Complex. Evidence for a New Hydrosilylation Mechanism
journal, November 2003

Redox-active on-surface polymerization of single-site divalent cations from pure metals by a ketone-functionalized phenanthroline
journal, February 2015

Diethyl sulfide stabilization of platinum-complex catalysts for hydrosilylation of olefins
journal, July 2011

Redox-Active On-Surface Assembly of Metal–Organic Chains with Single-Site Pt(II)
journal, July 2014

Expanded ring N-heterocyclic carbene complexes of zero valent platinum dvtms (divinyltetramethyldisiloxane): Highly efficient hydrosilylation catalysts
journal, January 2011

Novel liquid crystalline resins based on MQ siloxanes
journal, November 2006

Comparative single atom heterogeneous catalysts (SAHCs) on different platforms: a theoretical approach
journal, January 2017

Rational Design of a Well-Defined Soluble Calcium Hydride Complex
journal, May 2006

New Bis(dialkynyldisiloxane)triplatinum(0) Cluster: Synthesis, Structure, and Catalytic Activity in Olefin-Hydrosilylation Reactions
journal, September 2012

Palladium- and platinum-catalyzed coupling reactions of allyloxy aromatics with hydridosilanes and hydridosiloxanes: Novel liquid crystalline/organosilane materials
journal, December 1994

Redox Isomeric Surface Structures Are Preferred over Odd-Electron Pt ¹⁺
journal, September 2018

A Facile Preparation and Polymerization of 1,1-Difunctionalized Disiloxanes
journal, July 1996

Effect of triarylphosphane ligands on the rhodium-catalyzed hydrosilylation of alkene: Rhodium-catalyzed hydrosilylation of styrene
journal, January 2014

Synthesis and structural characterization of a new polysiloxane with second-order nonlinear optical effect
journal, January 2004

Thermally initiated cationic polymerization and properties of epoxy siloxane
journal, January 2006

Synthesis of platinum single-site centers through metal-ligand self-assembly on powdered metal oxide supports
journal, September 2018

Platinum Catalysis Revisited—Unraveling Principles of Catalytic Olefin Hydrosilylation
journal, January 2016

Catalytically Active Single-Atom Sites Fabricated from Silver Particles
journal, March 2012

Platinum Oxide (PtO ₂ ): A Potent Hydrosilylation Catalyst
journal, June 2002

Discovering Partially Charged Single-Atom Pt for Enhanced Anti-Markovnikov Alkene Hydrosilylation
journal, May 2018

One-Pot Pyrolysis to N-Doped Graphene with High-Density Pt Single Atomic Sites as Heterogeneous Catalyst for Alkene Hydrosilylation
journal, September 2018

Highly Active and Selective Platinum(0)-Carbene Complexes. Efficient, Catalytic Hydrosilylation of Functionalised Olefins
journal, October 2004

A Stable Single-Site Palladium Catalyst for Hydrogenations
journal, July 2015