Multi-metal catalysts and devices and methods of use thereof

Strongin, Daniel R.; Thenuwara, Akila C.

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Title: Multi-metal catalysts and devices and methods of use thereof

Abstract

Novel multi-metal catalysts comprising abundant Earth metals are described herein. Devices comprising the catalysts of the invention are also described.Methods of producing the catalysts are also described herein.Methods of producing hydrogen using the catalysts of the invention are also described herein.

Inventors:: Strongin, Daniel R.; Thenuwara, Akila C.

Issue Date:: 2022-10-04

Research Org.:: Temple Univ., Philadelphia, PA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1986649

Patent Number(s):: 11459664

Application Number:: 16/632,602

Assignee:: Temple University—Of The Commonwealth System of Higher Education (Philadelphia, PA)

DOE Contract Number:: SC0012575

Resource Type:: Patent

Resource Relation:: Patent File Date: 07/20/2018

Country of Publication:: United States

Language:: English

Citation Formats


                    Strongin, Daniel R., and Thenuwara, Akila C. Multi-metal catalysts and devices and methods of use thereof.  United States: N. p., 2022. 
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                    Strongin, Daniel R., & Thenuwara, Akila C. Multi-metal catalysts and devices and methods of use thereof.  United States.

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                    Strongin, Daniel R., and Thenuwara, Akila C. Tue .  
        "Multi-metal catalysts and devices and methods of use thereof".  United States.  https://www.osti.gov/servlets/purl/1986649.

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@article{osti_1986649,

  title        = {Multi-metal catalysts and devices and methods of use thereof},

  author       = {Strongin, Daniel R. and Thenuwara, Akila C.},

  abstractNote = {Novel multi-metal catalysts comprising abundant Earth metals are described herein. Devices comprising the catalysts of the invention are also described.Methods of producing the catalysts are also described herein.Methods of producing hydrogen using the catalysts of the invention are also described herein.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2022},

  month        = {10}

}

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Tian, Jingqi; Liu, Qian; Asiri, Abdullah M.
Journal of the American Chemical Society, Vol. 136, Issue 21
https://doi.org/10.1021/ja503372r

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Title: Multi-metal catalysts and devices and methods of use thereof

Abstract

Citation Formats

Carrier-attached copper foil, laminate, printed-wiring board and method for manufacturing the printed wiring board patent, February 2019

Hydrogen Evolution Reaction Catalysis patent-application, September 2015

Hydrogen electrochemistry on platinum low-index single-crystal surfaces in alkaline solution journal, January 1996

Cobalt-molybdenum-phosphorus alloys: Electroplating and corrosion properties journal, September 2009

Phase and Interface Engineering of Platinum-Nickel Nanowires for Efficient Electrochemical Hydrogen Evolution journal, September 2016

Cobalt-Embedded Nitrogen-Rich Carbon Nanotubes Efficiently Catalyze Hydrogen Evolution Reaction at All pH Values journal, March 2014

Catalytic adsorbent for the capture of arsenic and the selective hydrodesulfurization of gasolines patent, October 2018

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Electro-synthesis of 3D porous hierarchical Ni–Fe phosphate film/Ni foam as a high-efficiency bifunctional electrocatalyst for overall water splitting journal, January 2016

Ni–Mo Nanopowders for Efficient Electrochemical Hydrogen Evolution journal, January 2013

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In-Situ Formed Hydroxide Accelerating Water Dissociation Kinetics on Co 3 N for Hydrogen Production in Alkaline Solution journal, June 2018

Carrier-attached copper foil, laminate, method for manufacturing printed-wiring board and method for manufacturing electronic device patent, November 2018

Materials for solar fuels and chemicals journal, December 2016

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Highly efficient hydrogen evolution from seawater by a low-cost and stable CoMoP@C electrocatalyst superior to Pt/C journal, January 2017

Copper heat dissipation material, carrier-attached copper foil, connector, terminal, laminate, shield material, printed-wiring board, metal processed member, electronic device and method for manufacturing the printed wiring board patent, August 2017

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Suppressing Ion Transfer Enables Versatile Measurements of Electrochemical Surface Area for Intrinsic Activity Comparisons journal, February 2018

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Copper foil provided with carrier, laminate, printed wiring board, and method for fabricating printed wiring board patent, January 2019

Enhancing the Alkaline Hydrogen Evolution Reaction Activity through the Bifunctionality of Ni(OH) 2 /Metal Catalysts journal, November 2012

Amorphous molybdenum sulfide films as catalysts for electrochemical hydrogen production in water journal, January 2011

Electrodeposited Cobalt-Phosphorous-Derived Films as Competent Bifunctional Catalysts for Overall Water Splitting journal, April 2015

Copper heat dissipation material, carrier-attached copper foil, connector, terminal, laminate, shield material, printed-wiring board, metal processed member, electronic device and method for manufacturing the printed wiring board patent, November 2019

Artificial Photosynthesis: Solar Splitting of Water to Hydrogen and Oxygen journal, March 1995

Carrier-attached copper foil, laminate, method for manufacturing printed-wiring board and method for manufacturing electronic device patent, June 2019

Molybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction journal, January 2014

A robust hydrogen evolution catalyst based on crystalline nickel phosphide nanoflakes on three-dimensional graphene/nickel foam: high performance for electrocatalytic hydrogen production from pH 0–14 journal, January 2015

Compositions, electrodes, methods, and systems for water electrolysis and other electrochemical techniques patent, January 2013

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Copper clad laminate, multilayer printed circuit board and their processing method patent, October 1996

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Hydrogen Evolution Reaction in Alkaline Media: Alpha- or Beta-Nickel Hydroxide on the Surface of Platinum? journal, November 2017

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Hydrotreating Catalyst patent, August 1973

Acceleration of global warming due to carbon-cycle feedbacks in a coupled climate model journal, November 2000

Hydrogenative Denitrogenation patent, July 1973

Photoelectrochemical Hydrogen Production in Alkaline Solutions Using Cu 2 O Coated with Earth-Abundant Hydrogen Evolution Catalysts journal, November 2014

Noble metal-free hydrogen evolution catalysts for water splitting journal, January 2015

Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li+-Ni(OH)2-Pt Interfaces journal, December 2011

Universal dependence of hydrogen oxidation and evolution reaction activity of platinum-group metals on pH and hydrogen binding energy journal, March 2016

Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction journal, January 2016

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Mn Doping of CoP Nanosheets Array: An Efficient Electrocatalyst for Hydrogen Evolution Reaction with Enhanced Activity at All pH Values journal, November 2016

Cobalt Intercalated Layered NiFe Double Hydroxides for the Oxygen Evolution Reaction journal, October 2017

Self-Supported Nanoporous Cobalt Phosphide Nanowire Arrays: An Efficient 3D Hydrogen-Evolving Cathode over the Wide Range of pH 0–14 journal, May 2014

Carrier-attached copper foil, laminate, printed-wiring board and method for manufacturing the printed wiring board
patent, February 2019

Hydrogen Evolution Reaction Catalysis
patent-application, September 2015

Hydrogen electrochemistry on platinum low-index single-crystal surfaces in alkaline solution
journal, January 1996

Cobalt-molybdenum-phosphorus alloys: Electroplating and corrosion properties
journal, September 2009

Phase and Interface Engineering of Platinum-Nickel Nanowires for Efficient Electrochemical Hydrogen Evolution
journal, September 2016

Cobalt-Embedded Nitrogen-Rich Carbon Nanotubes Efficiently Catalyze Hydrogen Evolution Reaction at All pH Values
journal, March 2014

Catalytic adsorbent for the capture of arsenic and the selective hydrodesulfurization of gasolines
patent, October 2018

Intercalation of Cobalt into the Interlayer of Birnessite Improves Oxygen Evolution Catalysis
journal, October 2016

Electro-synthesis of 3D porous hierarchical Ni–Fe phosphate film/Ni foam as a high-efficiency bifunctional electrocatalyst for overall water splitting
journal, January 2016

Ni–Mo Nanopowders for Efficient Electrochemical Hydrogen Evolution
journal, January 2013

Copper foil provided with carrier, laminate, printed wiring board, electronic device, and method for fabricating printed wiring board
patent, January 2019

Carrier-attached copper foil, laminate, method for producing printed wiring board, and method for producing electronic device
patent, July 2019

Combining theory and experiment in electrocatalysis: Insights into materials design
journal, January 2017

Nickel Confined in the Interlayer Region of Birnessite: an Active Electrocatalyst for Water Oxidation
journal, May 2016

Self-Supported FeP Nanorod Arrays: A Cost-Effective 3D Hydrogen Evolution Cathode with High Catalytic Activity
journal, October 2014

In-Situ Formed Hydroxide Accelerating Water Dissociation Kinetics on Co ₃ N for Hydrogen Production in Alkaline Solution
journal, June 2018

Carrier-attached copper foil, laminate, method for manufacturing printed-wiring board and method for manufacturing electronic device
patent, November 2018

Materials for solar fuels and chemicals
journal, December 2016

Studies of the Hydrogen Evolution Reaction on Raney Nickel–Molybdenum Electrodes
journal, July 2004

Highly efficient hydrogen evolution from seawater by a low-cost and stable CoMoP@C electrocatalyst superior to Pt/C
journal, January 2017

Copper heat dissipation material, carrier-attached copper foil, connector, terminal, laminate, shield material, printed-wiring board, metal processed member, electronic device and method for manufacturing the printed wiring board
patent, August 2017

Carrier-attached copper foil, laminate, method for producing printed wiring board, and method for producing electronic device
patent, May 2019

Suppressing Ion Transfer Enables Versatile Measurements of Electrochemical Surface Area for Intrinsic Activity Comparisons
journal, February 2018

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journal, January 2006

Copper foil provided with carrier, laminate, printed wiring board, and method for fabricating printed wiring board
patent, January 2019

Enhancing the Alkaline Hydrogen Evolution Reaction Activity through the Bifunctionality of Ni(OH) ₂ /Metal Catalysts
journal, November 2012

Amorphous molybdenum sulfide films as catalysts for electrochemical hydrogen production in water
journal, January 2011

Electrodeposited Cobalt-Phosphorous-Derived Films as Competent Bifunctional Catalysts for Overall Water Splitting
journal, April 2015

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patent, November 2019

Artificial Photosynthesis: Solar Splitting of Water to Hydrogen and Oxygen
journal, March 1995

Carrier-attached copper foil, laminate, method for manufacturing printed-wiring board and method for manufacturing electronic device
patent, June 2019

Molybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction
journal, January 2014

A robust hydrogen evolution catalyst based on crystalline nickel phosphide nanoflakes on three-dimensional graphene/nickel foam: high performance for electrocatalytic hydrogen production from pH 0–14
journal, January 2015

Compositions, electrodes, methods, and systems for water electrolysis and other electrochemical techniques
patent, January 2013

Molybdenum Boride and Carbide Catalyze Hydrogen Evolution in both Acidic and Basic Solutions
journal, November 2012

Copper clad laminate, multilayer printed circuit board and their processing method
patent, October 1996

Bifunctionality and Mechanism of Electrodeposited Nickel-Phosphorous Films for Efficient Overall Water Splitting
journal, December 2015

Homogeneously dispersed multimetal oxygen-evolving catalysts
journal, March 2016

Carrier-attached copper foil, laminate, method for producing printed wiring board, and method for producing electronic device
patent, April 2019

Identification of Highly Active Fe Sites in (Ni,Fe)OOH for Electrocatalytic Water Splitting
journal, January 2015

Hollow Chevrel-Phase NiMo ₃ S ₄ for Hydrogen Evolution in Alkaline Electrolytes
journal, November 2016

Examination of the Bonding in Binary Transition-Metal Monophosphides MP (M = Cr, Mn, Fe, Co) by X-Ray Photoelectron Spectroscopy
journal, November 2005

Electrodeposited Cobalt-Sulfide Catalyst for Electrochemical and Photoelectrochemical Hydrogen Generation from Water
journal, November 2013

Catalyst and its use for the selective hydrodesulfurization of an olefin containing hydrocarbon feedstock
patent, February 2020

Surface-Treated Copper Foil, Copper Foil with Carrier, Substrate, Resin Substrate, Printed Wiring Board, Copper Clad Laminate and Method for Producing Printed Wiring Method
patent-application, June 2016

Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
journal, June 2013

Recent Development in Hydrogen Evolution Reaction Catalysts and Their Practical Implementation
journal, March 2015

Theoretical Investigation of the Activity of Cobalt Oxides for the Electrochemical Oxidation of Water
journal, August 2013

Enhanced hydrogen evolution reaction on hybrids of cobalt phosphide and molybdenum phosphide
journal, March 2017

One-Step Electrodeposition of Co/CoP Film on Ni Foam for Efficient Hydrogen Evolution in Alkaline Solution
journal, October 2016

Engineering water dissociation sites in MoS ₂ nanosheets for accelerated electrocatalytic hydrogen production
journal, January 2016

Trends in activity for the water electrolyser reactions on 3d M(Ni,Co,Fe,Mn) hydr(oxy)oxide catalysts
journal, May 2012

Surface-Treated Copper Foil, Copper Foil with Carrier, Substrate, Resin Substrate, Printed Wiring Board, Copper Clad Laminate and Method for Producing Printed Wiring Board
patent-application, September 2018

Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution
journal, January 2014

Hydrogen Evolution Reaction in Alkaline Media: Alpha- or Beta-Nickel Hydroxide on the Surface of Platinum?
journal, November 2017

Carrier-attached copper foil, laminate, laminate producing method, printed wiring board producing method, and electronic device producing method
patent, July 2019

Efficient hydrogen production on MoNi4 electrocatalysts with fast water dissociation kinetics
journal, May 2017

A mini review on nickel-based electrocatalysts for alkaline hydrogen evolution reaction
journal, December 2015

Powering the planet with solar fuel
journal, April 2009

Copper Foil with Release Layer, Laminated Material, Method for Producing Printed Wiring Board, and Method for Producing Electronic Apparatus
patent-application, December 2017

Hydrotreating Catalyst
patent, August 1973

Acceleration of global warming due to carbon-cycle feedbacks in a coupled climate model
journal, November 2000

Hydrogenative Denitrogenation
patent, July 1973

Photoelectrochemical Hydrogen Production in Alkaline Solutions Using Cu ₂ O Coated with Earth-Abundant Hydrogen Evolution Catalysts
journal, November 2014

Noble metal-free hydrogen evolution catalysts for water splitting
journal, January 2015

Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li+-Ni(OH)2-Pt Interfaces
journal, December 2011

Universal dependence of hydrogen oxidation and evolution reaction activity of platinum-group metals on pH and hydrogen binding energy
journal, March 2016

Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction
journal, January 2016

Copper Foil, Copper Foil for High Frequency Circuit, Carrier-Attached Copper Foil, Carrier-Attached Copper Foil for High Frequency Circuit, Laminate, Method of Manufacturing Printed Wiring Board, and Method of Manufacturing Electronic Device
patent-application, October 2017

Mn Doping of CoP Nanosheets Array: An Efficient Electrocatalyst for Hydrogen Evolution Reaction with Enhanced Activity at All pH Values
journal, November 2016

Cobalt Intercalated Layered NiFe Double Hydroxides for the Oxygen Evolution Reaction
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Self-Supported Nanoporous Cobalt Phosphide Nanowire Arrays: An Efficient 3D Hydrogen-Evolving Cathode over the Wide Range of pH 0–14
journal, May 2014