Enhanced oxygen transfer agent systems for oxidative dehydrogenation of hydrocarbons

Sofranko, John A.; Macwan, Royce; Chung, Elena Y.; Jones, C. Andrew

Advanced Search OptionsAdvanced Search queries use a traditional Term Search. For more info, see our FAQ.

All Fields:

Patent Title:

Abstract:

Assignee:

Inventor(s):

Patent Number:

Patent Classification (CPC):

All Classifications
A - human necessities
A01 - agriculture
A21 - baking
A22 - butchering
A23 - foods or foodstuffs
A24 - tobacco
A41 - wearing apparel
A42 - headwear
A43 - footwear
A44 - haberdashery
A45 - hand or travelling articles
A46 - brushware
A47 - furniture
A61 - medical or veterinary science
A62 - life-saving
A63 - sports
A99 - subject matter not otherwise provided for in this section
B - performing operations
B01 - physical or chemical processes or apparatus in general
B02 - crushing, pulverising, or disintegrating
B03 - separation of solid materials using liquids or using pneumatic tables or jigs
B04 - centrifugal apparatus or machines for carrying-out physical or chemical processes
B05 - spraying or atomising in general
B06 - generating or transmitting mechanical vibrations in general
B07 - separating solids from solids
B08 - cleaning
B09 - disposal of solid waste
B21 - mechanical metal-working without essentially removing material
B22 - casting
B23 - machine tools
B24 - grinding
B25 - hand tools
B26 - hand cutting tools
B27 - working or preserving wood or similar material
B28 - working cement, clay, or stone
B29 - working of plastics
B30 - presses
B31 - making articles of paper, cardboard or material worked in a manner analogous to paper
B32 - layered products
B33 - additive manufacturing technology
B41 - printing
B42 - bookbinding
B43 - writing or drawing implements
B44 - decorative arts
B60 - vehicles in general
B61 - railways
B62 - land vehicles for travelling otherwise than on rails
B63 - ships or other waterborne vessels
B64 - aircraft
B65 - conveying
B66 - hoisting
B67 - opening, closing {or cleaning} bottles, jars or similar containers
B68 - saddlery
B81 - microstructural technology
B82 - nanotechnology
B99 - subject matter not otherwise provided for in this section
C - chemistry
C01 - inorganic chemistry
C02 - treatment of water, waste water, sewage, or sludge
C03 - glass
C04 - cements
C05 - fertilisers
C06 - explosives
C07 - organic chemistry
C08 - organic macromolecular compounds
C09 - dyes
C10 - petroleum, gas or coke industries
C11 - animal or vegetable oils, fats, fatty substances or waxes
C12 - biochemistry
C13 - sugar industry
C14 - skins
C21 - metallurgy of iron
C22 - metallurgy
C23 - coating metallic material
C25 - electrolytic or electrophoretic processes
C30 - crystal growth
C40 - combinatorial technology
C99 - subject matter not otherwise provided for in this section
D - textiles
D01 - natural or man-made threads or fibres
D02 - yarns
D03 - weaving
D04 - braiding
D05 - sewing
D06 - treatment of textiles or the like
D07 - ropes
D10 - indexing scheme associated with sublasses of section d, relating to textiles
D21 - paper-making
D99 - subject matter not otherwise provided for in this section
E - fixed constructions
E01 - construction of roads, railways, or bridges
E02 - hydraulic engineering
E03 - water supply
E04 - building
E05 - locks
E06 - doors, windows, shutters, or roller blinds in general
E21 - earth drilling
E99 - subject matter not otherwise provided for in this section
F - mechanical engineering
F01 - machines or engines in general
F02 - combustion engines
F03 - machines or engines for liquids
F04 - positive - displacement machines for liquids
F05 - indexing schemes relating to engines or pumps in various subclasses of classes f01-f04
F15 - fluid-pressure actuators
F16 - engineering elements and units
F17 - storing or distributing gases or liquids
F21 - lighting
F22 - steam generation
F23 - combustion apparatus
F24 - heating
F25 - refrigeration or cooling
F26 - drying
F27 - furnaces
F28 - heat exchange in general
F41 - weapons
F42 - ammunition
F99 - subject matter not otherwise provided for in this section
G - physics
G01 - measuring
G02 - optics
G03 - photography
G04 - horology
G05 - controlling
G06 - computing
G07 - checking-devices
G08 - signalling
G09 - education
G10 - musical instruments
G11 - information storage
G12 - instrument details
G16 - information and communication technology [ict] specially adapted for specific application fields
G21 - nuclear physics
G99 - subject matter not otherwise provided for in this section
H - electricity
H01 - basic electric elements
H02 - generation
H03 - basic electronic circuitry
H04 - electric communication technique
H05 - electric techniques not otherwise provided for
H99 - subject matter not otherwise provided for in this section
Y - new / cross sectional technologies
Y02 - technologies or applications for mitigation or adaptation against climate change
Y04 - information or communication technologies having an impact on other technology areas
Y10 - technical subjects covered by former uspc

More Options ...

Title: Enhanced oxygen transfer agent systems for oxidative dehydrogenation of hydrocarbons

Abstract

Enhanced oxygen transfer agent systems and methods of use thereof are provided. According to one aspect, a method for producing olefins from a hydrocarbon feed includes the step of contacting a hydrocarbon feed comprised of one or more alkanes with an oxygen transfer agent at a temperature of 350° C. to 1000° C. The oxygen transfer agent includes an oxygen-donating chalcogen agent including at least one of S, Se, or Te and a reducible metal oxide. The chalcogen has an oxidation state greater than +2. A method for producing one or more olefins by partial combustion of a hydrocarbon feed is provided. The method includes partially combusting a hydrocarbon feed comprised of one or more alkanes by contacting the hydrocarbon feed with an oxygen transfer agent comprising CaSO₄ at a temperature of 350° C. to 1000° C. to produce one or more olefins comprising ethylene and coproducing water.

Inventors:: Sofranko, John A.; Macwan, Royce; Chung, Elena Y.; Jones, C. Andrew

Issue Date:: 2022-09-20

Research Org.:: EcoCatalytic, Inc., Weston, MA (United States)

Sponsoring Org.:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

OSTI Identifier:: 1925118

Patent Number(s):: 11447433

Application Number:: 17/145,587

Assignee:: EcoCatalytic Inc. (Weston, MA)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

Show more

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J23/002 - {Mixed oxides other than spinels, e.g. perovskite}
B01J23/34 - Manganese
B01J2523/00 - Constitutive chemical elements of heterogeneous catalysts
B01J2523/11 - Lithium
B01J2523/22 - Magnesium
B01J2523/23 - Calcium
B01J2523/305 - Boron
B01J2523/72 - Manganese
B01J27/053 - Sulfates
B01J27/055 - with alkali metals, copper, gold or silver
B01J27/057 - Selenium or tellurium
B01J35/002 - {Catalysts characterised by their physical properties}
B01J35/023 - {Catalysts characterised by dimensions, e.g. grain size}
B01J37/0036 - {Grinding}
B01J37/08 - Heat treatment {

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C11/04 - Ethylene
C07C2/84 - catalytic
C07C2521/02 - Boron or aluminium
C07C2521/10 - Magnesium
C07C2523/04 - Alkali metals
C07C2523/34 - Manganese
C07C2527/053 - Sulfates or other compounds comprising the anion
C07C5/42 - by dehydrogenation with a hydrogen acceptor
C07C5/46 - with sulfur or a sulfur-containing compound as an acceptor

Show less

DOE Contract Number:: AR0000327

Resource Type:: Patent

Resource Relation:: Patent File Date: 01/11/2021

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Sofranko, John A., Macwan, Royce, Chung, Elena Y., and Jones, C. Andrew. Enhanced oxygen transfer agent systems for oxidative dehydrogenation of hydrocarbons.  United States: N. p., 2022. 
        Web.

Copy to clipboard


                    Sofranko, John A., Macwan, Royce, Chung, Elena Y., & Jones, C. Andrew. Enhanced oxygen transfer agent systems for oxidative dehydrogenation of hydrocarbons.  United States.

Copy to clipboard


                    Sofranko, John A., Macwan, Royce, Chung, Elena Y., and Jones, C. Andrew. Tue .  
        "Enhanced oxygen transfer agent systems for oxidative dehydrogenation of hydrocarbons".  United States.  https://www.osti.gov/servlets/purl/1925118.

Copy to clipboard


                    
@article{osti_1925118,

  title        = {Enhanced oxygen transfer agent systems for oxidative dehydrogenation of hydrocarbons},

  author       = {Sofranko, John A. and Macwan, Royce and Chung, Elena Y. and Jones, C. Andrew},

  abstractNote = {Enhanced oxygen transfer agent systems and methods of use thereof are provided. According to one aspect, a method for producing olefins from a hydrocarbon feed includes the step of contacting a hydrocarbon feed comprised of one or more alkanes with an oxygen transfer agent at a temperature of 350° C. to 1000° C. The oxygen transfer agent includes an oxygen-donating chalcogen agent including at least one of S, Se, or Te and a reducible metal oxide. The chalcogen has an oxidation state greater than +2. A method for producing one or more olefins by partial combustion of a hydrocarbon feed is provided. The method includes partially combusting a hydrocarbon feed comprised of one or more alkanes by contacting the hydrocarbon feed with an oxygen transfer agent comprising CaSO4 at a temperature of 350° C. to 1000° C. to produce one or more olefins comprising ethylene and coproducing water.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2022},

  month        = {9}

}

Copy to clipboard

Patent:

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Methane conversion process
patent, June 1987

Withers, Jr., Howard Paul; Jones, C. Andrew; Leonard, John J.
US Patent Document 4,670,619
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4670619

Sulfur as a selective ‘soft’ oxidant for catalytic methane conversion probed by experiment and theory
journal, December 2012

Zhu, Qingjun; Wegener, Staci L.; Xie, Chao
Nature Chemistry, Vol. 5, Issue 2
https://doi.org/10.1038/nchem.1527

Methane conversion
patent, October 1985

Withers, Jr., Howard Paul; Sofranko, John A.
US Patent Document 4,544,785
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4544785

Effect of hematite addition to CaSO₄ oxygen carrier in chemical looping combustion of coal char
journal, January 2015

Ding, Ning; Zhang, Chengwu; Luo, Cong
RSC Advances, Vol. 5, Issue 69
https://doi.org/10.1039/C5RA06887H

Boron-promoted reducible metal oxides and methods of their use
patent, October 1988

Sofranko, John A.; Gastinger, Robert G.; Jones, C. Andrew
US Patent Document 4,777,313
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4777313

Continuous process for the oxidative coupling of methane to C.sub.2+ hydrocarbons in the presence of catalysts
patent, July 1990

Baerns, Manfred; da Silva Palla Carreiro, Joao A.; Bytyn, Wilfried
US Patent Document 4,939,312
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4939312

Methane conversion
patent, November 1989

Sofranko, John A.
US Patent Document 4,879,427
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4879427

Combined oxydehydrogenation and cracking catalyst for production of olefins
patent-application, September 2003

Ou, John Di-Yi; Risch, Michael A.; Aronson, Blake J.
US Patent Application 10/104322; 20030181325
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030181325

Catalyst materials
patent, September 2014

Gramiccioni, Gary A.; Siemund, Stephan; Chen, Shau-Lin F.
US Patent Document 8,835,346
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8835346

Similar Records in DOE Patents and OSTI.GOV collections:

Enhanced oxygen transfer agent systems for oxidative dehydrogenation of hydrocarbons

Patent Sofranko, John A.; Macwan, Royce; Chung, Emily Y.; ...

Aspects of the invention relate to enhanced oxygen transfer agent systems and methods of use thereof. According to one aspect, a method for producing olefins from a hydrocarbon feed includes the step of contacting a hydrocarbon feed comprised of one or more alkanes with an oxygen transfer agent at a temperature of 350° C. to 1000° C. The oxygen transfer agent comprising an oxygen-donating chalcogen agent comprised of at least one of S, Se, or Te and a reducible metal oxide. The chalcogen having an oxidation state greater than +2. According to another aspect, a method for producing one ormore » « less
Full Text Available
Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons

Patent Kung, Harold H.; Chaar, Mohamed A.

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M.sub.3 (VO.sub.4).sub.2 and MV.sub.2 O.sub.6, M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.
Full Text Available
Ethylene yield in oxidative dehydrogenation of ethane and ethane containing hydrocarbon mixtures

Patent Li, Fanxing; Neal, Luke M.

Methods and systems are provided for oxidative dehydrogenation of a hydrocarbon feed stream to produce a product stream with improved ethylene yield. The methods can include the steps of (i) combining a recycle stream with the feed stream to form a reactor feed stream, (ii) contacting the reactor feed stream with an oxide-based redox catalyst to produce the product stream comprising ethylene and one or more byproducts selected from the group consisting of methane, ethane, other byproducts, and mixtures thereof, and (iii) removing all or a part of the methane and ethane from the product stream to produce the recyclemore » « less
Full Text Available
Composite media for non-oxidative ethane dehydrogenation, and related ethane activation systems and method of processing an ethane-containing stream

Patent Wang, Lucun; Ding, Dong; Zhang, Yunya; ...

A composite media for non-oxidative C₂H₆ dehydrogenation comprises an aluminosilicate zeolite matrix, and an EDH catalyst on one or more of an external surface of the aluminosilicate zeolite matrix and internal surfaces within pores of the aluminosilicate zeolite matrix. The EDH catalyst comprises one or more of Fe, Zn, Pt, Ga, alloys thereof, and oxides thereof. A C₂H₆ activation system, and a method of processing a C₂H₆-containing stream are also described.
Full Text Available
Selective thermal oxidation of hydrocarbons in zeolites by oxygen

Patent Frei, Heinz [Berkeley, CA]; Blatter, Fritz [Basel, CH]; Sun, Hai [Saint Charles, MO]

A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.
Full Text Available

Similar Records

Title: Enhanced oxygen transfer agent systems for oxidative dehydrogenation of hydrocarbons

Abstract

Citation Formats

Methane conversion process patent, June 1987

Sulfur as a selective ‘soft’ oxidant for catalytic methane conversion probed by experiment and theory journal, December 2012

Methane conversion patent, October 1985

Effect of hematite addition to CaSO4 oxygen carrier in chemical looping combustion of coal char journal, January 2015

Boron-promoted reducible metal oxides and methods of their use patent, October 1988

Continuous process for the oxidative coupling of methane to C.sub.2+ hydrocarbons in the presence of catalysts patent, July 1990

Methane conversion patent, November 1989

Combined oxydehydrogenation and cracking catalyst for production of olefins patent-application, September 2003

Catalyst materials patent, September 2014

Methane conversion process
patent, June 1987

Sulfur as a selective ‘soft’ oxidant for catalytic methane conversion probed by experiment and theory
journal, December 2012

Methane conversion
patent, October 1985

Effect of hematite addition to CaSO₄ oxygen carrier in chemical looping combustion of coal char
journal, January 2015

Boron-promoted reducible metal oxides and methods of their use
patent, October 1988

Continuous process for the oxidative coupling of methane to C.sub.2+ hydrocarbons in the presence of catalysts
patent, July 1990

Methane conversion
patent, November 1989

Combined oxydehydrogenation and cracking catalyst for production of olefins
patent-application, September 2003

Catalyst materials
patent, September 2014