Three-dimensional rechargeable battery with solid-state electrolyte
Abstract
A scaffold of an electrolyte is fabricated in polymer material using 3D printing techniques. A thin layer of solid electrolyte is deposited on the scaffold followed by burning off the polymer. This leaves behind a 3D foam-like solid electrolyte with two distinct non-overlapping volumes. Lithium followed by a conductive layer (for anode) is then deposited through one volume on the first surface whereas a porous or non-porous conductive layer is deposited on the opposite surface through the second volume. The non-porous conductive layer on the second surface is made porous by a selective timed etch.
- Inventors:
- Issue Date:
- Research Org.:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1925112
- Patent Number(s):
- 11444347
- Application Number:
- 16/651,777
- Assignee:
- Lawrence Livermore National Security, LLC (Livermore, CA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B33 - ADDITIVE MANUFACTURING TECHNOLOGY B33Y - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- DOE Contract Number:
- AC52-07NA27344
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 02/28/2018
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Saha, Sourabh K., and Panas, Robert M. Three-dimensional rechargeable battery with solid-state electrolyte. United States: N. p., 2022.
Web.
Saha, Sourabh K., & Panas, Robert M. Three-dimensional rechargeable battery with solid-state electrolyte. United States.
Saha, Sourabh K., and Panas, Robert M. Tue .
"Three-dimensional rechargeable battery with solid-state electrolyte". United States. https://www.osti.gov/servlets/purl/1925112.
@article{osti_1925112,
title = {Three-dimensional rechargeable battery with solid-state electrolyte},
author = {Saha, Sourabh K. and Panas, Robert M.},
abstractNote = {A scaffold of an electrolyte is fabricated in polymer material using 3D printing techniques. A thin layer of solid electrolyte is deposited on the scaffold followed by burning off the polymer. This leaves behind a 3D foam-like solid electrolyte with two distinct non-overlapping volumes. Lithium followed by a conductive layer (for anode) is then deposited through one volume on the first surface whereas a porous or non-porous conductive layer is deposited on the opposite surface through the second volume. The non-porous conductive layer on the second surface is made porous by a selective timed etch.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2022},
month = {9}
}
Works referenced in this record:
A Solid-State, Rechargeable, Long Cycle Life Lithium–Air Battery
journal, January 2010
- Kumar, Binod; Kumar, Jitendra; Leese, Robert
- Journal of The Electrochemical Society, Vol. 157, Issue 1
Lithium Air Battery
patent-application, April 2015
- Ma, Sang-bok; Lee, Dong-joon; Im, Dong-min
- US Patent Application 14/291,154; 2015/0104720 Al
Lithium-air cell incorporating lithium aluminum germanium phosphate cathode
patent, August 2015
- Kumar, Binod; Kumar, Jitendra
- US Patent Document 9,099,758
Method for Producing Solid Electrolyte Battery
patent-application, August 2012
- Kitaura, Masayuki; Kawaoka, Hirokazu
- US Patent Application 13/505,133; 2012/0216394 Al
Electrochemical performance and reaction mechanism of all-solid-state lithium–air batteries composed of lithium, Li1+xAlyGe2−y(PO4)3 solid electrolyte and carbon nanotube air electrode
journal, January 2012
- Kitaura, Hirokazu; Zhou, Haoshen
- Energy & Environmental Science, Vol. 5, Issue 10
Lithium-air cells incorporating solid electrolytes having enhanced ionic transport and catalytic activity
patent, November 2015
- Kumar, Binod; Kumar, Jitendra
- US Patent Document 9,178,255
Lithium−Air Battery: Promise and Challenges
journal, June 2010
- Girishkumar, G.; McCloskey, B.; Luntz, A. C.
- The Journal of Physical Chemistry Letters, Vol. 1, Issue 14
Superior Rechargeability and Efficiency of Lithium-Oxygen Batteries: Hierarchical Air Electrode Architecture Combined with a Soluble Catalyst
journal, March 2014
- Lim, Hee-Dae; Song, Hyelynn; Kim, Jinsoo
- Angewandte Chemie International Edition, Vol. 53, Issue 15
A critical review on lithium–air battery electrolytes
journal, January 2014
- Balaish, Moran; Kraytsberg, Alexander; Ein-Eli, Yair
- Physical Chemistry Chemical Physics, Vol. 16, Issue 7
The pursuit of rechargeable solid-state Li–air batteries
journal, January 2013
- Li, Fujun; Kitaura, Hirokazu; Zhou, Haoshen
- Energy & Environmental Science, Vol. 6, Issue 8
A review of high energy density lithium–air battery technology
journal, August 2013
- Rahman, Md. Arafat; Wang, Xiaojian; Wen, Cuie
- Journal of Applied Electrochemistry, Vol. 44, Issue 1
Composite lithium metal anode by melt infusion of lithium into a 3D conducting scaffold with lithiophilic coating
journal, February 2016
- Liang, Zheng; Lin, Dingchang; Zhao, Jie
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 11
From Lithium-Oxygen to Lithium-Air Batteries: Challenges and Opportunities
journal, February 2016
- Geng, Dongsheng; Ding, Ning; Hor, T. S. Andy
- Advanced Energy Materials, Vol. 6, Issue 9