Title: Electrochemical cells with ionic sequestration provided by porous separators

Abstract

Provided are electrochemical cells including separators permeable to some materials and impermeable to other materials in electrolytes. Also provide are methods of forming such separators. The selective permeability of a separator is achieved by its specific pore diameter and a narrow distribution of this diameter. Specifically, a species responsible for ion transport in an electrochemical cell are allowed to pass through the separator, while another species is blocked thereby preventing degradation of the cell. For example, a species containing lithium ions is allowed to pass in rechargeable cells, while one or more species containing transition metals are blocked. In some embodiments, a separator may include a membrane layer with at least 90% of pores of this having a diameter of between about 0.1 nanometers and 1.0 nanometer. The membrane layer may be a standalone layer or supported by a membrane support.

Inventors:

Frischmann, Peter David; Helms, Brett Anthony; Alessandro, Jon-Michael

Issue Date:

2022-07-19

Research Org.:

Sepion Technologies, Inc., Emeryville, CA (United States)

Sponsoring Org.:

USDOE

OSTI Identifier:

1924921

Patent Number(s):

11394082

Application Number:

16/335,219

Assignee:

Sepion Technologies, Inc. (Emeryville, CA)

Patent Classifications (CPCs):

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

Show more

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

H01M10/052 - Li-accumulators
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M4/505 - of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M4/587 - for inserting or intercalating light metals

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

Y02E60/10 - Energy storage

Show less

DOE Contract Number:  

SC0015119

Resource Type:

Patent

Resource Relation:

Patent File Date: 09/28/2017

Country of Publication:

United States

Language:

English

Subject:

25 ENERGY STORAGE; 33 ADVANCED PROPULSION SYSTEMS