Methods for producing perovskite halide films
Abstract
An aspect of the present disclosure is a method that includes exchanging at least a portion of a first cation of a perovskite solid with a second cation, where the exchanging is performed by exposing the perovskite solid to a precursor of the second cation, such that the precursor of the second cation oxidizes to form the second cation and the first cation reduces to form a precursor of the first cation.
- Inventors:
- Issue Date:
- Research Org.:
- National Renewable Energy Laboratory (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1924893
- Patent Number(s):
- 11387420
- Application Number:
- 16/514,344
- Assignee:
- Alliance for Sustainable Energy, LLC (Golden, CO); Brown University (Providence, RI)
- Patent Classifications (CPCs):
-
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AC36-08GO28308
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 07/17/2019
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 14 SOLAR ENERGY
Citation Formats
Zhu, Kai, Yang, Mengjin, Zhou, Yuanyuan, and Padture, Nitin P. Methods for producing perovskite halide films. United States: N. p., 2022.
Web.
Zhu, Kai, Yang, Mengjin, Zhou, Yuanyuan, & Padture, Nitin P. Methods for producing perovskite halide films. United States.
Zhu, Kai, Yang, Mengjin, Zhou, Yuanyuan, and Padture, Nitin P. Tue .
"Methods for producing perovskite halide films". United States. https://www.osti.gov/servlets/purl/1924893.
@article{osti_1924893,
title = {Methods for producing perovskite halide films},
author = {Zhu, Kai and Yang, Mengjin and Zhou, Yuanyuan and Padture, Nitin P.},
abstractNote = {An aspect of the present disclosure is a method that includes exchanging at least a portion of a first cation of a perovskite solid with a second cation, where the exchanging is performed by exposing the perovskite solid to a precursor of the second cation, such that the precursor of the second cation oxidizes to form the second cation and the first cation reduces to form a precursor of the first cation.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2022},
month = {7}
}
Works referenced in this record:
Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells
journal, January 2014
- Eperon, Giles E.; Stranks, Samuel D.; Menelaou, Christopher
- Energy & Environmental Science, Vol. 7, Issue 3
Cation exchange for thin film lead iodide perovskite interconversion
journal, January 2016
- Eperon, Giles E.; Beck, Clara E.; Snaith, Henry J.
- Materials Horizons, Vol. 3, Issue 1
NH 2 CH═NH 2 PbI 3 : An Alternative Organolead Iodide Perovskite Sensitizer for Mesoscopic Solar Cells
journal, January 2014
- Pang, Shuping; Hu, Hao; Zhang, Jiliang
- Chemistry of Materials, Vol. 26, Issue 3
Transformative Evolution of Organolead Triiodide Perovskite Thin Films from Strong Room-Temperature Solid–Gas Interaction between HPbI 3 -CH 3 NH 2 Precursor Pair
journal, January 2016
- Pang, Shuping; Zhou, Yuanyuan; Wang, Zaiwei
- Journal of the American Chemical Society, Vol. 138, Issue 3
Impact of the organic halide salt on final perovskite composition for photovoltaic applications
journal, August 2014
- Moore, David T.; Sai, Hiroaki; Wee Tan, Kwan
- APL Materials, Vol. 2, Issue 8
High-performance photovoltaic perovskite layers fabricated through intramolecular exchange
journal, May 2015
- Yang, W. S.; Noh, J. H.; Jeon, N. J.
- Science, Vol. 348, Issue 6240
Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals
journal, January 2015
- Shi, D.; Adinolfi, V.; Comin, R.
- Science, Vol. 347, Issue 6221
The fabrication of formamidinium lead iodide perovskite thin films via organic cation exchange
journal, January 2016
- Zhou, Zhongmin; Pang, Shuping; Ji, Fuxiang
- Chemical Communications, Vol. 52, Issue 19
Perovskite-Containing Solar Cells Comprising Fulleropyrrolidine Interlayers
patent-application, May 2017
- Russell, Thomas P.; Emrick, Todd; Liu, Yao
- US Patent Application 15/335918; 20170133163