DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: High energy density redox flow device

Abstract

Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

Inventors:
; ; ;
Issue Date:
Research Org.:
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1892973
Patent Number(s):
11342567
Application Number:
16/252,088
Assignee:
Massachusetts Institute of Technology (Cambridge, MA)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B60 - VEHICLES IN GENERAL B60L - PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
DOE Contract Number:  
FC26-05NT42403
Resource Type:
Patent
Resource Relation:
Patent File Date: 01/18/2019
Country of Publication:
United States
Language:
English

Citation Formats

Chiang, Yet-Ming, Carter, William Craig, Duduta, Mihai, and Limthongkul, Pimpa. High energy density redox flow device. United States: N. p., 2022. Web.
Chiang, Yet-Ming, Carter, William Craig, Duduta, Mihai, & Limthongkul, Pimpa. High energy density redox flow device. United States.
Chiang, Yet-Ming, Carter, William Craig, Duduta, Mihai, and Limthongkul, Pimpa. Tue . "High energy density redox flow device". United States. https://www.osti.gov/servlets/purl/1892973.
@article{osti_1892973,
title = {High energy density redox flow device},
author = {Chiang, Yet-Ming and Carter, William Craig and Duduta, Mihai and Limthongkul, Pimpa},
abstractNote = {Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue May 24 00:00:00 EDT 2022},
month = {Tue May 24 00:00:00 EDT 2022}
}

Works referenced in this record:

Semi-solid electrode cell having a porous current collector and methods of manufacture
patent, November 2017


Semi-solid electrodes having high rate capability
patent, July 2016


Fuel system using redox flow battery
patent, July 2014


Reversible Conversion Reactions with Lithium in Bismuth Oxyfluoride Nanocomposites
journal, January 2006


Fuel-cell based power source having internal series redundancy
patent-application, November 2003


Perfluorinated membranes and improved electrolytes for redox cells and batteries
patent, September 2013


Energy Storage Modeling And Control
patent-application, February 2014


Damage Tolerant Batteries
patent-application, October 2015


Semi-solid electrodes with a polymer additive
patent, March 2021


Thin lithium battery with slurry cathode
patent, August 2001


Fuel cell with proton conducting membrane
patent-application, October 2008


Fuel system using redox flow battery
patent, February 2017


Galvanic Electrochemical Cells Utilizing Taylor Vortex Flows
patent-application, January 2012


Electrochemical Slurry Compositions and Methods for Preparing the Same
patent-application, December 2013


Systems and methods for series battery charging
patent, February 2021


Semi-Solid Electrodes Having High Rate Capability
patent-application, June 2014


Electrochemical Slurry Compositions and Methods for Preparing the Same
patent-application, June 2017


Optimizing layout of obstacles for enhanced mixing in microchannels
journal, September 2002


Electrochemical behavior of LiCoO2 as aqueous lithium-ion battery electrodes
journal, February 2009


Mechanical Systems and Methods for Providing Edge Support and Protection in Semi-Solid Electrodes
patent-application, November 2016


Battery Cell
patent, November 1969


Redox Fuel Cell
patent, November 1970


Multiple Cell Redox Battery
patent, November 1970


Damage tolerant batteries
patent, March 2019


Electrically recharged battery employing a packed/spouted bed metal particle electrode
patent, August 1995


Limited rechargeable lithium battery based on a cathode slurry
patent, August 1998


Systems and methods for series battery charging
patent, December 2018


Electronically conductive phospho-olivines as lithium storage electrodes
journal, September 2002


Module for an aqueous battery system
patent, February 1997


Continuous and Semi-Continuous Methods of Semi-Solid Electrode and Battery Manufacturing
patent-application, January 2020


Fuel cell
patent, March 1982


Electrochemical cells having semi-solid electrodes and methods of manufacturing the same
patent, January 2021


Investigation of the Lithiation and Delithiation Conversion Mechanisms of Bismuth Fluoride Nanocomposites
journal, January 2006


Four-way valve for battery circulation system
patent-application, December 2001


High Energy Density Redox Flow Device
patent-application, February 2010


Redox flow cells for energy conversion
journal, September 2006


Electrochemical Cells Having Semi-Solid Electrodes and Methods of Manufacturing the Same
patent-application, May 2016


Battery with bifunctional electrolyte
patent-application, March 2006


Stationary semi-solid battery module and method of manufacture
patent, February 2020


Curved Battery Container
patent-application, May 2015


Lithium-ion secondary battery and manufacturing method thereof
patent-application, January 2007


Spill and leak containment system for zinc-bromine battery
patent, July 2001


Electrochemical cells and methods of manufacturing the same
patent, July 2016


Overcharge Protection of Batteries Using Current Interrupt Devices
patent-application, October 2018


Electroconversion cell
patent, December 2002


Semi-solid electrodes having high rate capability
patent, November 2019


Process for Converting Chemical Energy Into Electrical Energy
patent, December 1967


Fuel System Using Redox Flow Battery
patent-application, September 2016


Electric devices with improved bipolar electrode
patent, April 2006


Fuel cell with proton conducting membrane
patent, December 2002


Electrolyte for redox flow battery, and redox flow battery
patent-application, September 2004


Virus-Enabled Synthesis and Assembly of Nanowires for Lithium Ion Battery Electrodes
journal, May 2006


Semi-solid Electrodes Having High Rate Capability
patent-application, June 2018


Efficient Vanadium Redox Flow Cell
journal, January 1987


Micromixer Using Integrated Three-Dimensional Porous Structure
patent-application, April 2008


EELS Spectroscopy of Iron Fluorides and FeFx/C Nanocomposite Electrodes Used in Li-Ion Batteries
journal, February 2007


Short-circuit Protection of Battery Cells Using Fuses
patent-application, February 2019


Electrochemical cells and methods of manufacturing the same
patent, November 2017


Semi-solid electrodes having high rate capability
patent, March 2015


Pouch-Type Flexible Film Battery and Method of Manufacturing the Same
patent-application, March 2012


The Electrical Properties of Graphite
journal, March 1953


Systems and Methods for Infusion Mixing a Slurry-Based Electrode
patent-application, July 2017


Alkaline cell with semisolid cathode
patent, March 2001


Systems and Methods for Series Battery Charging
patent-application, October 2019


Catalyst surfaces for the chromous/chromic redox couple
patent, March 1980


High energy density redox flow device
patent, October 2017


Aqueous borohydride compositions
patent, March 2005


Dry particle based electro-chemical device and methods of making same
patent-application, December 2005


Rechargeable batteries with organic radical cathodes
journal, June 2002


Dual Electrochemical Cells, Systems, and Methods of Manufacturing the Same
patent-application, December 2020


Asymmetric battery having a semi-solid cathode and high energy density anode
patent, November 2017


Semi-Solid Electrodes Having High Rate Capability
patent-application, February 2016


Semi-Solid Electrodes Having High Rate Capability
patent-application, February 2016


Stationary semi-solid battery module and method of manufacture
patent, December 2015


Electrochemical Cells and Methods of Manufacturing the Same
patent-application, August 2018


Stationary Semi-Solid Battery Module And Method Of Manufacture
patent-application, March 2013


Redox gel battery
patent, April 2004


Batteries And Electrodes For Use Thereof
patent-application, August 2009


Fabricating Genetically Engineered High-Power Lithium Ion Batteries Using Multiple Virus Genes
journal, April 2009


Electrochemical Cell Having a Coiled Core
patent-application, June 2009


Ca Electrochemical cell
patent, July 1984


Short-circuit protection of battery cells using fuses
patent, December 2020


Intercalation anode protection for cells with dissolved lithium polysulfides
patent-application, August 2006


Organic radical battery: nitroxide polymers as a cathode-active material
journal, November 2004


Lithium ion secondary battery
patent-application, November 2004


Battery recharging device and method and an automatic battery detection system and method therefor
patent-application, April 2001


Battery with gelled electrolyte
patent, November 2007


Redox Battery
patent-application, August 2010


Energy analysis of batteries in photovoltaic systems. Part II: Energy return factors and overall battery efficiencies
journal, July 2005


Electroconversion cell
patent, September 1998


Energy analysis of batteries in photovoltaic systems. Part I: Performance and energy requirements
journal, July 2005


Electrochemical technology for environmental treatment and clean energy conversion
journal, January 2001


Electrochemical methods for recovery of ascorbic acid
patent, December 1999


Semi-Solid Electrodes Having High Rate Capability
patent-application, October 2015


Methods for Electrochemical Cell Remediation
patent-application, December 2016


Semi-solid electrodes having high rate capability
patent, November 2017


Electrochemical Cells and Methods of Manufacturing the Same
patent-application, March 2017


Semi-Solid Lithium Rechargeable Flow Battery
journal, May 2011


Membrane-separated, bipolar multicell electrochemical reactor
patent, April 2003


Semi-solid electrodes having high rate capability
patent, November 2017


Metal halide redox flow battery
patent-application, November 2005


Electrically rechargeable REDOX flow cell
patent, December 1976


Fuel system using redox flow battery
patent, March 2016


Method of electrode reconditioning
patent, July 1997


Conductive lithium storage electrode
patent, March 2008


Porous Spacers for Electrochemical Cells
patent-application, August 2017


Hybrid Electrochemical Generator with a Soluble Anode
patent-application, June 2010


Capacitor having non-conductive plastic frames
patent, February 1997


Centrally Located Spacers for Electrochemical Cells
patent-application, August 2017


Vanadium/polyhalide redox flow battery
patent-application, November 2004


Single Pouch Battery Cells and Methods of Manufacture
patent-application, October 2019


Asymmetric Battery Having a Semi-solid Cathode and High Energy Density Anode
patent-application, June 2018


High energy density redox flow device
patent, April 2017


Electrolyte circulation type secondary battery operating method
patent, October 1991


Method Of Operating Fuel Cell
patent-application, August 2003


Battery
patent-application, August 2005


A study of the Fe(III)/Fe(II)–triethanolamine complex redox couple for redox flow battery application
journal, May 2006


Electrochemical Cell Including Selectively Permeable Membranes, Systems and Methods of Manufacturing the Same
patent-application, November 2020


Preparation and electrochemical performance of Ag doped Li4Ti5O12
journal, November 2004


Development and Advances of a V-Flow FC Stack for FCX Clarity
journal, April 2009


Zinc-bromine battery with non-flowing electrolyte
patent, January 1997


Closed battery module
patent, November 2003


Current Interrupt Device Based on Thermal Activation of Frangible Glass Bulb
patent-application, December 2019


Electrolytic process and apparatus
patent-application, November 2005


Perfluorinated Membranes and Improved Electrolytes for Redox Cells and Batteries
patent-application, November 2008


Electrochemical cell
patent, July 1988


Single pouch battery cells and methods of manufacture
patent, January 2019


Semi-Solid Electrodes With Gel Polymer Additive
patent-application, January 2015


Metal/acid ion permeable membrane fuel cell
patent, April 1984


Electrochemical cell
patent, October 1983


Solution Redox Couples for Electrochemical Energy Storage
journal, January 1981


Systems and Methods for Improving Safety Features in Electrochemical Cells
patent-application, August 2018


Systems and Methods for Series Battery Charging
patent-application, August 2020


Lanthanide batteries
patent, August 2007


Electrochemical Cells and Methods of Manufacturing the Same
patent-application, July 2020


Aqueous Polysulfide-Based Electrochemical Cell
patent-application, January 2020


Semi-solid electrodes having high rate capability
patent, June 2016


Electrochemical Energy Storage Device Having a Reservoir for an Additive
patent-application, July 2010


Stationary, Fluid Redox Electrode
patent-application, June 2012


Regenerative fuel cell with ph control
patent-application, August 2004


Effect of Electrode Parameters on LiFePO4 Cathodes
journal, January 2006


Electrochemical slurry compositions and methods for preparing the same
patent, November 2016


Fluidic distribution system and related methods
patent, March 2012


Semi-Solid Electrodes Having High Rate Capability
patent-application, May 2020


Fuel System Using Redox Flow Battery
patent-application, December 2010


Electrochemistry of Tris(β-diketonato)ruthenium(III) Complexes at Platinum Electrodes in Nonaqueous Solutions and Substituent Effects on Their Reversible Half-Wave Potentials
journal, March 1989


Mesoporous network electrode for electrochemical cell
patent-application, July 2004


Asymmetric Battery Having a Semi-Solid Cathode and High Energy Density Anode
patent-application,  


Pre-Lithiation of Electrode Materials in a Semi-Solid Electrode
patent-application, April 2020


Compact energy storage system
patent, March 1997


Battery with bifunctional electrolyte
patent, January 2006


Electrochemical cells and methods of manufacturing the same
patent, November 2015


High energy density redox flow device
patent, March 2019


Studies on promising cell performance with H2SO4 as the catholyte for electrogeneration of Ag2+ from Ag+ in HNO3 anolyte in mediated electrochemical oxidation process
journal, July 2008


Novel vanadium halide redox flow battery
patent-application, August 2006


Method of Manufacturing Lithium Battery
patent-application, January 2014


Fuel System Using Redox Flow Battery
patent-application, May 2015


Fuel Cell
patent, December 1970


Electrochemical cells and methods of manufacturing the same
patent, February 2020


Semi-Solid Filled Battery And Method Of Manufacture
patent-application, January 2014


Structure and Electrochemistry of Carbon-Metal Fluoride Nanocomposites Fabricated by Solid-State Redox Conversion Reaction
journal, January 2005


Lithium secondary battery
patent, January 1998


Secondary battery with autolytic dendrites
patent, May 2007


Colloidal battery
patent, December 2005


Asymmetric Battery Having A Semi-Solid Cathode And High Energy Density Anode
patent-application, October 2014


Fluoride based electrode materials for advanced energy storage devices
journal, April 2007


Chromium redox couples for application to redox flow batteries
journal, December 2002


Catalytic converter system for diesel engines
patent, August 2008


High efficiency semi-fuel cell incorporating an ion exchange membrane
patent, April 2009


Metal/acid ion permeable membrane fuel cell
patent, October 1982


Chrome-halogen energy storage device and system
patent, January 1983


Optimum Electronic and Ionic Conductivity Ratios in Semi-Solid Electrodes
patent-application, January 2017


Carbon-Metal Fluoride Nanocomposites: Structure and Electrochemistry of FeF3 : C
journal, January 2003


Semi-solid electrodes having high rate capability
patent, November 2015


Stationary Semi-Solid Battery Module and Method of Manufacture
patent-application, June 2016


Improved fuel utilization in microfluidic fuel cells: A computational study
journal, April 2005


Metal-halogen energy storage device and system
patent, November 1988


Fuel cell with proton conducting membrane and with improved water and fuel management
patent-application, October 2004


Battery Electrodes And Methods Of Manufacture
patent-application, December 2010


Semi-Solid Electrodes Having High Rate Capability
patent-application, February 2017


Electroactive material for charge transport
patent, January 2012


Asymmetric Battery Having a Semi-Solid Cathode and High Energy Density Anode
patent-application, January 2017


Stationary Semi-Solid Battery Module and Method of Manufacture
patent-application, October 2020


Pre-Lithiation of Electrode Materials in a Semi-Solid Electrode
patent-application, May 2016


Battery circulation system with improved four-way valve
patent, June 2001


Mixed electrolyte battery
patent, July 2009


Nonaqueous electrolyte secondary battery
patent, January 2003


Thin-film cathode for 3-dimensional microbattery and method for preparing such cathode
patent-application, February 2006


Electrolytic Method To Make Alkali Alcoholates Using Ion Conducting Alkali Electrolyte/Seperator
patent-application, June 2008


Current Interrupt Devices Using Shape Memory Materials
patent-application, January 2019


Asymmetric battery having a semi-solid cathode and high energy density anode
patent, December 2019


Iron Oxyfluorides as High Capacity Cathode Materials for Lithium Batteries
journal, January 2009


Systems and Methods for Series Battery Charging
patent-application, April 2016


Structure and Electrochemistry of Copper Fluoride Nanocomposites Utilizing Mixed Conducting Matrices
journal, August 2007


Single Pouch Battery Cells and Methods of Manufacture
patent-application, January 2017


Asymmetric battery having a semi-solid cathode and high energy density anode
patent, September 2016


High Energy Density Redox Flow Device
patent-application, February 2018


Integrated fuel cell stack shunt current prevention arrangement
patent, January 1992


Gels as battery separators for soluble electrode cells
patent, April 1977


Electrochemical Cells Including Selectively Permeable Membranes, Systems and Methods of Manufacturing the Same
patent-application, November 2019


Semi-solid electrodes with gel polymer additive
patent, November 2018


Load leveling battery and methods therefor
patent, September 2007


Development of redox flow batteries. A historical bibliography
journal, September 1989


Electrochemical cell
patent, March 1982


Magnesium-solution phase catholyte semi-fuel cell for undersea vehicles
journal, October 2004


Semi-Solid Electrodes Having High Rate Capability
patent-application, February 2017


Zirconium carbide as an electrocatalyst for the chromous/chromic REDOX couple
patent, May 1983


Fuel cell with proton conducting membrane
patent-application, May 2003


Enhancements in the Electron-Transfer Kinetics of Uranium-Based Redox Couples Induced by Tetraketone Ligands with Potential Chelate Effect
journal, December 2007


Liquid-circulating battery
patent, June 1998


Electrochemical Cells and Methods of Manufacturing the Same
patent-application, June 2015


Short-circuit protection of battery cells using fuses
patent-application, March 2021


Apparatus and method for regenerating electrolyte of a redox flow battery
patent, September 1990


Magnetic slurry fueled battery system
patent, February 1999


Methods for electrochemical cell remediation
patent, September 2019


High-performance lithium battery anodes using silicon nanowires
journal, December 2007


Vanadium/polyhalide redox flow battery
patent, January 2008


Vanadium redox battery electrolyte
patent-application, December 2004


Rechargeable positive electrodes
patent, April 2002


Systems and methods for series battery charging
patent, March 2020


Structure, ionic conduction, and phase transformations in lithium titanate Li4Ti5O12
journal, November 2003


Lithium cells
patent, June 1982


Electrochemical cells having semi-solid electrodes and methods of manufacturing the same
patent, April 2020


Assessment of the Degree of Mixedness of Filled Polymers
journal, September 2005


Semi-solid electrodes with porous current collectors and methods of manufacture
patent, October 2018


Rechargeable Lithium Batteries with Aqueous Electrolytes
journal, May 1994


Overcharge protection of batteries using current interrupt devices
patent, September 2020


Semi-Solid Electrode Cell Having A Porous Current Collector And Methods Of Manufacture
patent-application, March 2013


Vanadium redox flow battery electrolyte-use amorphous solid composition
patent-application, December 2005


Methods for Electrochemical Cell Remediation
patent-application, February 2020


Electrochemical Cells having Semi-Solid Electrodes and Methods of Manufacturing the Same
patent-application, October 2020


Long cycle-life alkali metal battery
patent, March 2001


Semi-Solid Electrodes with a Polymer Additive
patent-application, August 2019


Thin lithium battery with slurry cathode
patent, April 2003


Organic fuel cell methods and apparatus
patent-application, September 2006


Ion conductive matrixes and their use
patent, November 2004


Liquid flow in microchannels: experimental observations and computational analyses of microfluidics effects
journal, May 2003


Semi-Solid Electrodes with Porous Current Collectors and Methods of Manufacture
patent-application, October 2016


High Energy-density Composition-gradient Electrodes and Methods of Making the Same
patent-application, November 2019


Carbon Metal Fluoride Nanocomposites: High-Capacity Reversible Metal Fluoride Conversion Materials as Rechargeable Positive Electrodes for Li Batteries
journal, January 2003


Bismuth Fluoride Nanocomposite as a Positive Electrode Material for Rechargeable Lithium Batteries
journal, January 2005


Energy Transfer Using Electrochemically Isolated Fluids
patent-application, November 2011


Electrochemical cell with a liquid negative electrode
patent, February 1984


Redox reaction in 1-ethyl-3-methylimidazolium–iron chlorides molten salt system for battery application
journal, July 2002


Redox flow battery
patent, July 2004


Metal-halogen secondary battery
patent, September 1986


Fuel cell with proton conducting membrane with a pore size less than 30 nm
patent, September 2002


Porous Semi-Solid Electrode and Methods of Manufacturing the Same
patent-application, December 2015


Cathode formulations for super-iron batteries
patent-application, October 2002


Multiple metal oxide submicron particles
patent-application, June 2008


Fuel System Using Redox Flow Battery
patent-application, January 2016


High energy density redox flow device
patent, October 2015


Cerium batteries
patent, December 2009


High Energy Density Redox Flow Device
patent-application, June 2014


High Energy Density Redox Flow Device
patent-application, August 2011


Redox battery
patent, August 1997


Pre-lithiation of electrode materials in a semi-solid electrode
patent, December 2019


Stacked Flow Cell Design And Method
patent-application, January 2014


Conjugated dicarboxylate anodes for Li-ion batteries
journal, January 2009


Electrolyte tank and manufacturing method thereof
patent, July 2004


Shut-Off Valve Having Two Valve Seats Providing Pressure Equalization
patent-application, February 2009


Calcium electrochemical reserve cell
patent, June 1984


Secondary Battery, Power Supply System Using Same and Usage of Power Supply System
patent-application, January 2009


High Energy Density Redox Flow Device
patent-application, August 2011


Enzymatic fuel cell
patent-application, February 2003


Electrochemical cell
patent, March 1983


Electrochemical Cells and Methods of Manufacturing the Same
patent-application, November 2013


High Energy Density Redox Flow Device
patent-application, September 2014


High Energy Density Redox Flow Device
patent-application, July 2016


Lithium Metal Electrodes and Batteries Thereof
patent-application, October 2017


Li-Storage via Heterogeneous Reaction in Selected Binary Metal Fluorides and Oxides
journal, January 2004


End block constructions for batteries
patent, May 1994


High energy density redox flow device
patent, May 2014


Evaluation of electrolytes for redox flow battery applications
journal, January 2007


High energy density redox flow device
patent, May 2014