Ultramicro to mesopore frameworks for selective separation and storage of noble gases
Abstract
Methods and materials for the selective capture and storage of preselected materials from gas streams using metal organic framework (MOF) materials are described. In various embodiments preselected target material gases could include noble gasses such as Kr, Xe, Rn, Arultramicro to mesopore frameworks for selective separation and storage of noble gases, other gasses such as I2 or other particular isotopes either naturally occurring or man-made, or another preselected gas capture material such as a target material for legal, regulatory or treaty compliance, or a preselected material from a particular process such as a cleaning or etching agent from semiconducting or microelectronic manufacture, or a portion of an anesthetic gas such as nitrous oxide, isoflurane, sevoflurane or a fluorinated ethers.
- Inventors:
- Issue Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1892885
- Patent Number(s):
- 11318409
- Application Number:
- 16/078,502
- Assignee:
- Battelle Memorial Institute (Richland, WA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
- DOE Contract Number:
- AC05-76RL01830
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 06/09/2017
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Thallapally, Praveen K., and Vienna, John D. Ultramicro to mesopore frameworks for selective separation and storage of noble gases. United States: N. p., 2022.
Web.
Thallapally, Praveen K., & Vienna, John D. Ultramicro to mesopore frameworks for selective separation and storage of noble gases. United States.
Thallapally, Praveen K., and Vienna, John D. Tue .
"Ultramicro to mesopore frameworks for selective separation and storage of noble gases". United States. https://www.osti.gov/servlets/purl/1892885.
@article{osti_1892885,
title = {Ultramicro to mesopore frameworks for selective separation and storage of noble gases},
author = {Thallapally, Praveen K. and Vienna, John D.},
abstractNote = {Methods and materials for the selective capture and storage of preselected materials from gas streams using metal organic framework (MOF) materials are described. In various embodiments preselected target material gases could include noble gasses such as Kr, Xe, Rn, Arultramicro to mesopore frameworks for selective separation and storage of noble gases, other gasses such as I2 or other particular isotopes either naturally occurring or man-made, or another preselected gas capture material such as a target material for legal, regulatory or treaty compliance, or a preselected material from a particular process such as a cleaning or etching agent from semiconducting or microelectronic manufacture, or a portion of an anesthetic gas such as nitrous oxide, isoflurane, sevoflurane or a fluorinated ethers.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue May 03 00:00:00 EDT 2022},
month = {Tue May 03 00:00:00 EDT 2022}
}
Works referenced in this record:
Hybrid Ultra-Microporous Materials for Selective Xenon Adsorption and Separation
journal, May 2016
- Mohamed, Mona H.; Elsaidi, Sameh K.; Pham, Tony
- Angewandte Chemie International Edition, Vol. 55, Issue 29
Understanding the Adsorption Mechanism of Xe and Kr in a Metal–Organic Framework from X-ray Structural Analysis and First-Principles Calculations
journal, April 2015
- Ghose, Sanjit K.; Li, Yan; Yakovenko, Andrey
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 10
The first example of commensurate adsorption of atomic gas in a MOF and effective separation of xenon from other noble gases
journal, January 2014
- Wang, Hao; Yao, Kexin; Zhang, Zhijuan
- Chemical Science, Vol. 5, Issue 2, p. 620-624
Noble Gas Adsorption in Metal–Organic Frameworks Containing Open Metal Sites
journal, May 2014
- Perry, John J.; Teich-McGoldrick, Stephanie L.; Meek, Scott T.
- The Journal of Physical Chemistry C, Vol. 118, Issue 22, p. 11685-11698
Direct Observation of Xe and Kr Adsorption in a Xe-Selective Microporous Metal–Organic Framework
journal, May 2015
- Chen, Xianyin; Plonka, Anna M.; Banerjee, Debasis
- Journal of the American Chemical Society, Vol. 137, Issue 22
Identification of Metal–Organic Framework Materials for Adsorption Separation of Rare Gases: Applicability of Ideal Adsorbed Solution Theory (IAST) and Effects of Inaccessible Framework Regions
journal, June 2012
- Van Heest, Timothy; Teich-McGoldrick, Stephanie L.; Greathouse, Jeffery A.
- The Journal of Physical Chemistry C, Vol. 116, Issue 24, p. 13183-13195
Metal–organic framework with optimally selective xenon adsorption and separation
journal, June 2016
- Banerjee, Debasis; Simon, Cory M.; Plonka, Anna M.
- Nature Communications, Vol. 7, Issue 1
Potential of Metal–Organic Frameworks for Separation of Xenon and Krypton
journal, December 2014
- Banerjee, Debasis; Cairns, Amy J.; Liu, Jian
- Accounts of Chemical Research, Vol. 48, Issue 2
Dynamic separation of Xe and Kr by metal-organic framework and covalent-organic materials: a comparison with activated charcoal
journal, March 2016
- Wang, Qian; Xiong, Shunshun; Xiang, Zhonghua
- Science China Chemistry, Vol. 59, Issue 5
Facile xenon capture and release at room temperature using a metal–organic framework: a comparison with activated charcoal
journal, January 2012
- Thallapally, Praveen K.; Grate, Jay W.; Motkuri, Radha Kishan
- Chem. Commun., Vol. 48, Issue 3
Switching Kr/Xe Selectivity with Temperature in a Metal–Organic Framework
journal, May 2012
- Fernandez, Carlos A.; Liu, Jian; Thallapally, Praveen K.
- Journal of the American Chemical Society, Vol. 134, Issue 22, p. 9046-9049
Computational screening of metal-organic frameworks for xenon/krypton separation
journal, September 2010
- Ryan, Patrick; Farha, Omar K.; Broadbelt, Linda J.
- AIChE Journal, Vol. 57, Issue 7
Separation with Organic Molecular Solids
patent-application, May 2017
- Cooper, Andrew; Hasell, Thomas; Holden, Daniel
- US Patent Application 15/321,886; 2017/0128910 Al
A Two-Column Method for the Separation of Kr and Xe from Process Off-Gases
journal, July 2014
- Liu, Jian; Fernandez, Carlos A.; Martin, Paul F.
- Industrial & Engineering Chemistry Research, Vol. 53, Issue 32
Reversible and Irreversible Chemisorption in Nonporous Crystalline Hybrid Structures
patent-application, July 2016
- Karunadasa, Hemamala I.; Solis-Ibarra, Diego
- US Patent Application 14/916,821; 2016/0193566 Al
Process and Adsorbent for the Recovery of Krypton and Xenon from a Gas or Liquid Stream
patent-application, June 2003
- Golden, Timothy Christopher; Farris, Thomas Stephen; Chiang, Robert Ling
- US Patent Application 10/208,078; 2003/0106335 Al
Effect of ring rotation upon gas adsorption in SIFSIX-3-M (M = Fe, Ni) pillared square grid networks
journal, January 2017
- Elsaidi, Sameh K.; Mohamed, Mona H.; Simon, Cory M.
- Chemical Science, Vol. 8, Issue 3
Kr/Xe Separation over a Chabazite Zeolite Membrane
journal, August 2016
- Feng, Xuhui; Zong, Zhaowang; Elsaidi, Sameh K.
- Journal of the American Chemical Society, Vol. 138, Issue 31
Formation of High Surface Area Metal-Organic Frameworks
patent-application, June 2016
- Fuller, Patrick; Weston, Mitchell Hugh; Morris, William
- US Patent Application 14/956,223; 2016/0151762 Al
Enhanced noble gas adsorption in Ag@MOF-74Ni
journal, January 2014
- Liu, Jian; Strachan, Denis M.; Thallapally, Praveen K.
- Chem. Commun., Vol. 50, Issue 4
Separation of rare gases and chiral molecules by selective binding in porous organic cages
journal, July 2014
- Chen, Linjiang; Reiss, Paul S.; Chong, Samantha Y.
- Nature Materials, Vol. 13, Issue 10
High xenon/krypton selectivity in a metal-organic framework with small pores and strong adsorption sites
journal, March 2013
- Bae, Youn-Sang; Hauser, Brad G.; Colón, Yamil J.
- Microporous and Mesoporous Materials, Vol. 169
Adsorption Systems Using Metal-Organic Frameworks
patent-application, October 2015
- Van Horn, Brett L.; Bertelo, Christopher A.; Silverman, Gary S.
- US Patent Application 14/420,042; 2015/0291870 Al
Noble gases and microporous frameworks; from interaction to application
journal, November 2012
- Soleimani Dorcheh, A.; Denysenko, D.; Volkmer, D.
- Microporous and Mesoporous Materials, Vol. 162
Metal–Organic Frameworks for Removal of Xe and Kr from Nuclear Fuel Reprocessing Plants
journal, July 2012
- Liu, Jian; Thallapally, Praveen K.; Strachan, Denis
- Langmuir, Vol. 28, Issue 31
Frontispiece: Noria: A Highly Xe-Selective Nanoporous Organic Solid
journal, August 2016
- Patil, Rahul S.; Banerjee, Debasis; Simon, Cory M.
- Chemistry - A European Journal, Vol. 22, Issue 36