Catalytic synthesis of super linear alkenyl arenes using rhodium catalysts
Abstract
Catalytic methods for synthesis of super linear alkenyl arenes and alkyl arenes are provided. The methods are capable of synthesizing super linear alkyl and alkenyl arenes from simple arene and olefin starting materials and with high selectivity for linear coupling. Methods are also provided for making a 2,6-dimethylnapthalene (DMN) or 2,6-methylethylnapthalene (MEN).
- Inventors:
- Issue Date:
- Research Org.:
- Univ. of Virginia, Charlottesville, VA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1892838
- Patent Number(s):
- 11306041
- Application Number:
- 16/499,756
- Assignee:
- University of Virginia Patent Foundation (Charlottesville, VA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
- DOE Contract Number:
- SC0000776
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 03/30/2018
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Schinski, William, Goldman, Alan, Gunnoe, Thomas B., Webster-Gardiner, Michael S., and Schwartz, Nichole. Catalytic synthesis of super linear alkenyl arenes using rhodium catalysts. United States: N. p., 2022.
Web.
Schinski, William, Goldman, Alan, Gunnoe, Thomas B., Webster-Gardiner, Michael S., & Schwartz, Nichole. Catalytic synthesis of super linear alkenyl arenes using rhodium catalysts. United States.
Schinski, William, Goldman, Alan, Gunnoe, Thomas B., Webster-Gardiner, Michael S., and Schwartz, Nichole. Tue .
"Catalytic synthesis of super linear alkenyl arenes using rhodium catalysts". United States. https://www.osti.gov/servlets/purl/1892838.
@article{osti_1892838,
title = {Catalytic synthesis of super linear alkenyl arenes using rhodium catalysts},
author = {Schinski, William and Goldman, Alan and Gunnoe, Thomas B. and Webster-Gardiner, Michael S. and Schwartz, Nichole},
abstractNote = {Catalytic methods for synthesis of super linear alkenyl arenes and alkyl arenes are provided. The methods are capable of synthesizing super linear alkyl and alkenyl arenes from simple arene and olefin starting materials and with high selectivity for linear coupling. Methods are also provided for making a 2,6-dimethylnapthalene (DMN) or 2,6-methylethylnapthalene (MEN).},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2022},
month = {4}
}
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