KVOPO4 cathode for sodium ion batteries
Abstract
An electrode comprising: NaVOPO4 having orthorhombic crystalline symmetry and space group Pna21, as an active intercalation host material, wherein the electrode is capable of electrochemical insertion and release of greater than one sodium ion per vanadium, wherein the NaVOPO4 is formed by a solid phase synthesis process from a heated powdered mixture of ammonium metavanadate, ammonium phosphate monobasic, and potassium carbonate, to yield NaVOPO4 having corner-sharing VO6 octahedra and PO4 tetrahedra, defining two types of tunnels comprising a first type of tunnel formed of rings of two PO4 tetrahedra and a second type of tunnel formed of rings of three PO4 tetrahedra and three VO6 octahedra, followed by substitution of the potassium ions with sodium ions.
- Inventors:
- Issue Date:
- Research Org.:
- State Univ. of New York (SUNY), Binghamton, NY (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1892775
- Patent Number(s):
- 11289700
- Application Number:
- 15/633,240
- Assignee:
- The Research Foundation of State University of New York (Binghamton, NY)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- DOE Contract Number:
- SC0012583
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 06/26/2017
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Whittingham, M. Stanley, and Ding, Jia. KVOPO4 cathode for sodium ion batteries. United States: N. p., 2022.
Web.
Whittingham, M. Stanley, & Ding, Jia. KVOPO4 cathode for sodium ion batteries. United States.
Whittingham, M. Stanley, and Ding, Jia. Tue .
"KVOPO4 cathode for sodium ion batteries". United States. https://www.osti.gov/servlets/purl/1892775.
@article{osti_1892775,
title = {KVOPO4 cathode for sodium ion batteries},
author = {Whittingham, M. Stanley and Ding, Jia},
abstractNote = {An electrode comprising: NaVOPO4 having orthorhombic crystalline symmetry and space group Pna21, as an active intercalation host material, wherein the electrode is capable of electrochemical insertion and release of greater than one sodium ion per vanadium, wherein the NaVOPO4 is formed by a solid phase synthesis process from a heated powdered mixture of ammonium metavanadate, ammonium phosphate monobasic, and potassium carbonate, to yield NaVOPO4 having corner-sharing VO6 octahedra and PO4 tetrahedra, defining two types of tunnels comprising a first type of tunnel formed of rings of two PO4 tetrahedra and a second type of tunnel formed of rings of three PO4 tetrahedra and three VO6 octahedra, followed by substitution of the potassium ions with sodium ions.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2022},
month = {3}
}
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