Group transfer polymerization for the production of functional monomers
Abstract
The present invention provides efficient processes for preparing brush polymers. In general, the process comprises three distinct reaction steps utilizing two separate catalysts. In the first step, the initiating compound comprising norbornene is contacted with a silane in the presence of a catalyst, thereby forming a silated intermediate. This silated intermediate is then contacted with a monomer in the presence of a catalyst via Group Transfer Polymerization (GTP). The resulting compound from GTP is contacted with a ring opening metathesis polymerization (ROMP) catalyst to prepare the brush polymer. Surprisingly, the brush polymers obtained from the above process are accessed in an efficient and rapid GTP methodology as compared to prior methods.
- Inventors:
- Issue Date:
- Research Org.:
- Colorado State Univ., Fort Collins, CO (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1892748
- Patent Number(s):
- 11286340
- Application Number:
- 16/775,755
- Assignee:
- Colorado State University Research Foundation (Fort Collins, CO)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- DOE Contract Number:
- AR0000881
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 01/29/2020
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Miyake, Garret, Pearson, Ryan M., and Ryan, Matthew D. Group transfer polymerization for the production of functional monomers. United States: N. p., 2022.
Web.
Miyake, Garret, Pearson, Ryan M., & Ryan, Matthew D. Group transfer polymerization for the production of functional monomers. United States.
Miyake, Garret, Pearson, Ryan M., and Ryan, Matthew D. Tue .
"Group transfer polymerization for the production of functional monomers". United States. https://www.osti.gov/servlets/purl/1892748.
@article{osti_1892748,
title = {Group transfer polymerization for the production of functional monomers},
author = {Miyake, Garret and Pearson, Ryan M. and Ryan, Matthew D.},
abstractNote = {The present invention provides efficient processes for preparing brush polymers. In general, the process comprises three distinct reaction steps utilizing two separate catalysts. In the first step, the initiating compound comprising norbornene is contacted with a silane in the presence of a catalyst, thereby forming a silated intermediate. This silated intermediate is then contacted with a monomer in the presence of a catalyst via Group Transfer Polymerization (GTP). The resulting compound from GTP is contacted with a ring opening metathesis polymerization (ROMP) catalyst to prepare the brush polymer. Surprisingly, the brush polymers obtained from the above process are accessed in an efficient and rapid GTP methodology as compared to prior methods.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2022},
month = {3}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Copolymer formulation for directed self-assembly, methods of manufacture thereof and articles comprising the same
patent-application, September 2016
- Hustad, Phillip D.; Trefonas, III, Peter; Ginzburg, Valeriy V.
- US Patent Application 15/052925; 20160251508
Design and Synthesis of Alq3-Functionalized Polymers
journal, February 2003
- Meyers, Amy; Weck, Marcus
- Macromolecules, Vol. 36, Issue 6
Ethers of Endoethylene-substituted Cyclopentanols
patent, November 1946
- Bruson, Herman A.
- US Patent Document 2411516
Norbornene monomer, polynorbornene derivative, liquid crystal photoalignment film containing the same and liquid crystal display containing the same
patent-application, July 2014
- Choi, Dai-Seung; Kim, Heon; Chun, Sung-Ho
- US Patent Application 14/227878; 20140213815
Influencing Receptor−Ligand Binding Mechanisms with Multivalent Ligand Architecture
journal, December 2002
- Gestwicki, Jason E.; Cairo, Christopher W.; Strong, Laura E.
- Journal of the American Chemical Society, Vol. 124, Issue 50
Domino ring opening–ring closing metathesis (ROM–RCM) strategy toward bicyclo[n.3.0]cycloalkenes
journal, August 2002
- Hagiwara, Hisahiro; Katsumi, Tomoko; Endou, Satoru
- Tetrahedron, Vol. 58, Issue 33
Alkene-Directed Regioselective Nickel-Catalyzed Cross-Coupling of Cyclic Anhydrides with Diorganozinc Reagents
journal, December 2007
- Rogers, Rebecca L.; Moore, Jennifer L.; Rovis, Tomislav
- Angewandte Chemie International Edition, Vol. 46, Issue 48
Precise synthesis of polymers containing functional end groups by living ring-opening metathesis polymerization (ROMP): Efficient tools for synthesis of block/graft copolymers
journal, April 2010
- Nomura, Kotohiro; Abdellatif, Mohamed Mehawed
- Polymer, Vol. 51, Issue 9
Periodic Nanostructures From Self Assembled Wedge-Type Block-Copolymers
patent-application, November 2013
- Xia, Yan; Sveinbjornsson, Benjamin R.; Grubbs, Robert H.
- US Patent Application 13/801710; 20130296491
Photonic structures from self assembly of brush block copolymers and polymer blends
patent-application, January 2014
- Miyake, Garret M.; Weitekamp, Raymond; Grubbs, Robert H.
- US Patent Application 13/930400; 20140011958