Additively manufactured metal energetic ligand precursors and combustion synthesis
Abstract
Processes for tailoring the macroscopic shape, metallic composition, mechanical properties, and pore structure of nanoporous metal foams prepared through combustion synthesis via direct write 3D printing of metal energetic ligand precursor inks made with water and an organic thickening agent are disclosed. Such processes enable production of never before obtainable metal structures with hierarchical porosity, tailorable from the millimeter size regime to the nanometer size regime. Structures produced by these processes have numerous applications including, but not limited to, catalysts, heat exchangers, low density structural materials, biomedical implants, hydrogen storage medium, fuel cells, and batteries.
- Inventors:
- Issue Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1892719
- Patent Number(s):
- 11278960
- Application Number:
- 16/381,074
- Assignee:
- Triad National Security, LLC (Los Alamos, NM)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B22 - CASTING B22F - WORKING METALLIC POWDER
C - CHEMISTRY C09 - DYES C09D - COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS
- DOE Contract Number:
- 89233218CNA000001
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 04/11/2019
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Tappan, Bryce, Schmalzer, Andrew, and Mueller, Alexander. Additively manufactured metal energetic ligand precursors and combustion synthesis. United States: N. p., 2022.
Web.
Tappan, Bryce, Schmalzer, Andrew, & Mueller, Alexander. Additively manufactured metal energetic ligand precursors and combustion synthesis. United States.
Tappan, Bryce, Schmalzer, Andrew, and Mueller, Alexander. Tue .
"Additively manufactured metal energetic ligand precursors and combustion synthesis". United States. https://www.osti.gov/servlets/purl/1892719.
@article{osti_1892719,
title = {Additively manufactured metal energetic ligand precursors and combustion synthesis},
author = {Tappan, Bryce and Schmalzer, Andrew and Mueller, Alexander},
abstractNote = {Processes for tailoring the macroscopic shape, metallic composition, mechanical properties, and pore structure of nanoporous metal foams prepared through combustion synthesis via direct write 3D printing of metal energetic ligand precursor inks made with water and an organic thickening agent are disclosed. Such processes enable production of never before obtainable metal structures with hierarchical porosity, tailorable from the millimeter size regime to the nanometer size regime. Structures produced by these processes have numerous applications including, but not limited to, catalysts, heat exchangers, low density structural materials, biomedical implants, hydrogen storage medium, fuel cells, and batteries.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2022},
month = {3}
}
Works referenced in this record:
Ultralow-Density Nanostructured Metal Foams: Combustion Synthesis, Morphology, and Composition
journal, May 2006
- Tappan, B. C.; Huynh, M. H.; Hiskey, M. A.
- Journal of the American Chemical Society, Vol. 128, Issue 20
Three-Dimensional Printing of Elastomeric, Cellular Architectures with Negative Stiffness
journal, May 2014
- Duoss, Eric B.; Weisgraber, Todd H.; Hearon, Keith
- Advanced Functional Materials, Vol. 24, Issue 31
Controlling shockwave dynamics using architecture in periodic porous materials
journal, April 2017
- Branch, Brittany; Ionita, Axinte; Clements, Bradford E.
- Journal of Applied Physics, Vol. 121, Issue 13
Preparation of Nanoporous Metal Foam From High Nitrogen Transition Metal Complexes
patent-application, April 2006
- Tappan, Bryce C.; Huynh, My Hang V.; Hiskey, Michael A.
- US Patent Application 10/964218; 20060078454
Nanoporous Metal Foams
journal, May 2010
- Tappan, Bryce C.; Steiner, Stephen A.; Luther, Erik P.
- Angewandte Chemie International Edition, Vol. 49, Issue 27
A review of dry (CO 2 ) reforming of methane over noble metal catalysts
journal, January 2014
- Pakhare, Devendra; Spivey, James
- Chem. Soc. Rev., Vol. 43, Issue 22
Preparation of nanoporous metal foam from high nitrogen transition metal complexes
patent, November 2006
- Tappan, Bryce C.; Huynh, My Hang V.; Hiskey, Michael A.
- US Patent Document 7,141,675
Direct Ink Writing of 3D Functional Materials
journal, November 2006
- Lewis, J. A.
- Advanced Functional Materials, Vol. 16, Issue 17
Ultrafast Syntheses of Silver Foams from Ag 2 NCN: Combustion Synthesis versus Chemical Reduction
journal, July 2014
- Ressnig, Debora; Antonietti, Markus
- Chemistry of Materials, Vol. 26, Issue 14
Evolution of nanoporosity in dealloying
journal, March 2001
- Erlebacher, Jonah; Aziz, Michael J.; Karma, Alain
- Nature, Vol. 410, Issue 6827, p. 450-453
Iron and Nickel Cellular Structures by Sintering of 3D-Printed Oxide or Metallic Particle Inks : Iron and Nickel Cellular Structures by Sintering…
journal, September 2016
- Taylor, Shannon L.; Jakus, Adam E.; Shah, Ramille N.
- Advanced Engineering Materials, Vol. 19, Issue 11