Methods for producing and using perovskite materials and devices therefrom

Zhu, Kai; Luther, Joseph M.; Zhao, Yixin

Title: Methods for producing and using perovskite materials and devices therefrom

Abstract

The present disclosure describes solution methods for manufacturing perovskite halide films for use in solar cells. The methods include the use of additives that facilitate the formation of transitory, intermediate films that are later transformed into the final target perovskite halide films, such that the final films provide improved physical characteristics and operational performance.

Inventors:: Zhu, Kai; Luther, Joseph M.; Zhao, Yixin

Issue Date:: 2022-03-01

Research Org.:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1892669

Patent Number(s):: 11264179

Application Number:: 16/704,207

Assignee:: Alliance for Sustainable Energy, LLC (Golden, CO)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01G - CAPACITORS

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01G - CAPACITORS
H01G9/2013 - {the electrolyte comprising ionic liquids, e.g. alkyl imidazolium iodide}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E10/542 - Dye sensitized solar cells
Y02E10/549 - organic PV cells

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P70/50 - Manufacturing or production processes characterised by the final manufactured product

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DOE Contract Number:: AC36-08GO28308

Resource Type:: Patent

Resource Relation:: Patent File Date: 12/05/2019

Country of Publication:: United States

Language:: English

Citation Formats


                    Zhu, Kai, Luther, Joseph M., and Zhao, Yixin. Methods for producing and using perovskite materials and devices therefrom.  United States: N. p., 2022. 
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                    Zhu, Kai, Luther, Joseph M., & Zhao, Yixin. Methods for producing and using perovskite materials and devices therefrom.  United States.

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                    Zhu, Kai, Luther, Joseph M., and Zhao, Yixin. Tue .  
        "Methods for producing and using perovskite materials and devices therefrom".  United States.  https://www.osti.gov/servlets/purl/1892669.

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@article{osti_1892669,

  title        = {Methods for producing and using perovskite materials and devices therefrom},

  author       = {Zhu, Kai and Luther, Joseph M. and Zhao, Yixin},

  abstractNote = {The present disclosure describes solution methods for manufacturing perovskite halide films for use in solar cells. The methods include the use of additives that facilitate the formation of transitory, intermediate films that are later transformed into the final target perovskite halide films, such that the final films provide improved physical characteristics and operational performance.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2022},

  month        = {3}

}

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Chloride Inclusion and Hole Transport Material Doping to Improve Methyl Ammonium Lead Bromide Perovskite-Based High Open-Circuit Voltage Solar Cells
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Edri, Eran; Kirmayer, Saar; Kulbak, Michael
The Journal of Physical Chemistry Letters, Vol. 5, Issue 3, p. 429-433
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Mesoporous perovskite solar cells: material composition, charge-carrier dynamics, and device characteristics
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Zhao, Yixin; Nardes, Alexandre M.; Zhu, Kai
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Optical bleaching of perovskite (CH3NH3)PbI3 through room-temperature phase transformation induced by ammonia
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Zhao, Yixin; Zhu, Kai
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Heterojunction Device
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Snaith, Henry J.
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Effect of Different Hole Transport Materials on Recombination in CH₃NH₃PbI₃ Perovskite-Sensitized Mesoscopic Solar Cells
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Bi, Dongqin; Yang, Lei; Boschloo, Gerrit
The Journal of Physical Chemistry Letters, Vol. 4, Issue 9, p. 1532-1536
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Enhanced Extraction Rates through Gap States of Molybdenum Oxide Anode Buffer
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Dasgupta, Binayak; Goh, Wei Peng; Ooi, Zi En
The Journal of Physical Chemistry C, Vol. 117, Issue 18, p. 9206-9211
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Sequential deposition as a route to high-performance perovskite-sensitized solar cells
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Burschka, Julian; Pellet, Norman; Moon, Soo-Jin
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Three-step sequential solution deposition of PbI ₂ -free CH ₃ NH ₃ PbI ₃ perovskite
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Zhao, Yixin; Zhu, Kai
Journal of Materials Chemistry A, Vol. 3, Issue 17
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All-solid-state hybrid solar cells based on a new organometal halide perovskite sensitizer and one-dimensional TiO2 nanowire arrays
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Qiu, Jianhang; Qiu, Yongcai; Yan, Keyou
Nanoscale, Vol. 5, Issue 8
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Depleted hole conductor-free lead halide iodide heterojunction solar cells
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Laban, Waleed Abu; Etgar, Lioz
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Epitaxial BiFeO₃ Multiferroic Thin Film Heterostructures
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Wang, J.; Neaton, J. B.; Zheng, H.
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Perovskite complex oxide and method of producing the same
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Yano, Takuya; Suda, Hisashi
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Silicon heterojunction solar cell with passivated hole selective MoO _x contact
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Battaglia, Corsin; de Nicolás, Silvia Martín; De Wolf, Stefaan
Applied Physics Letters, Vol. 104, Issue 11
https://doi.org/10.1063/1.4868880

Performance improvement of inverted polymer solar cells with different top electrodes by introducing a MoO3 buffer layer
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Tao, Chen; Ruan, Shengping; Zhang, Xindong
Applied Physics Letters, Vol. 93, Issue 19
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Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
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Lee, M. M.; Teuscher, J.; Miyasaka, T.
Science, Vol. 338, Issue 6107, p. 643-647
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Mitzi, David B.
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Jin, S.; Tiefel, T. H.; McCormack, M.
Science, Vol. 264, Issue 5157
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Qin, Peng; Tanaka, Soichiro; Ito, Seigo
Nature Communications, Vol. 5, Issue 1
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Optoelectronic Devices With Organometal Perovskites With Mixed Anions
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Snaith, Henry; Lee, Michael; Murakami, Takuro
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Organolead Halide Perovskite: New Horizons in Solar Cell Research
journal, February 2014

Kim, Hui-Seon; Im, Sang Hyuk; Park, Nam-Gyu
The Journal of Physical Chemistry C, Vol. 118, Issue 11, p. 5615-5625
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Organic-Inorganic Hybrid Materials as Semiconducting Channels in Thin-Film Field-Effect Transistors
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Kagan, C. R.; Mitzi, D. B.; Dimitrakopoulos, C. D.
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Synthesis and Characterization of Organic−Inorganic Perovskite Thin Films Prepared Using a Versatile Two-Step Dipping Technique
journal, January 1998

Liang, Kangning; Mitzi, David B.; Prikas, Michael T.
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Huang, Jinsong; Dong, Qingfeng; Sao, Yuchuan
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MAPbI_3-xCl_x Mixed Halide Perovskite for Hybrid Solar Cells: The Role of Chloride as Dopant on the Transport and Structural Properties
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Colella, Silvia; Mosconi, Edoardo; Fedeli, Paolo
Chemistry of Materials, Vol. 25, Issue 22, p. 4613-4618
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Nanocrystalline Rutile Electron Extraction Layer Enables Low-Temperature Solution Processed Perovskite Photovoltaics with 13.7% Efficiency
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Yella, Aswani; Heiniger, Leo-Philipp; Gao, Peng
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Title: Methods for producing and using perovskite materials and devices therefrom

Abstract

Citation Formats

Liquid Exfoliation of Layered Materials journal, June 2013

Enhanced Crystallinity in Organic–Inorganic Lead Halide Perovskites on Mesoporous TiO2 via Disorder–Order Phase Transition journal, July 2014

Solid-State Mesostructured Perovskite CH 3 NH 3 PbI 3 Solar Cells: Charge Transport, Recombination, and Diffusion Length journal, January 2014

The emergence of perovskite solar cells journal, July 2014

Mesoscopic CH3NH3PbI3/TiO2 Heterojunction Solar Cells journal, October 2012

Charge Transport and Recombination in Perovskite (CH 3 NH 3 )PbI 3 Sensitized TiO 2 Solar Cells journal, August 2013

An Inorganic Hole Conductor for Organo-Lead Halide Perovskite Solar Cells. Improved Hole Conductivity with Copper Iodide journal, December 2013

High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization journal, July 2015

Tandem photovoltaic cell patent, October 2013

Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3 journal, October 2013

Solution Deposition-Conversion for Planar Heterojunction Mixed Halide Perovskite Solar Cells journal, May 2014

Additive Enhanced Crystallization of Solution-Processed Perovskite for Highly Efficient Planar-Heterojunction Solar Cells journal, March 2014

A highly efficient mesoscopic solar cell based on CH 3 NH 3 PbI 3−x Cl x fabricated via sequential solution deposition journal, January 2014

Dynamic Response of Dye-Sensitized Nanocrystalline Solar Cells: Characterization by Intensity-Modulated Photocurrent Spectroscopy journal, December 1997

Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells journal, July 2014

Voltage-Enhancement Mechanisms of an Organic Dye in High Open-Circuit Voltage Solid-State Dye-Sensitized Solar Cells journal, September 2011

Perovskites by Design: A Toolbox of Solid-State Reactions journal, April 2002

Efficient inorganic–organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors journal, May 2013

Controllable Sequential Deposition of Planar CH 3 NH 3 PbI 3 Perovskite Films via Adjustable Volume Expansion journal, May 2015

All-solid-state dye-sensitized solar cells with high efficiency journal, May 2012

Films and crystalline powder of PbI2 intercalated with ammonia and pyridine journal, March 2008

Process for forming epitaxial perovskite thin film layers using halide precursors patent, May 2001

Organometal Perovskite Light Absorbers Toward a 20% Efficiency Low-Cost Solid-State Mesoscopic Solar Cell journal, July 2013

Planar Heterojunction Perovskite Solar Cells via Vapor-Assisted Solution Process journal, December 2013

n-Type Transition Metal Oxide as a Hole Extraction Layer in PbS Quantum Dot Solar Cells journal, August 2011

Unusual defect physics in CH 3 NH 3 PbI 3 perovskite solar cell absorber journal, February 2014

High performance hybrid solar cells sensitized by organolead halide perovskites journal, January 2013

Structure of Methylammonium Lead Iodide Within Mesoporous Titanium Dioxide: Active Material in High-Performance Perovskite Solar Cells journal, December 2013

Effective hole extraction using MoO x -Al contact in perovskite CH 3 NH 3 PbI 3 solar cells journal, May 2014

Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% journal, August 2012

Trap-limited recombination in dye-sensitized nanocrystalline metal oxide electrodes journal, May 2001

Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques journal, December 2013

Retarding the crystallization of PbI 2 for highly reproducible planar-structured perovskite solar cells via sequential deposition journal, January 2014

Thermally Induced Structural Evolution and Performance of Mesoporous Block Copolymer-Directed Alumina Perovskite Solar Cells journal, April 2014

High Open-Circuit Voltage Solar Cells Based on Organic–Inorganic Lead Bromide Perovskite journal, March 2013

Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells journal, January 2014

Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber journal, October 2013

Methods for producing single crystal mixed halide perovskites patent, July 2017

High performance organic light emitting diodes using substoichiometric tungsten oxide as efficient hole injection layer journal, May 2012

High Efficiency Solid-State Sensitized Solar Cell-Based on Submicrometer Rutile TiO2 Nanorod and CH3NH3PbI3 Perovskite Sensitizer journal, May 2013

Photoexcitation and photoluminescence study of coordination complexes of lead diiodide with pyridine journal, September 1990

Hybrid Organic Solar Cell With Perovskite Structure As Absorption Material And Manufacturing Method Thereof patent-application, November 2014

Impedance Spectroscopic Analysis of Lead Iodide Perovskite-Sensitized Solid-State Solar Cells journal, December 2013

Superconductivity in a layered perovskite without copper journal, December 1994

Light Absorbing Oxide Materials for Photovoltaic and Photocatalytic Applications and Devices patent-application, March 2014

Mixed-Organic-Cation Perovskite Photovoltaics for Enhanced Solar-Light Harvesting journal, February 2014

Low-Temperature Processed Electron Collection Layers of Graphene/TiO2 Nanocomposites in Thin Film Perovskite Solar Cells journal, December 2013

High voltage and efficient bilayer heterojunction solar cells based on an organic–inorganic hybrid perovskite absorber with a low-cost flexible substrate journal, January 2014

Interpretation of the Time Constants Measured by Kinetic Techniques in Nanostructured Semiconductor Electrodes and Dye-Sensitized Solar Cells journal, February 2004

Electron Transport in the Nanostructured TiO 2 −Electrolyte System Studied with Time-Resolved Photocurrents journal, April 1997

Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells journal, March 2013

Organic Semiconductor Device patent-application, December 2010

Optoelectronic Device patent-application, September 2015

Size and shape control of nanocrystallites in mesoporous TiO2 films journal, January 2007

Hybrid Lead Halide Iodide and Lead Halide Bromide in Efficient Hole Conductor Free Perovskite Solar Cell journal, May 2014

Role of the Selective Contacts in the Performance of Lead Halide Perovskite Solar Cells journal, January 2014

Efficient Planar Perovskite Solar Cells Based on 1.8 eV Band Gap CH 3 NH 3 PbI 2 Br Nanosheets via Thermal Decomposition journal, August 2014

Hole-conductor-free perovskite organic lead iodide heterojunction thin-film solar cells: High efficiency and junction property journal, February 2014

Morphological Control for High Performance, Solution-Processed Planar Heterojunction Perovskite Solar Cells journal, September 2013

Low-temperature processed meso-superstructured to thin-film perovskite solar cells journal, January 2013

Optoelectronic Device Comprising Perovskites patent-application, May 2015

Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates journal, November 2013

Two-step dipping technique for the preparation of organic-inorganic perovskite thin films patent, February 1999

Mechanism of carrier accumulation in perovskite thin-absorber solar cells journal, July 2013

6.5% efficient perovskite quantum-dot-sensitized solar cell journal, January 2011

Efficient Inorganic–Organic Hybrid Perovskite Solar Cells Based on Pyrene Arylamine Derivatives as Hole-Transporting Materials journal, December 2013

Active Materials For Electro-Optic Devices And Electro-Optic Devices patent-application, January 2014

Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells journal, October 2013

Redox Material For Thermochemical Water Splitting, And Method For Producing Hydrogen patent-application, December 2011

Systems and Methods for Scalable Perovskite Device Fabrication patent-application, July 2016

CH 3 NH 3 Cl-Assisted One-Step Solution Growth of CH 3 NH 3 PbI 3 : Structure, Charge-Carrier Dynamics, and Photovoltaic Properties of Perovskite Solar Cells journal, April 2014

Methods for producing single crystal mixed halide perovskites patent-application, September 2016

Perovskite-Based Hybrid Solar Cells Exceeding 10% Efficiency with High Reproducibility Using a Thin Film Sandwich Approach journal, December 2013

Efficient planar heterojunction perovskite solar cells by vapour deposition journal, September 2013

Self-powered GHZ solution-processed hybrid perovskite photodetectors patent, February 2019

Method for producing high quality, ultra-thin organic-inorganic hybrid perovskite patent, October 2017

Effect of Annealing Temperature on Film Morphology of Organic-Inorganic Hybrid Pervoskite Solid-State Solar Cells journal, February 2014

Liquid Exfoliation of Layered Materials
journal, June 2013

Enhanced Crystallinity in Organic–Inorganic Lead Halide Perovskites on Mesoporous TiO₂ via Disorder–Order Phase Transition
journal, July 2014

Solid-State Mesostructured Perovskite CH ₃ NH ₃ PbI ₃ Solar Cells: Charge Transport, Recombination, and Diffusion Length
journal, January 2014

The emergence of perovskite solar cells
journal, July 2014

Mesoscopic CH₃NH₃PbI₃/TiO₂ Heterojunction Solar Cells
journal, October 2012

Charge Transport and Recombination in Perovskite (CH ₃ NH ₃ )PbI ₃ Sensitized TiO ₂ Solar Cells
journal, August 2013

An Inorganic Hole Conductor for Organo-Lead Halide Perovskite Solar Cells. Improved Hole Conductivity with Copper Iodide
journal, December 2013

High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization
journal, July 2015

Tandem photovoltaic cell
patent, October 2013

Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH₃NH₃PbI₃
journal, October 2013

Solution Deposition-Conversion for Planar Heterojunction Mixed Halide Perovskite Solar Cells
journal, May 2014

Additive Enhanced Crystallization of Solution-Processed Perovskite for Highly Efficient Planar-Heterojunction Solar Cells
journal, March 2014

A highly efficient mesoscopic solar cell based on CH ₃ NH ₃ PbI _3−x Cl _x fabricated via sequential solution deposition
journal, January 2014

Dynamic Response of Dye-Sensitized Nanocrystalline Solar Cells: Characterization by Intensity-Modulated Photocurrent Spectroscopy
journal, December 1997

Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
journal, July 2014

Voltage-Enhancement Mechanisms of an Organic Dye in High Open-Circuit Voltage Solid-State Dye-Sensitized Solar Cells
journal, September 2011

Perovskites by Design: A Toolbox of Solid-State Reactions
journal, April 2002

Efficient inorganic–organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors
journal, May 2013

Controllable Sequential Deposition of Planar CH ₃ NH ₃ PbI ₃ Perovskite Films via Adjustable Volume Expansion
journal, May 2015

All-solid-state dye-sensitized solar cells with high efficiency
journal, May 2012

Films and crystalline powder of PbI2 intercalated with ammonia and pyridine
journal, March 2008

Process for forming epitaxial perovskite thin film layers using halide precursors
patent, May 2001

Organometal Perovskite Light Absorbers Toward a 20% Efficiency Low-Cost Solid-State Mesoscopic Solar Cell
journal, July 2013

Planar Heterojunction Perovskite Solar Cells via Vapor-Assisted Solution Process
journal, December 2013

n-Type Transition Metal Oxide as a Hole Extraction Layer in PbS Quantum Dot Solar Cells
journal, August 2011

Unusual defect physics in CH ₃ NH ₃ PbI ₃ perovskite solar cell absorber
journal, February 2014

High performance hybrid solar cells sensitized by organolead halide perovskites
journal, January 2013

Structure of Methylammonium Lead Iodide Within Mesoporous Titanium Dioxide: Active Material in High-Performance Perovskite Solar Cells
journal, December 2013

Effective hole extraction using MoO _x -Al contact in perovskite CH ₃ NH ₃ PbI ₃ solar cells
journal, May 2014

Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9%
journal, August 2012

Trap-limited recombination in dye-sensitized nanocrystalline metal oxide electrodes
journal, May 2001

Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques
journal, December 2013

Retarding the crystallization of PbI ₂ for highly reproducible planar-structured perovskite solar cells via sequential deposition
journal, January 2014

Thermally Induced Structural Evolution and Performance of Mesoporous Block Copolymer-Directed Alumina Perovskite Solar Cells
journal, April 2014

High Open-Circuit Voltage Solar Cells Based on Organic–Inorganic Lead Bromide Perovskite
journal, March 2013

Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells
journal, January 2014

Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
journal, October 2013

Methods for producing single crystal mixed halide perovskites
patent, July 2017

High performance organic light emitting diodes using substoichiometric tungsten oxide as efficient hole injection layer
journal, May 2012

High Efficiency Solid-State Sensitized Solar Cell-Based on Submicrometer Rutile TiO₂ Nanorod and CH₃NH₃PbI₃ Perovskite Sensitizer
journal, May 2013

Photoexcitation and photoluminescence study of coordination complexes of lead diiodide with pyridine
journal, September 1990

Hybrid Organic Solar Cell With Perovskite Structure As Absorption Material And Manufacturing Method Thereof
patent-application, November 2014

Impedance Spectroscopic Analysis of Lead Iodide Perovskite-Sensitized Solid-State Solar Cells
journal, December 2013

Superconductivity in a layered perovskite without copper
journal, December 1994

Light Absorbing Oxide Materials for Photovoltaic and Photocatalytic Applications and Devices
patent-application, March 2014

Mixed-Organic-Cation Perovskite Photovoltaics for Enhanced Solar-Light Harvesting
journal, February 2014

Low-Temperature Processed Electron Collection Layers of Graphene/TiO₂ Nanocomposites in Thin Film Perovskite Solar Cells
journal, December 2013

High voltage and efficient bilayer heterojunction solar cells based on an organic–inorganic hybrid perovskite absorber with a low-cost flexible substrate
journal, January 2014

Interpretation of the Time Constants Measured by Kinetic Techniques in Nanostructured Semiconductor Electrodes and Dye-Sensitized Solar Cells
journal, February 2004

Electron Transport in the Nanostructured TiO ₂ −Electrolyte System Studied with Time-Resolved Photocurrents
journal, April 1997

Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells
journal, March 2013

Organic Semiconductor Device
patent-application, December 2010

Optoelectronic Device
patent-application, September 2015

Size and shape control of nanocrystallites in mesoporous TiO₂ films
journal, January 2007

Hybrid Lead Halide Iodide and Lead Halide Bromide in Efficient Hole Conductor Free Perovskite Solar Cell
journal, May 2014

Role of the Selective Contacts in the Performance of Lead Halide Perovskite Solar Cells
journal, January 2014

Efficient Planar Perovskite Solar Cells Based on 1.8 eV Band Gap CH ₃ NH ₃ PbI ₂ Br Nanosheets via Thermal Decomposition
journal, August 2014

Hole-conductor-free perovskite organic lead iodide heterojunction thin-film solar cells: High efficiency and junction property
journal, February 2014

Morphological Control for High Performance, Solution-Processed Planar Heterojunction Perovskite Solar Cells
journal, September 2013

Low-temperature processed meso-superstructured to thin-film perovskite solar cells
journal, January 2013

Optoelectronic Device Comprising Perovskites
patent-application, May 2015

Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates
journal, November 2013

Two-step dipping technique for the preparation of organic-inorganic perovskite thin films
patent, February 1999

Mechanism of carrier accumulation in perovskite thin-absorber solar cells
journal, July 2013

6.5% efficient perovskite quantum-dot-sensitized solar cell
journal, January 2011

Efficient Inorganic–Organic Hybrid Perovskite Solar Cells Based on Pyrene Arylamine Derivatives as Hole-Transporting Materials
journal, December 2013

Active Materials For Electro-Optic Devices And Electro-Optic Devices
patent-application, January 2014

Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells
journal, October 2013

Redox Material For Thermochemical Water Splitting, And Method For Producing Hydrogen
patent-application, December 2011

Systems and Methods for Scalable Perovskite Device Fabrication
patent-application, July 2016

CH ₃ NH ₃ Cl-Assisted One-Step Solution Growth of CH ₃ NH ₃ PbI ₃ : Structure, Charge-Carrier Dynamics, and Photovoltaic Properties of Perovskite Solar Cells
journal, April 2014

Methods for producing single crystal mixed halide perovskites
patent-application, September 2016

Perovskite-Based Hybrid Solar Cells Exceeding 10% Efficiency with High Reproducibility Using a Thin Film Sandwich Approach
journal, December 2013

Efficient planar heterojunction perovskite solar cells by vapour deposition
journal, September 2013

Self-powered GHZ solution-processed hybrid perovskite photodetectors
patent, February 2019

Method for producing high quality, ultra-thin organic-inorganic hybrid perovskite
patent, October 2017

Effect of Annealing Temperature on Film Morphology of Organic-Inorganic Hybrid Pervoskite Solid-State Solar Cells
journal, February 2014

Development of MoOx thin films as back contact buffer for CdTe solar cells in substrate configuration
journal, May 2013

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009

A facile solvothermal growth of single crystal mixed halide perovskite CH₃NH₃Pb(Br_1−xCl_x)₃
journal, January 2015