ϵ-VOPO4 cathode for lithium ion batteries
Abstract
The epsilon polymorph of vanadyl phosphate, ε-VOPO4, made from the solvothermally synthesized H2VOPO4, is a high density cathode material for lithium-ion batteries optimized to reversibly intercalate two Li-ions to reach the full theoretical capacity at least 50 cycles with a coulombic efficiency of 98%. This material adopts a stable 3D tunnel structure and can extract two Li-ions per vanadium ion, giving a theoretical capacity of 305 mAh/g, with an upper charge/discharge plateau at around 4.0 V, and one lower at around 2.5 V.
- Inventors:
- Issue Date:
- Research Org.:
- State University of New York (SUNY), Binghamton, NY (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1892621
- Patent Number(s):
- 11251430
- Application Number:
- 16/291,617
- Assignee:
- The Research Foundation of State University of New York (Binghamton, NY)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- DOE Contract Number:
- SC0012583
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 03/04/2019
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Siu, Carrie, and Whittingham, M. Stanley. ϵ-VOPO4 cathode for lithium ion batteries. United States: N. p., 2022.
Web.
Siu, Carrie, & Whittingham, M. Stanley. ϵ-VOPO4 cathode for lithium ion batteries. United States.
Siu, Carrie, and Whittingham, M. Stanley. Tue .
"ϵ-VOPO4 cathode for lithium ion batteries". United States. https://www.osti.gov/servlets/purl/1892621.
@article{osti_1892621,
title = {ϵ-VOPO4 cathode for lithium ion batteries},
author = {Siu, Carrie and Whittingham, M. Stanley},
abstractNote = {The epsilon polymorph of vanadyl phosphate, ε-VOPO4, made from the solvothermally synthesized H2VOPO4, is a high density cathode material for lithium-ion batteries optimized to reversibly intercalate two Li-ions to reach the full theoretical capacity at least 50 cycles with a coulombic efficiency of 98%. This material adopts a stable 3D tunnel structure and can extract two Li-ions per vanadium ion, giving a theoretical capacity of 305 mAh/g, with an upper charge/discharge plateau at around 4.0 V, and one lower at around 2.5 V.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2022},
month = {2}
}
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