Polymers and methods for their manufacture
Abstract
Embodiments of the invention relate to a novel class of polymers with superior mechanical properties and chemical stability, as compared to known polymers. These polymers are particularly well suited for use in anion exchange membranes (AEMs), including those employed in fuel cells. Novel methods for the manufacture of these polymers are also described.
- Inventors:
- Issue Date:
- Research Org.:
- Rensselaer Polytechnic Inst., Troy, NY (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- OSTI Identifier:
- 1892577
- Patent Number(s):
- 11236196
- Application Number:
- 16/788,506
- Assignee:
- Rensselaer Polytechnic Institute (Troy, NY)
- Patent Classifications (CPCs):
-
A - HUMAN NECESSITIES A01 - AGRICULTURE A01N - PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- DOE Contract Number:
- AR0000769
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 02/12/2020
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Bae, Chulsung, and Lee, Woo-Hyung. Polymers and methods for their manufacture. United States: N. p., 2022.
Web.
Bae, Chulsung, & Lee, Woo-Hyung. Polymers and methods for their manufacture. United States.
Bae, Chulsung, and Lee, Woo-Hyung. Tue .
"Polymers and methods for their manufacture". United States. https://www.osti.gov/servlets/purl/1892577.
@article{osti_1892577,
title = {Polymers and methods for their manufacture},
author = {Bae, Chulsung and Lee, Woo-Hyung},
abstractNote = {Embodiments of the invention relate to a novel class of polymers with superior mechanical properties and chemical stability, as compared to known polymers. These polymers are particularly well suited for use in anion exchange membranes (AEMs), including those employed in fuel cells. Novel methods for the manufacture of these polymers are also described.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2022},
month = {2}
}
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patent, June 2015
- Kim, Yu Seung; Bae, Chulsung
- US Patent Document 9,051,431
Synthesis of sulfonated aromatic poly(ether amide)s and their application to proton exchange membrane fuel cells
journal, January 2009
- Jo, Tae Soo; Ozawa, Coreen H.; Eagar, Bryce R.
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 47, Issue 2
Synthesis of Aromatic Anion Exchange Membranes by Friedel–Crafts Bromoalkylation and Cross-Linking of Polystyrene Block Copolymers
journal, February 2019
- Jeon, Jong Yeob; Park, Sungmin; Han, Junyoung
- Macromolecules, Vol. 52, Issue 5
Crosslinking of Aromatic Polymers for Anion Exchange Membranes
patent-application, April 2021
- Bae, Chulsung; Jeon, Jong Yeob; Han, Junyoung
- US Patent Application 17/050,256; 2021/0108067 Al
Impact of Microstructured Morphology on Macroscale Properties of Semi-Crystalline Triblock Copolymer Anion Exchange Membranes
journal, November 2020
- Trant, Carrie; Bae, Chulsung; Lee, Sangwoo
- ECS Meeting Abstracts, Vol. MA2020-02, Issue 35
Fabrication of Dense Cerium Pyrophosphate-Polystyrene Composite for Application as Low-Temperature Proton-Conducting Electrolytes
journal, January 2015
- Kim, Ji-Hye; Park, Eun J.; Lim, Dae-Kwang
- Journal of The Electrochemical Society, Vol. 162, Issue 10
Functionalization of poly(phenylene) by the attachment of sidechains
patent, August 2014
- Hibbs, Michael
- US Patent Document 8,809,483
Anion Exchange Membranes and Polymers for Use in Same
patent-application, March 2020
- Bae, Chulsung; Mohanty, Angela Dee
- US Patent Application 16/696,186; 2020/0094241 Al
Polystyrene Ionomers Functionalized with Partially Fluorinated Short Side???Chain Sulfonic Acid for Fuel Cell Membrane Applications
other, January 2012
- Chang, Ying; Bae, Chulsung
- Sustainable Membrane Technology for Energy, Water, and Environment
Ionic Functionalization of Aromatic Polymers for Ion Exchange Membranes
patent-application, July 2020
- Bae, Chulsung; Jeon, Jong Yeob
- US Patent Application 16/842,037; 2020/0238272 Al
Synthesis of polar block grafted syndiotactic polystyrenes via a combination of iridium‐catalyzed activation of aromatic CH bonds and atom transfer radical polymerization
journal, October 2009
- Brownell, Lacie V.; Shin, Jihoon; Bae, Chulsung
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 47, Issue 23
High-Throughput Anion Exchange Membrane Characterization at NREL
journal, July 2019
- Meek, Kelly M.; Antunes, Christopher M.; Strasser, Derek
- ECS Transactions, Vol. 92, Issue 8
Mesoscale Simulations of Quaternary Ammonium-Tethered Triblock Copolymers: Effects of the Degree of Functionalization and Styrene Content
journal, July 2020
- Luo, Xubo; Liu, Hongjun; Bae, Chulsung
- The Journal of Physical Chemistry C, Vol. 124, Issue 30
Modification of polymers with basic N-groups and ion exchange groups in the lateral chain
patent, July 2003
- Kerres, Jochen; Ullrich, Andreas; Häring, Thomas
- US Patent Document 6,590,067
Anion exchange membranes based on quaternized polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene for direct methanol alkaline fuel cells
journal, March 2010
- Zeng, Qing Hua; Liu, Qing Lin; Broadwell, Ian
- Journal of Membrane Science, Vol. 349, Issue 1-2
(Invited) Development of Versatile Polymer Materials for Anion Exchange Membranes in Electrochemical Energy Conversion Technology
journal, November 2020
- Bae, Chulsung
- ECS Meeting Abstracts, Vol. MA2020-02, Issue 37
Method for Producing Anion Exchange Membrane, Fuel Cell Membrane Electrode Assembly, and Fuel Cell
patent-application, April 2015
- Matsuda, Koso; Nakano, Takeshi; Nishii, Hiroyuki
- US Patent Application 14/403,792; 2015/0111128 Al
Novel Sulfonated Aromatic Polymer Membranes for Breaking the Coulombic and Voltage Efficiency Trade-Off Limitation in Vanadium Redox Flow Battery
journal, September 2019
- Kim, Sangil; Wang, Tongshuai; Han, Junyoung
- ECS Meeting Abstracts, Vol. MA2019-02, Issue 6
Toward Improved Conductivity of Sulfonated Aromatic Proton Exchange Membranes at Low Relative Humidity
journal, September 2008
- Einsla, Melinda L.; Kim, Yu Seung; Hawley, Marilyn
- Chemistry of Materials, Vol. 20, Issue 17
Synthesis and Characterization of Anion-Exchange Membranes Using Semicrystalline Triblock Copolymers in Ordered and Disordered States
journal, September 2020
- Trant, Carrie; Hwang, Sooyeon; Bae, Chulsung
- Macromolecules, Vol. 53, Issue 19
Proton-Conducting Polymer Membrane
patent-application, January 2009
- Fritsch, Detlev; Vetter, Serge; Nunes, Suzana
- US Patent Application 12/169,181; 2009/0004528 Al
Synthesis of anion conducting polymer electrolyte membranes by Pd-Catalyzed Buchwald-Hartwig Amination coupling reaction
journal, August 2019
- Pagels, Michael K.; Walgama, Ramali C.; Bush, Nancy G.
- Tetrahedron, Vol. 75, Issue 31
Aromatic Polymer with Pendant Perfluoroalkyl Sulfonic Acid for Fuel Cell Applications
journal, October 2009
- Yoshimura, Ken; Iwasaki, Katsuhiko
- Macromolecules, Vol. 42, Issue 23
Factors Enhancing the Reactivity of Carbonyl Compounds for Polycondensations with Aromatic Hydrocarbons. A Computational Study
journal, August 2004
- Peña, Estrella Ramos; Zolotukhin, Mikhail; Fomine, Serguei
- Macromolecules, Vol. 37, Issue 16
Chemically durable polymer electrolytes for solid-state alkaline water electrolysis
journal, January 2018
- Park, Eun Joo; Capuano, Christopher B.; Ayers, Katherine E.
- Journal of Power Sources, Vol. 375
Hydrophilic graft modification of a commercial crystalline polyolefin
journal, January 2008
- Shin, Jihoon; Chang, Andrew Y.; Brownell, Lacie V.
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 46, Issue 11
Molecular Engineering of Ion-Conducting Polymers for Fuel Cell Membrane Applications
journal, September 2015
- Lee, Woo-Hyung; Mohanty, Angela D.; Bae, Chulsung
- ECS Transactions, Vol. 69, Issue 17
Self-Cleaning CO 2 Reduction Systems: Unsteady Electrochemical Forcing Enables Stability
journal, February 2021
- Xu, Yi; Edwards, Jonathan P.; Liu, Shijie
- ACS Energy Letters, Vol. 6, Issue 2
Measuring water hydrogen bonding distributions in proton exchange membranes using linear Fourier Transform Infrared spectroscopy
journal, July 2015
- Smedley, Sarah B.; Chang, Ying; Bae, Chulsung
- Solid State Ionics, Vol. 275
An alkaline polymer electrolyte CO 2 electrolyzer operated with pure water
journal, January 2019
- Yin, Zhenglei; Peng, Hanqing; Wei, Xing
- Energy & Environmental Science, Vol. 12, Issue 8
Dramatic Enhancement of Superacid-Catalyzed Polyhydroxyalkylation Reactions
journal, December 2010
- Guzmán-Gutiérrez, Maria T.; Nieto, Daniel R.; Fomine, Serguei
- Macromolecules, Vol. 44, Issue 2
Direct nucleophilic fluorination of carbonyl groups of benzophenones and benzils with Deoxofluor
journal, October 2008
- Chang, Ying; Tewari, Amit; Adi, Avi-Izak
- Tetrahedron, Vol. 64, Issue 42
Poly(Arylene Ether Sulfone) Ionomers with Different Acidity Strengths and Fuel Cell Membrane Properties
journal, March 2013
- Chang, Ying; Brunello, Giuseppe F.; Disabb-Miller, Melanie
- ECS Transactions, Vol. 50, Issue 2
Alkylation and Acylation Reactions
patent-application, May 2002
- Swan, Thomas M.; Ross, Stephen K.; Poliakoff, Martyn
- US Patent Application 09/939,187; 2002/0062046 Al
Resilient Anion Exchange Membranes
patent-application, December 2014
- Yin, Xiangchum; Zhou, Zhongyuan
- US Patent Application 14/463,794; 2014/0353241 Al
Proton exchange membrane material and methods of making the same
patent-application, March 2020
- Bae, Chulsung; Park, Eun Joo; Han, Junyoung
- US Patent Application 16/471358; 20200091535
Blended PEM's with Elastomers for Improved Mechanical Durability
patent-application, November 2009
- Mackinnon, Sean M.; Fuller, Timothy J.; Schoeneweiss, Michael R.
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Partially Fluorinated Sulfonated Poly(ether amide) Fuel Cell Membranes: Influence of Chemical Structure on Membrane Properties
journal, January 2011
- Chang, Ying; Lee, Yeong-Beom; Bae, Chulsung
- Polymers, Vol. 3, Issue 1
Synthetic Approach to Hydrocarbon Proton Exchange Membranes Using Anion Exchange Membrane Precursors
journal, November 2020
- Pagels, Michael; Adhikari, Santosh; Walgama, Ramali
- ECS Meeting Abstracts, Vol. MA2020-02, Issue 35
Sulfonated Polyamide Based IPMCs
conference, March 2009
- Park, Il-Seok; Bae, Chulsung; Jo, Tae Soo
- Electroactive Polymer Actuators and Devices (EAPAD) 2009
Novel Aromatic Polymers with Pentafluorophenyl Pendent Groups
journal, October 2008
- Velasco, Victor M.; Zolotukhin, Mikhail G.; Guzmán-Gutiérrez, Maria Teresa
- Macromolecules, Vol. 41, Issue 22
Functionalization of Diels-Alder polyphenylene polymers
patent, August 2018
- Fujimoto, Cy
- US Patent Document 10,053,534
Poly(phenylene)-based anion exchange polymers and methods thereof
patent, August 2018
- Kim, Yu Seung; Lee, Kwan-Soo; Fujimoto, Cy
- US Patent Document 10,053,535
Development of Novel Proton-conductive Polymers for Proton Exchange Membrane Fuel Cell (PEMFC) Technology
patent-application, March 2007
- Bae, Chulsung
- US Patent Application 11/512937; 20070048579
Anion Exchange Fuel Cell Membranes Prepared from C–H Borylation and Suzuki Coupling Reactions
journal, March 2014
- Mohanty, Angela D.; Lee, Yeong-Beom; Zhu, Liang
- Macromolecules, Vol. 47, Issue 6