Process for making propenyl ethers and photopolymerizable compositions containing them
Abstract
Propenyl ether monomers of formula A(OCH{double_bond}CHCH{sub 3}){sub n} (V) wherein n is an integer from one to six and A is selected from cyclic ethers, polyether, and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of formula V together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.
- Inventors:
- Issue Date:
- Research Org.:
- Rensselaer Polytechnic Inst
- OSTI Identifier:
- 187064
- Patent Number(s):
- 5486545
- Application Number:
- PAN: 8-232,507
- Assignee:
- Rensselaer Polytechnic Inst., Troy, NY (United States)
- DOE Contract Number:
- FG02-91ER12117
- Resource Type:
- Patent
- Resource Relation:
- Other Information: PBD: 23 Jan 1996
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 40 CHEMISTRY; ETHERS; CHEMICAL COMPOSITION; POLYMERIZATION; POLYETHYLENE GLYCOLS; PRODUCTION; RADIOLYSIS; USES; PROTECTIVE COATINGS; SEALING MATERIALS
Citation Formats
Crivello, J V. Process for making propenyl ethers and photopolymerizable compositions containing them. United States: N. p., 1996.
Web.
Crivello, J V. Process for making propenyl ethers and photopolymerizable compositions containing them. United States.
Crivello, J V. Tue .
"Process for making propenyl ethers and photopolymerizable compositions containing them". United States.
@article{osti_187064,
title = {Process for making propenyl ethers and photopolymerizable compositions containing them},
author = {Crivello, J V},
abstractNote = {Propenyl ether monomers of formula A(OCH{double_bond}CHCH{sub 3}){sub n} (V) wherein n is an integer from one to six and A is selected from cyclic ethers, polyether, and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of formula V together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 23 00:00:00 EST 1996},
month = {Tue Jan 23 00:00:00 EST 1996}
}
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