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Title: Mixed metal sorbents for CO2/H2O displacement desorption

Abstract

The disclosure generally relates to CCS sorbents, particularly for CO2/H2O displacement desorption process. The sorbents include an aluminum oxide support that includes two alkali metal salts impregnated on the support. The two alkali metals include a potassium metal salts and a second alkali metal salt which is not potassium. The second metal salt disrupts poisoning effects that degrade sorbent lifetime. The sorbents demonstrate improved CO2 loadings and better H2O/CO2 ratios, as well as improved stability. Compositions and methods of making are disclosed.

Inventors:
; ; ; ; ;
Issue Date:
Research Org.:
ExxonMobil Research and Engineering Company, Annadale, NJ (United States); TDA Research, Inc., Wheat Ridge, CO (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1860158
Patent Number(s):
11198109
Application Number:
15/910,159
Assignee:
ExxonMobil Research and Engineering Company (Annadale, NJ); TDA Research (Wheat Ridge, CO)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
DOE Contract Number:  
FE0012870
Resource Type:
Patent
Resource Relation:
Patent File Date: 03/02/2018
Country of Publication:
United States
Language:
English

Citation Formats

Bai, Chuansheng, Cunningham, Majosefina, McCall, Patrick P., Thomann, Hans, Elliott, Jeannine Elizabeth, and Nguyen, Vinh. Mixed metal sorbents for CO2/H2O displacement desorption. United States: N. p., 2021. Web.
Bai, Chuansheng, Cunningham, Majosefina, McCall, Patrick P., Thomann, Hans, Elliott, Jeannine Elizabeth, & Nguyen, Vinh. Mixed metal sorbents for CO2/H2O displacement desorption. United States.
Bai, Chuansheng, Cunningham, Majosefina, McCall, Patrick P., Thomann, Hans, Elliott, Jeannine Elizabeth, and Nguyen, Vinh. Tue . "Mixed metal sorbents for CO2/H2O displacement desorption". United States. https://www.osti.gov/servlets/purl/1860158.
@article{osti_1860158,
title = {Mixed metal sorbents for CO2/H2O displacement desorption},
author = {Bai, Chuansheng and Cunningham, Majosefina and McCall, Patrick P. and Thomann, Hans and Elliott, Jeannine Elizabeth and Nguyen, Vinh},
abstractNote = {The disclosure generally relates to CCS sorbents, particularly for CO2/H2O displacement desorption process. The sorbents include an aluminum oxide support that includes two alkali metal salts impregnated on the support. The two alkali metals include a potassium metal salts and a second alkali metal salt which is not potassium. The second metal salt disrupts poisoning effects that degrade sorbent lifetime. The sorbents demonstrate improved CO2 loadings and better H2O/CO2 ratios, as well as improved stability. Compositions and methods of making are disclosed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2021},
month = {12}
}

Works referenced in this record:

Simulated moving bed system for CO2 separation, and method of same
patent, September 2016


Rotary moving bed for CO2 separation and use of same
patent, January 2017


Circulating moving bed system for CO2 separation, and method of same
patent, December 2016


Reactor, CO2 sorbent system, and process of making H2 with simultaneous CO2 sorption
patent-application, October 2016


Carbon dioxide separation using adsorption with steam regeneration
patent, November 2016