Mixed metal sorbents for CO2/H2O displacement desorption
Abstract
The disclosure generally relates to CCS sorbents, particularly for CO2/H2O displacement desorption process. The sorbents include an aluminum oxide support that includes two alkali metal salts impregnated on the support. The two alkali metals include a potassium metal salts and a second alkali metal salt which is not potassium. The second metal salt disrupts poisoning effects that degrade sorbent lifetime. The sorbents demonstrate improved CO2 loadings and better H2O/CO2 ratios, as well as improved stability. Compositions and methods of making are disclosed.
- Inventors:
- Issue Date:
- Research Org.:
- ExxonMobil Research and Engineering Company, Annadale, NJ (United States); TDA Research, Inc., Wheat Ridge, CO (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1860158
- Patent Number(s):
- 11198109
- Application Number:
- 15/910,159
- Assignee:
- ExxonMobil Research and Engineering Company (Annadale, NJ); TDA Research (Wheat Ridge, CO)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
- DOE Contract Number:
- FE0012870
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 03/02/2018
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Bai, Chuansheng, Cunningham, Majosefina, McCall, Patrick P., Thomann, Hans, Elliott, Jeannine Elizabeth, and Nguyen, Vinh. Mixed metal sorbents for CO2/H2O displacement desorption. United States: N. p., 2021.
Web.
Bai, Chuansheng, Cunningham, Majosefina, McCall, Patrick P., Thomann, Hans, Elliott, Jeannine Elizabeth, & Nguyen, Vinh. Mixed metal sorbents for CO2/H2O displacement desorption. United States.
Bai, Chuansheng, Cunningham, Majosefina, McCall, Patrick P., Thomann, Hans, Elliott, Jeannine Elizabeth, and Nguyen, Vinh. Tue .
"Mixed metal sorbents for CO2/H2O displacement desorption". United States. https://www.osti.gov/servlets/purl/1860158.
@article{osti_1860158,
title = {Mixed metal sorbents for CO2/H2O displacement desorption},
author = {Bai, Chuansheng and Cunningham, Majosefina and McCall, Patrick P. and Thomann, Hans and Elliott, Jeannine Elizabeth and Nguyen, Vinh},
abstractNote = {The disclosure generally relates to CCS sorbents, particularly for CO2/H2O displacement desorption process. The sorbents include an aluminum oxide support that includes two alkali metal salts impregnated on the support. The two alkali metals include a potassium metal salts and a second alkali metal salt which is not potassium. The second metal salt disrupts poisoning effects that degrade sorbent lifetime. The sorbents demonstrate improved CO2 loadings and better H2O/CO2 ratios, as well as improved stability. Compositions and methods of making are disclosed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2021},
month = {12}
}
Works referenced in this record:
Simulated moving bed system for CO2 separation, and method of same
patent, September 2016
- Elliott, Jeannine Elizabeth; Copeland, Robert James; Lind, Jeff
- US Patent Document 9,446,343
Rotary moving bed for CO2 separation and use of same
patent, January 2017
- Elliott, Jeannine Elizabeth; Copeland, Robert James; McCall, Patrick P.
- US Patent Document 9,539,540
Alumina based adsorbent containing alkali metal compounds
patent, August 1999
- Kanazirev, Vladislav I.
- US Patent Document 5,935,894
Circulating moving bed system for CO2 separation, and method of same
patent, December 2016
- Elliott, Jeannine Elizabeth; Copeland, Robert James
- US Patent Document 9,527,029
Reactor, CO2 sorbent system, and process of making H2 with simultaneous CO2 sorption
patent-application, October 2016
- Liu, Wei; Li, Xiaohong Shari
- US Patent Application 15/012791; 20160304344
Carbon dioxide separation using adsorption with steam regeneration
patent, November 2016
- Elliott, Jeannine Elizabeth; Copeland, Robert James; Leta, Daniel P.
- US Patent Document 9,504,955