Porous Fe3O4/S composites for Li/S batteries

Abruna, Hector D.; Zhang, Na

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Title: Porous Fe3O4/S composites for Li/S batteries

Abstract

Provided are porous Fe3O4/sulfur composites. The composites are composed of porous Fe₃O₄ nanoparticles and sulfur, where the sulfur loading is 70-85% by weight based on the total weight of the composite. Also provided are batteries having cathodes containing porous FE₃O₄ composites of the present disclosure.

Inventors:: Abruna, Hector D.; Zhang, Na

Issue Date:: 2021-11-23

Research Org.:: Cornell Univ., Ithaca, NY (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1860103

Patent Number(s):: 11183688

Application Number:: 16/959,086

Assignee:: Cornell University (Ithaca, NY)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS

Show more

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B17/00 - Sulfur

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2004/64 - Nanometer sized, i.e. from 1-100 nanometer
C01P2006/12 - Surface area
C01P2006/16 - Pore diameter

C - CHEMISTRY C09 - DYES C09C - TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES
C09C1/24 - Oxides of iron

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M10/44 - Methods for charging or discharging
H01M2004/021 - {Physical characteristics, e.g. porosity, surface area}
H01M4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M4/364 - {as mixtures}
H01M4/38 - of elements or alloys
H01M4/483 - {for non-aqueous cells
H01M4/523 - {for non-aqueous cells

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

Show less

DOE Contract Number:: SC0001086

Resource Type:: Patent

Resource Relation:: Patent File Date: 12/31/2018

Country of Publication:: United States

Language:: English

Citation Formats


                    Abruna, Hector D., and Zhang, Na. Porous Fe3O4/S composites for Li/S batteries.  United States: N. p., 2021. 
        Web.

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                    Abruna, Hector D., & Zhang, Na. Porous Fe3O4/S composites for Li/S batteries.  United States.

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                    Abruna, Hector D., and Zhang, Na. Tue .  
        "Porous Fe3O4/S composites for Li/S batteries".  United States.  https://www.osti.gov/servlets/purl/1860103.

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@article{osti_1860103,

  title        = {Porous Fe3O4/S composites for Li/S batteries},

  author       = {Abruna, Hector D. and Zhang, Na},

  abstractNote = {Provided are porous Fe3O4/sulfur composites. The composites are composed of porous Fe3O4 nanoparticles and sulfur, where the sulfur loading is 70-85% by weight based on the total weight of the composite. Also provided are batteries having cathodes containing porous FE3O4 composites of the present disclosure.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2021},

  month        = {11}

}

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Similar Records

Title: Porous Fe3O4/S composites for Li/S batteries

Abstract

Citation Formats

Fe3O4@S nanoparticles embedded/coated on the multi-wall carbon nanotubes for rechargeable lithium batteries journal, February 2018

Ferromagnetic Nanoparticle-Assisted Polysulfide Trapping for Enhanced Lithium-Sulfur Batteries journal, April 2018

Elaborately Designed Micro–Mesoporous Graphitic Carbon Spheres as Efficient Polysulfide Reservoir for Lithium–Sulfur Batteries journal, April 2017

High capacity cathode patent, January 2018

Sulfur-loaded monodisperse carbon nanocapsules anchored on graphene nanosheets as cathodes for high performance lithium–sulfur batteries journal, January 2017

Fe-MOF derived jujube pit like Fe3O4/C composite as sulfur host for lithium-sulfur battery journal, February 2019

Improved lithium–sulfur batteries with a conductive coating on the separator to prevent the accumulation of inactive S-related species at the cathode–separator interface journal, January 2014

Polar and conductive iron carbide@N-doped porous carbon nanosheets as a sulfur host for high performance lithium sulfur batteries journal, February 2019

Lithium battery having a large capacity using Fe3O4 as a cathode material journal, August 2005

Porous nitrogen-doped carbon/MnO coaxial nanotubes as an efficient sulfur host for lithium sulfur batteries journal, September 2018

Porous Fe2O3 Doped Cathodes for Lithium-Sulfur Batteries journal, April 2014

Carbon-Metal Oxide-Sulfur Cathodes for High-Performance Lithium-Sulfur Batteries patent-application, August 2012

Lithium Sulfur Batteries and Electrolytes and Sulfur Cathodes Thereof patent-application, July 2015

Nano-sized γ-Fe2O3 as lithium battery cathode journal, August 2005

Titanium nitride hollow nanospheres with strong lithium polysulfide chemisorption as sulfur hosts for advanced lithium-sulfur batteries journal, March 2018

Process of Preparing a Chemically Pre-Formed (CPF) Iron Negative Electrode with Oxidizing Gases patent-application, March 2015

Process for Producing an Active Cathode Material Comprising a Mixture of a Metal Oxide and a Metal Sulfide and Use of the Active Cathode Material in Rechargeable Electrochemical Cells patent-application, June 2016

Electrospun carbon nanofibers decorated with MnO nanoparticles as a sulfur-absorbent for lithium-sulfur batteries journal, October 2018

Yolk-Shelled C@Fe 3 O 4 Nanoboxes as Efficient Sulfur Hosts for High-Performance Lithium-Sulfur Batteries journal, July 2017

Battery with an Iron Electrode Having a Fused Coating patent, April 1970

Effect of chemical oxidation for nano-size γ-Fe2O3 as lithium battery cathode journal, February 2007

Three-dimensionally ordered, ultrathin graphitic-carbon frameworks with cage-like mesoporosity for highly stable Li-S batteries journal, April 2017

Catalytic Effects in Lithium-Sulfur Batteries: Promoted Sulfur Transformation and Reduced Shuttle Effect journal, September 2017

Multi-Heteroatom-Doped Hollow Carbon Attached on Graphene Using LiFePO4 Nanoparticles as Hard Templates for High-Performance Lithium–Sulfur Batteries journal, July 2018

Surface Chemistry in Cobalt Phosphide-Stabilized Lithium–Sulfur Batteries journal, January 2018

Scalable Synthesis of Honeycomb-like Ordered Mesoporous Carbon Nanosheets and Their Application in Lithium–Sulfur Batteries journal, January 2017

Fe 3 O 4 -Decorated Porous Graphene Interlayer for High-Performance Lithium–Sulfur Batteries journal, July 2018

Prussian blue-derived Fe2O3/sulfur composite cathode for lithium–sulfur batteries journal, December 2014

Fe3O4@S nanoparticles embedded/coated on the multi-wall carbon nanotubes for rechargeable lithium batteries
journal, February 2018

Ferromagnetic Nanoparticle-Assisted Polysulfide Trapping for Enhanced Lithium-Sulfur Batteries
journal, April 2018

Elaborately Designed Micro–Mesoporous Graphitic Carbon Spheres as Efficient Polysulfide Reservoir for Lithium–Sulfur Batteries
journal, April 2017

High capacity cathode
patent, January 2018

Sulfur-loaded monodisperse carbon nanocapsules anchored on graphene nanosheets as cathodes for high performance lithium–sulfur batteries
journal, January 2017

Fe-MOF derived jujube pit like Fe3O4/C composite as sulfur host for lithium-sulfur battery
journal, February 2019

Improved lithium–sulfur batteries with a conductive coating on the separator to prevent the accumulation of inactive S-related species at the cathode–separator interface
journal, January 2014

Polar and conductive iron carbide@N-doped porous carbon nanosheets as a sulfur host for high performance lithium sulfur batteries
journal, February 2019

Lithium battery having a large capacity using Fe3O4 as a cathode material
journal, August 2005

Porous nitrogen-doped carbon/MnO coaxial nanotubes as an efficient sulfur host for lithium sulfur batteries
journal, September 2018

Porous Fe₂O₃ Doped Cathodes for Lithium-Sulfur Batteries
journal, April 2014

Carbon-Metal Oxide-Sulfur Cathodes for High-Performance Lithium-Sulfur Batteries
patent-application, August 2012

Lithium Sulfur Batteries and Electrolytes and Sulfur Cathodes Thereof
patent-application, July 2015

Nano-sized γ-Fe2O3 as lithium battery cathode
journal, August 2005

Titanium nitride hollow nanospheres with strong lithium polysulfide chemisorption as sulfur hosts for advanced lithium-sulfur batteries
journal, March 2018

Process of Preparing a Chemically Pre-Formed (CPF) Iron Negative Electrode with Oxidizing Gases
patent-application, March 2015

Process for Producing an Active Cathode Material Comprising a Mixture of a Metal Oxide and a Metal Sulfide and Use of the Active Cathode Material in Rechargeable Electrochemical Cells
patent-application, June 2016

Electrospun carbon nanofibers decorated with MnO nanoparticles as a sulfur-absorbent for lithium-sulfur batteries
journal, October 2018

Yolk-Shelled C@Fe ₃ O ₄ Nanoboxes as Efficient Sulfur Hosts for High-Performance Lithium-Sulfur Batteries
journal, July 2017

Battery with an Iron Electrode Having a Fused Coating
patent, April 1970

Effect of chemical oxidation for nano-size γ-Fe2O3 as lithium battery cathode
journal, February 2007

Three-dimensionally ordered, ultrathin graphitic-carbon frameworks with cage-like mesoporosity for highly stable Li-S batteries
journal, April 2017

Catalytic Effects in Lithium-Sulfur Batteries: Promoted Sulfur Transformation and Reduced Shuttle Effect
journal, September 2017

Multi-Heteroatom-Doped Hollow Carbon Attached on Graphene Using LiFePO₄ Nanoparticles as Hard Templates for High-Performance Lithium–Sulfur Batteries
journal, July 2018

Surface Chemistry in Cobalt Phosphide-Stabilized Lithium–Sulfur Batteries
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journal, January 2017

Fe ₃ O ₄ -Decorated Porous Graphene Interlayer for High-Performance Lithium–Sulfur Batteries
journal, July 2018

Prussian blue-derived Fe2O3/sulfur composite cathode for lithium–sulfur batteries
journal, December 2014