Composite bilayer coatings for high capacity cathodes and anodes
Abstract
An electrode comprises an electrode core. A composite bilayer coating is conformally disposed on the electrode core. The composite bilayer coating comprises a first layer disposed on at least a portion of the electrode core. The first layer comprises a metal fluoride, a metal oxide or a metal sulfide. A second layer is disposed on the first layer and comprises a metal fluoride, a metal oxide or a metal sulfide.
- Inventors:
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1860007
- Patent Number(s):
- 11158856
- Application Number:
- 15/968,314
- Assignee:
- UChicago Argonne, LLC (Chicago, IL)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AC02-06CH11357; W-31-109-ENG-38
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 05/01/2018
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Mane, Anil U., Croy, Jason R., Elam, Jeffrey W., and Balasubramanian, Mahalingam. Composite bilayer coatings for high capacity cathodes and anodes. United States: N. p., 2021.
Web.
Mane, Anil U., Croy, Jason R., Elam, Jeffrey W., & Balasubramanian, Mahalingam. Composite bilayer coatings for high capacity cathodes and anodes. United States.
Mane, Anil U., Croy, Jason R., Elam, Jeffrey W., and Balasubramanian, Mahalingam. Tue .
"Composite bilayer coatings for high capacity cathodes and anodes". United States. https://www.osti.gov/servlets/purl/1860007.
@article{osti_1860007,
title = {Composite bilayer coatings for high capacity cathodes and anodes},
author = {Mane, Anil U. and Croy, Jason R. and Elam, Jeffrey W. and Balasubramanian, Mahalingam},
abstractNote = {An electrode comprises an electrode core. A composite bilayer coating is conformally disposed on the electrode core. The composite bilayer coating comprises a first layer disposed on at least a portion of the electrode core. The first layer comprises a metal fluoride, a metal oxide or a metal sulfide. A second layer is disposed on the first layer and comprises a metal fluoride, a metal oxide or a metal sulfide.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2021},
month = {10}
}
Works referenced in this record:
Atomic Layer Deposition of LiF Thin Films from Lithd, Mg(thd) 2 , and TiF 4 Precursors
journal, April 2013
- Mäntymäki, Miia; Hämäläinen, Jani; Puukilainen, Esa
- Chemistry of Materials, Vol. 25, Issue 9
Ultrathin Direct Atomic Layer Deposition on Composite Electrodes for Highly Durable and Safe Li-Ion Batteries
journal, April 2010
- Jung, Yoon Seok; Cavanagh, Andrew S.; Riley, Leah A.
- Advanced Materials, Vol. 22, Issue 19
Advances in Stabilizing ‘Layered-Layered’ xLi2MnO3·(1-x)LiMO2(M=Mn, Ni, Co) Electrodes with a Spinel Component
journal, January 2014
- Long, Brandon R.; Croy, Jason R.; Park, Joong Sun
- Journal of The Electrochemical Society, Vol. 161, Issue 14, p. A2160-A2167
Amorphous Metal Fluoride Passivation Coatings Prepared by Atomic Layer Deposition on LiCoO 2 for Li-Ion Batteries
journal, March 2015
- Park, Joong Sun; Mane, Anil U.; Elam, Jeffrey W.
- Chemistry of Materials, Vol. 27, Issue 6
Method for Covering Particles, Especially a Battery Electrode Material Particles, and Particles Obtained with Such Method and a Battery Comprising Such Particle
patent-application, June 2009
- Kelder, Erik Maria; Van Ommen, Jan Rudolf; Nijenhuis, John
- US Patent Application 11/955184; 20090155590
(Invited) Synthesis, Characterization, and Application of Tunable Resistance Coatings Prepared by Atomic Layer Deposition
journal, August 2013
- Elam, J. W.; Mane, A. U.; Libera, J. A.
- ECS Transactions, Vol. 58, Issue 10
Mechanistic Study of Lithium Aluminum Oxide Atomic Layer Deposition
journal, January 2013
- Comstock, David J.; Elam, Jeffrey W.
- The Journal of Physical Chemistry C, Vol. 117, Issue 4
Tunable Resistance Coatings
patent-application, December 2013
- Elam, Jeffrey W.; Mane, Anil U.
- US Patent Application 13/525067; 20130335190
Microchannel Plate Detector and Methods for Their Fabrication
patent-application, July 2012
- Elam, Jeffrey W.; Mane, Anil U.; Peng, Qing
- US Patent Application 13/011645; 20120187305
Studies of LiCoO[sub 2] Coated with Metal Oxides
journal, January 2003
- Chen, Zhaohui; Dahn, J. R.
- Electrochemical and Solid-State Letters, Vol. 6, Issue 11
Atomic Layer Deposition of MgF 2 Thin Films Using TaF 5 as a Novel Fluorine Source
journal, August 2008
- Pilvi, Tero; Puukilainen, Esa; Kreissig, Ulrich
- Chemistry of Materials, Vol. 20, Issue 15
Materials for Solid State Electrolytes and Protective Electrode Coatings for Lithium Batteries
patent-application, December 2015
- Elam, Jeffrey W.; Meng, Xiangbo
- US Patent Application 14/711504; 20150364747
Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries
journal, January 2012
- Thackeray, Michael M.; Wolverton, Christopher; Isaacs, Eric D.
- Energy & Environmental Science, Vol. 5, Issue 7
Tunable resistance coatings
patent, December 2014
- Elam, Jeffrey W.; Mane, Anil U.
- US Patent Document 8,921,799
Improving the Capacity Retention of LiCoO[sub 2] Cycled to 4.5 V by Heat-Treatment
journal, January 2004
- Chen, Zhaohui; Dahn, J. R.
- Electrochemical and Solid-State Letters, Vol. 7, Issue 1
Ultrathin Lithium-Ion Conducting Coatings for Increased Interfacial Stability in High Voltage Lithium-Ion Batteries
journal, May 2014
- Park, Joong Sun; Meng, Xiangbo; Elam, Jeffrey W.
- Chemistry of Materials, Vol. 26, Issue 10
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Atomic Layer Deposition of W:Al 2 O 3 Nanocomposite Films with Tunable Resistivity
journal, May 2013
- Mane, Anil U.; Elam, Jeffrey W.
- Chemical Vapor Deposition, Vol. 19, Issue 4-6
Electrode Material with Core-Shell Structure
patent-application, August 2012
- Richard, Monique N.
- US Patent Application 13/018989; 20120196186
Atomic Layer Deposition: An Overview
journal, January 2010
- George, Steven M.
- Chemical Reviews, Vol. 110, Issue 1, p. 111-131
Multifunctional Hybrid Coatings for Electrodes Made by Atomic Layer Deposition Techniques
patent-application, June 2015
- Xiao, Xingcheng; Verbrugge, Mark W.; Wang, John S.
- US Patent Application 14/138267; 20150180023
Switchable hydrophobic-hydrophilic layer obtained onto porous alumina by plasma-enhanced fluorination
journal, January 2009
- Tressaud, A.; Labrugère, C.; Durand, E.
- Science in China Series E: Technological Sciences, Vol. 52, Issue 1
Atomic Layer Deposition of Amorphous Niobium Carbide-Based Thin Film Superconductors
journal, November 2011
- Klug, Jeffrey A.; Proslier, Thomas; Elam, Jeffrey W.
- The Journal of Physical Chemistry C, Vol. 115, Issue 50
Coatings for Lithium Titanate to Suppress Gas Generation in Lithium-Ion Batteries and Methods for Making and Use Thereof
patent-application, April 2014
- Xiao, Xingcheng; Verbrugge, Mark W.; Wang, John S.
- US Patent Application 13/654905; 20140113197
Cathode Active Material Coated With Fluorine Compound for Lithium Secondary Batteries and Method for Preparing the Same
patent-application, April 2009
- Sun, Yang Kook; Kim, Woo Seong; Han, Jung Min
- US Patent Application 11/918163; 20090087362
Role of surface coating on cathode materials for lithium-ion batteries
journal, January 2010
- Chen, Zonghai; Qin, Yan; Amine, Khalil
- Journal of Materials Chemistry, Vol. 20, Issue 36, p. 7606-7612
Metal Fluoride Passivation Coatings Prepared by Atomic Layer Deposition on LiCoO2 for Li-Ion Batteries
patent-application, September 2016
- mane, Anil U.; Elam, Jeffrey W.; Park, Joong Sunb
- US Patent Application 14/693719; 20160260962
Atomic layer deposition of solid-state electrolyte coated cathode materials with superior high-voltage cycling behavior for lithium ion battery application
journal, January 2014
- Li, Xifei; Liu, Jian; Banis, Mohammad Norouzi
- Energy Environ. Sci., Vol. 7, Issue 2
Atomic layer deposition process with TiF_4 as a precursor for depositing metal fluoride thin films
journal, January 2008
- Pilvi, Tero; Ritala, Mikko; Leskelä, Markku
- Applied Optics, Vol. 47, Issue 13
Microstructure of LiCoO 2 with and without “AlPO 4 ” Nanoparticle Coating: Combined STEM and XPS Studies
journal, November 2007
- Appapillai, Anjuli T.; Mansour, Azzam N.; Cho, Jaephil
- Chemistry of Materials, Vol. 19, Issue 23
TEM Study of Electrochemical Cycling-Induced Damage and Disorder in LiCoO[sub 2] Cathodes for Rechargeable Lithium Batteries
journal, January 1999
- Wang, Haifeng
- Journal of The Electrochemical Society, Vol. 146, Issue 2
Atomic layer-deposited tunnel oxide stabilizes silicon photoanodes for water oxidation
journal, June 2011
- Chen, Yi Wei; Prange, Jonathan D.; Dühnen, Simon
- Nature Materials, Vol. 10, Issue 7
Cathode materials modified by surface coating for lithium ion batteries
journal, May 2006
- Li, C.; Zhang, H. P.; Fu, L. J.
- Electrochimica Acta, Vol. 51, Issue 19
Towards systems materials engineering
journal, July 2012
- Yang, Peidong; Tarascon, Jean-Marie
- Nature Materials, Vol. 11, Issue 7, p. 560-563
Significant improvement of high voltage cycling behavior AlF3-coated LiCoO2 cathode
journal, May 2006
- Sun, Y.; Han, J.; Myung, S.
- Electrochemistry Communications, Vol. 8, Issue 5, p. 821-826
Atomic Layer Deposition of Lithium Tantalate Solid-State Electrolytes
journal, September 2013
- Liu, Jian; Banis, Mohammad N.; Li, Xifei
- The Journal of Physical Chemistry C, Vol. 117, Issue 39
Enhanced Stability of LiCoO2 Cathodes in Lithium-Ion Batteries Using Surface Modification by Atomic Layer Deposition
journal, January 2010
- Jung, Yoon Seok; Cavanagh, Andrew S.; Dillon, Anne C.
- Journal of The Electrochemical Society, Vol. 157, Issue 1, p. A75-A81
Uniform Stabilization Nanocoatings for Lithium Rich Complex Metal Oxides and Atomic Layer Deposition for Forming the Coating
patent-application, October 2014
- Li, Bing; Amiruddin, Shabab; Dalavi, Swapnil
- US Patent Application 13/859070; 20140302392
Lithium secondary battery containing capsule for controlled-release of additives
patent-application, January 2007
- Lee, Hochun; Kim, Hyeongjin
- US Patent Application 11/484931; 20070015048
Atomic Layer Deposition of MgO Using Bis(ethylcyclopentadienyl)magnesium and H2O
journal, January 2009
- Burton, B. B.; Goldstein, D. N.; George, S. M.
- The Journal of Physical Chemistry C, Vol. 113, Issue 5
Metal Fluoride Thin Films Prepared by Atomic Layer Deposition
journal, May 1994
- Ylilammi, M.; Ranta‐aho, T.
- Journal of The Electrochemical Society, Vol. 141, Issue 5
Advanced cathode materials for lithium-ion batteries
journal, July 2011
- Chen, Zonghai; Lee, Dong-Ju; Sun, Yang-Kook
- MRS Bulletin, Vol. 36, Issue 7
Roles of Surface Chemistry on Safety and Electrochemistry in Lithium Ion Batteries
journal, April 2012
- Lee, Kyu Tae; Jeong, Sookyung; Cho, Jaephil
- Accounts of Chemical Research, Vol. 46, Issue 5
The Role of AlF3 Coatings in Improving Electrochemical Cycling of Li-Enriched Nickel-Manganese Oxide Electrodes for Li-Ion Batteries
journal, February 2012
- Sun, Yang-Kook; Lee, Min-Joon; Yoon, Chong S.
- Advanced Materials, Vol. 24, Issue 9