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Title: Self-assembly assisted additive manufacturing of thermosets

Abstract

The present invention relates to formulations including a self-assembly monomer. In particular embodiments, the self-assembly monomer provides a thermoset having beneficial viscoelastic properties for printing methodologies. Methods of making and using such formulations are also provided.

Inventors:
; ;
Issue Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1859962
Patent Number(s):
11149108
Application Number:
16/453,431
Assignee:
National Technology & Engineering Solutions of Sandia, LLC (Albuquerque, NM)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B29 - WORKING OF PLASTICS B29C - SHAPING OR JOINING OF PLASTICS
B - PERFORMING OPERATIONS B33 - ADDITIVE MANUFACTURING TECHNOLOGY B33Y - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
DOE Contract Number:  
NA0003525
Resource Type:
Patent
Resource Relation:
Patent File Date: 06/26/2019
Country of Publication:
United States
Language:
English

Citation Formats

Manning, Kylie, Celina, Mathias C., and Cook, Adam. Self-assembly assisted additive manufacturing of thermosets. United States: N. p., 2021. Web.
Manning, Kylie, Celina, Mathias C., & Cook, Adam. Self-assembly assisted additive manufacturing of thermosets. United States.
Manning, Kylie, Celina, Mathias C., and Cook, Adam. Tue . "Self-assembly assisted additive manufacturing of thermosets". United States. https://www.osti.gov/servlets/purl/1859962.
@article{osti_1859962,
title = {Self-assembly assisted additive manufacturing of thermosets},
author = {Manning, Kylie and Celina, Mathias C. and Cook, Adam},
abstractNote = {The present invention relates to formulations including a self-assembly monomer. In particular embodiments, the self-assembly monomer provides a thermoset having beneficial viscoelastic properties for printing methodologies. Methods of making and using such formulations are also provided.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2021},
month = {10}
}

Works referenced in this record:

Molecular self-assembly and patterning induced by sound waves. The case of gelation
journal, January 2009


Two-Fluid Hydrodynamic Printing
patent-application, May 2016


A review on 3D micro-additive manufacturing technologies
journal, November 2012


Thermochromic Block Copolymer Photonic Gel
journal, July 2008


Effect of ultrasound sonication in nanoclay clusters of nanoclay/epoxy composites
journal, May 2005


Exploring the Role of Supramolecular Associations in Mechanical Toughening of Interpenetrating Polymer Networks
journal, September 2015


Unidirectional Dimerization and Stacking of Ureidopyrimidinone End Groups in Polycaprolactone Supramolecular Polymers
journal, November 2007


Aggregation of Ureido-Pyrimidinone Supramolecular Thermoplastic Elastomers into Nanofibers: A Kinetic Analysis
journal, September 2011


Electrical and Mechanical Properties of 3D-Printed Graphene-Reinforced Epoxy
journal, December 2017


High impact resistance epoxy resins by incorporation of quadruply hydrogen bonded supramolecular polymers
journal, May 2016


Engineering Orthogonality in Supramolecular Polymers: From Simple Scaffolds to Complex Materials
journal, June 2014


Supramolecular engineering polyesters: endgroup functionalization of glycol modified PET with ureidopyrimidinone
journal, January 2016


Multi-Responsive Wrinkling Patterns by the Photoswitchable Supramolecular Network
journal, July 2017


Apparatus for pneumatic shuttering of an aerosol particle stream
patent, August 2018


Waterproof characteristics of nanoclay/epoxy nanocomposite in adhesively bonded joints
journal, December 2013


High performance polymer nanocomposites for additive manufacturing applications
journal, June 2016


Process for epoxy foam production
patent, August 2011


Functional Supramolecular Polymers
journal, February 2012


Fracture toughness of the nano-particle reinforced epoxy composite
journal, November 2008


Curable Epoxy Resin Compositions and Cured Products Therefrom
patent-application, January 2012


Effect Of Nanoclay On The Toughness Of Epoxy And Mechanical, Impact Properties Of E-glass-epoxy Composites
journal, August 2015


Probing the Interplay of Ultraviolet Cross-Linking and Noncovalent Interactions in Supramolecular Elastomers
journal, August 2014


High-strength epoxy nanocomposites for 3D printing
journal, May 2018


Amine-Catalyzed Thiol-Curing of Epoxide Resins
patent-application, June 2017


Two-component adhesive of epoxy resins and amine compound
patent, March 2009


Superior relaxation of stresses and self-healing behavior of epoxy-amine coatings
journal, January 2016


Mechanically Induced Gelation of a Kinetically Trapped Supramolecular Polymer
journal, November 2014


Hydrogen bonding in polymers. 4. Infrared temperature studies of a simple polyurethane
journal, August 1986


Supramolecular Polymers: Historical Development, Preparation, Characterization, and Functions
journal, March 2015


Supramolecular Polymers
journal, December 2001


An overview of high temperature micro-ATR IR spectroscopy to monitor polymer reactions
journal, September 2012


Airfoil-shaped micro-mixers for reducing fouling on membrane surfaces
patent, October 2012


Combined Effect of Chain Extension and Supramolecular Interactions on Rheological and Adhesive Properties of Acrylic Pressure-Sensitive Adhesives
journal, November 2016


Fabrication of tough epoxy with shape memory effects by UV-assisted direct-ink write printing
journal, January 2018


Hierarchical Co-Assembly Enhanced Direct Ink Writing
journal, March 2018


Extreme wet adhesion of a novel epoxy-amine coating on aluminum alloy 2024-T3
journal, January 2014


Epoxy-based networks combining chemical and supramolecular hydrogen-bonding crosslinks
journal, January 2010


Tool Path Generator with Embedded Process Control Commands for Additive Manufacturing
patent-application, March 2017


Adaptive bio-based polyurethane elastomers engineered by ionic hydrogen bonding interactions
journal, June 2017


3D Printing of Biocompatible Supramolecular Polymers and their Composites
journal, January 2016


Mechanical properties of epoxy-based composites using nanoclays
journal, September 2006


Biomimetic Design of Reversibly Unfolding Cross-Linker to Enhance Mechanical Properties of 3D Network Polymers
journal, October 2007


Self Assembly–Assisted Additive Manufacturing: Direct Ink Write 3D Printing of Epoxy–Amine Thermosets
journal, December 2018


Recyclable 3D printing of vitrimer epoxy
journal, January 2017


3D Printing of Free Standing Liquid Metal Microstructures
journal, July 2013


Supramolecular polymers at work
journal, April 2004


Probing the solvent-induced tautomerism of a redox-active ureidopyrimidinone
journal, January 2007


UV-Assisted 3D Printing of Glass and Carbon Fiber-Reinforced Dual-Cure Polymer Composites
journal, July 2016


Use of Molecules having Associative Groups as Hardeners for Thermosetting Resin
patent-application, March 2012


Direct Ink Writing of 3D Functional Materials
journal, November 2006


Two-fluid hydrodynamic printing
patent, November 2018


Direct Ink Writing of Three-Dimensional Ceramic Structures
journal, December 2006


3D-Printing of Lightweight Cellular Composites
journal, June 2014


Spectroscopic analysis of phase separation behavior of model polyurethanes
journal, September 1987


Method of making a cyanate ester foam
patent, August 2014


Novel self-assembled dynamic [2]catenanes interlocked by the quadruple hydrogen bonding ureidopyrimidinone motif
journal, January 2012


3D Printing of Highly Stretchable, Shape-Memory, and Self-Healing Elastomer toward Novel 4D Printing
journal, February 2018


Epoxy Adhesive, Manufacture and Use Thereof
patent-application, February 2015


Synthesis and characterization of poly(2-ethylhexyl methacrylate) copolymers containing pendant, self-complementary multiple-hydrogen-bonding sites
journal, January 2005


Epoxy Resin-Inspired Reconfigurable Supramolecular Networks
journal, October 2016


N,N-Disubstituted Ureas: Influence of Substituents on the Formation of Supramolecular Polymers
journal, July 2003


Extended amine curing agents and epoxy resins cured therewith
patent, November 1985


Multi-component Nanoinks for Direct Write Applications
patent-application, June 2017


Polymers for 3D Printing and Customized Additive Manufacturing
journal, July 2017


3D printing with polymers: Challenges among expanding options and opportunities
journal, January 2016


Mechanism of reinforcement in a nanoclay/polymer composite
journal, September 2011


Light-Adaptive Supramolecular Nacre-Mimetic Nanocomposites
journal, July 2016


Amine curable compositions
patent, July 1996


Supramolecular polymerization of a ureidopyrimidinone-based [2]catenane prepared via ring-closing metathesis
journal, July 2017

  • Teunissen, Abraham J. P.; Berrocal, José Augusto; Corbet, Christiaan H. W. A.
  • Journal of Polymer Science Part A: Polymer Chemistry, Vol. 55, Issue 18
  • https://doi.org/10.1002/pola.28694

3D-printable CFR polymer composites with dual-cure sequential IPNs
journal, May 2016


Stability and Lifetime of Quadruply Hydrogen Bonded 2-Ureido-4[1 H ]-pyrimidinone Dimers
journal, August 2000

  • Söntjens, Serge H. M.; Sijbesma, Rint P.; van Genderen, Marcel H. P.
  • Journal of the American Chemical Society, Vol. 122, Issue 31
  • https://doi.org/10.1021/ja000435m

Self-consuming materials
patent, May 2017


Additive Manufacturing With Conductive, Viscoelastic Polymer Composites: Direct-Ink-Writing of Electrolytic and Anodic Poly(Ethylene Oxide) Composites
journal, September 2017


3D-Printing of Meso-structurally Ordered Carbon Fiber/Polymer Composites with Unprecedented Orthotropic Physical Properties
journal, March 2017


Mechanism of Shear Thickening in Reversibly Cross-Linked Supramolecular Polymer Networks
journal, April 2010


Tough Stimuli-Responsive Supramolecular Hydrogels with Hydrogen-Bonding Network Junctions
journal, May 2014


3D printing of polymer matrix composites: A review and prospective
journal, February 2017


3D Printing Polymers with Supramolecular Functionality for Biological Applications
journal, August 2017


Strong Dimerization of Ureidopyrimidones via Quadruple Hydrogen Bonding
journal, July 1998


Epoxy Resin Compositions
patent-application, December 2012


Dendronized Organoplatinum(II) Metallacyclic Polymers Constructed by Hierarchical Coordination-Driven Self-Assembly and Hydrogen-Bonding Interfaces
journal, November 2013


Binary Cellulose Nanocrystal Blends for Bioinspired Damage Tolerant Photonic Films
journal, May 2018


Amine hardener for epoxy resins
patent, May 2007


Hierarchical Nacre Mimetics with Synergistic Mechanical Properties by Control of Molecular Interactions in Self-Healing Polymers
journal, June 2015


Ultraviolet-Assisted Direct-Write Fabrication of Carbon Nanotube/Polymer Nanocomposite Microcoils
journal, February 2010


3D printing of high performance cyanate ester thermoset polymers
journal, January 2018


Water based coating composition
patent, June 2003


Facile Routes to Patterned Surface Neutralization Layers for Block Copolymer Lithography
journal, December 2007


Airfoil-Shaped Micro-Mixers for Reducing Fouling on Membrane Surfaces
patent-application, May 2010


Rheology of non-Newtonian fluids: A new flow equation for pseudoplastic systems
journal, June 1965


Three-Dimensional Printing of Shape Memory Composites with Epoxy-Acrylate Hybrid Photopolymer
journal, January 2017