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Title: High efficiency electrolytes for high voltage battery systems

Abstract

Disclosed herein are embodiments of an electrolyte that is stable and efficient at high voltages. The electrolyte can be used in combination with certain cathodes that exhibit poor activity at such high voltages with other types of electrolytes and can further be used in combination with a variety of anodes. In some embodiments, the electrolyte can be used in battery systems comprising a lithium cobalt oxide cathode and lithium metal anodes, silicon anodes, silicon/graphite composite anodes, graphite anodes, and the like.

Inventors:
; ;
Issue Date:
Research Org.:
US Department of Energy (USDOE), Washington, DC (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1840363
Patent Number(s):
11094966
Application Number:
16/230,531
Assignee:
Battelle Memorial Institute (Richland, WA)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Patent
Resource Relation:
Patent File Date: 12/21/2018
Country of Publication:
United States
Language:
English

Citation Formats

Ren, Xiaodi, Xu, Wu, and Zhang, Ji-Guang. High efficiency electrolytes for high voltage battery systems. United States: N. p., 2021. Web.
Ren, Xiaodi, Xu, Wu, & Zhang, Ji-Guang. High efficiency electrolytes for high voltage battery systems. United States.
Ren, Xiaodi, Xu, Wu, and Zhang, Ji-Guang. Tue . "High efficiency electrolytes for high voltage battery systems". United States. https://www.osti.gov/servlets/purl/1840363.
@article{osti_1840363,
title = {High efficiency electrolytes for high voltage battery systems},
author = {Ren, Xiaodi and Xu, Wu and Zhang, Ji-Guang},
abstractNote = {Disclosed herein are embodiments of an electrolyte that is stable and efficient at high voltages. The electrolyte can be used in combination with certain cathodes that exhibit poor activity at such high voltages with other types of electrolytes and can further be used in combination with a variety of anodes. In some embodiments, the electrolyte can be used in battery systems comprising a lithium cobalt oxide cathode and lithium metal anodes, silicon anodes, silicon/graphite composite anodes, graphite anodes, and the like.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Aug 17 00:00:00 EDT 2021},
month = {Tue Aug 17 00:00:00 EDT 2021}
}

Works referenced in this record:

High rate and stable cycling of lithium metal anode
journal, February 2015


Lithium-Ion Electrolytes Containing Flame-Retardant Additives for Increased Safety Characteristics
journal, August 2009


Dimethyl methylphosphonate (DMMP) as an efficient flame retardant additive for the lithium-ion battery electrolytes
journal, November 2007


Tris(2,2,2-trifluoroethyl) phosphite as a co-solvent for nonflammable electrolytes in Li-ion batteries
journal, January 2003


Determining oxidative stability of battery electrolytes: validity of common electrochemical stability window (ESW) data and alternative strategies
journal, January 2017


Electrolyte additive enabled fast charging and stable cycling lithium metal batteries
journal, March 2017


Electrochemical performance of lithium-ion batteries with triphenylphosphate as a flame-retardant additive
journal, October 2007


Electrolyte System for High Voltage Lithium Ion Battery
patent-application, August 2016


Review—Superconcentrated Electrolytes for Lithium Batteries
journal, January 2015


Lithium Metal Battery
patent-application, March 2017


Lithium Metal Battery
patent-application, April 2017


Flame-retardant additives for lithium-ion batteries
journal, June 2003


A Novel Flame-Retardant Additive for Lithium Batteries
journal, January 1999


The Evaluation of Triphenyl Phosphate as A Flame Retardant Additive to Improve The Safety of Lithium-Ion Battery Electrolytes
journal, April 2011


Thermal Behavior of Charged Graphite and Li[sub x]CoO[sub 2] in Electrolytes Containing Alkyl Phosphate for Lithium-Ion Cells
journal, January 2009


"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries
journal, November 2015


Lithium metal anodes for rechargeable batteries
journal, January 2014


Nonaqueous electrolyte battery
patent-application, August 2011


A highly safe battery with a non-flammable triethyl-phosphate-based electrolyte
journal, January 2015


Flame retardant battery
patent, August 2014


Electrolyte for a Lithium Ion Battery
patent-application, May 2011


Electrolyte System for Lithium Metal Secondary Battery and Lithium Metal Secondary Battery Including the Same
patent-application, November 2018


Nonflammable Electrolytes for Li-Ion Batteries Based on a Fluorinated Phosphate
journal, January 2002


Secondary Battery
patent-application, December 2017


Nonflammable Trimethyl Phosphate Solvent-Containing Electrolytes for Lithium-Ion Batteries: I. Fundamental Properties
journal, January 2001


Nonflammable Trimethyl Phosphate Solvent-Containing Electrolytes for Lithium-Ion Batteries: II. The Use of an Amorphous Carbon Anode
journal, January 2001


Ionic Liquid Electrolyte and Fluorinated Carbon Electrode
patent-application, December 2015


Solvate Ionic Liquid Electrolyte for Li–S Batteries
journal, January 2013


Fire-extinguishing organic electrolytes for safe batteries
journal, November 2017


Electrolyte for Stable Cycling of Rechargeable Alkali Metal and Alkali Ion Batteries
patent-application, May 2020


Lithium Metal Battery
patent-application, November 2017


Electrolyte for Electrochemical Energy Storage Devices
patent-application, January 2016


Electrolyte for Lithium Second Battery, and Lithium Second Battery Comprising the Electrolyte
patent-application, October 2016


Low Flammability Electrolytes for Stable Operation of Electrochemical Devices
patent-application, September 2018


Localized Superconcentrated Electrolytes for Silicon Anodes
patent-application, May 2019


Self-extinguishing electrolytes using fluorinated alkyl phosphates for lithium batteries
journal, January 2017


Flame Retardant Electrolyte for Rechargeable Lithium Battery and Rechargeable Lithium Battery Including the Same
patent-application, August 2010


Tumorigenesis protein
patent, November 1998


High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes
journal, March 2018


Low Flammability Electrolytes for Stable Operation of Lithium and Sodium Ion Batteries
patent-application, April 2019


Dilution of Highly Concentrated LiBF 4 /Propylene Carbonate Electrolyte Solution with Fluoroalkyl Ethers for 5-V LiNi 0.5 Mn 1.5 O 4 Positive Electrodes
journal, January 2017


Electrolyte Structure for Metal Batteries
patent-application, September 2016


Lithium-Ion Electrolytes with Improved Safety Tolerance to High Voltage Systems
patent-application, June 2012


High Coulombic Efficiency Cycling of Metal Batteries
patent-application, August 2016


Lithium Secondary Batteries Containing Lithium Salt-ionic Liquid Solvent Electrolyte
patent-application, November 2014


Li + -Desolvation Dictating Lithium-Ion Battery’s Low-Temperature Performances
journal, November 2017


Lithium Energy Storage Device
patent-application, May 2014


Negative Electrode for Lithium Battery and Lithium Battery Comprisin the Same
patent-application, November 2016


Lithium Metal Battery
patent-application, November 2016


High Salt Concentration Electrolytes For Rechargeable Lithium Battery
patent-application, August 2016


Localized Superconcentrated Electrolytes for Stable Cycling of Electrochemical Devices
patent-application, September 2018


Alkali metal/niobium triselenide cell having a dioxolane-based electrolyte
patent, April 1978


Nonaqueous Electrolyte Solution and Secondary Battery Using the Electrolyte Solution
patent-application, October 2007


An Attempt to Formulate Nonflammable Lithium Ion Electrolytes with Alkyl Phosphates and Phosphazenes
journal, January 2002


Electrolyte Solution and Secondary Battery Using Same
patent-application, June 2017


Superconcentrated electrolytes for a high-voltage lithium-ion battery
journal, June 2016


Negative Electrode for Ltihium Metal Battery and Lithium Metal Battery Including the Same
patent-application, December 2016


Effects of Carbonate Solvents and Lithium Salts on Morphology and Coulombic Efficiency of Lithium Electrode
journal, January 2013


Methylene ethylene carbonate: Novel additive to improve the high temperature performance of lithium ion batteries
journal, June 2012