Title: Biodegradable surfactants and related compositions, methods and systems

Abstract

Biodegradable surfactants are described, in which an amphiphilic heteroatom containing hydrocarbon optionally comprising at least one counterion (Z), and related compositions, methods and systems. Biodegradable surfactant described herein has an aHLB value in accordance with equation (1): aHLB=20*Gh/(Gh−Gt) (1) wherein Gh is the Group Number of a hydrophilic head portion of the biodegradable surfactant optionally comprising the at least one counterion (Z), and Gt is the Group Number of a hydrophobic tail portion of the biodegradable surfactant. A biodegradable surfactant in the sense of the disclosure can be tuned to a set hydrophilic-lipophilic balance (aHLB) by selectively modifying at least one tuning moiety of the biodegradable surfactants to provide tuned biodegradable surfactants having an increase or decrease in their adjusted hydrophilic-lipophilic balance (aHLB).

Inventors:

Lyman, Mathew Gerald; Dugan, Lawrence C.; Leif, Roald N.; Rubinfeld, Bonnee; Souza, Brian E.; Valdez, Carlos A.

Issue Date:

2021-07-20

Research Org.:

Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Org.:

USDOE

OSTI Identifier:

1840272

Patent Number(s):

11066359

Application Number:

16/484,817

Assignee:

Lawrence Livermore National Security, LLC (Livermore, CA)

Patent Classifications (CPCs):

A - HUMAN NECESSITIES A61 - MEDICAL OR VETERINARY SCIENCE A61K - PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES

A - HUMAN NECESSITIES A61 - MEDICAL OR VETERINARY SCIENCE A61Q - SPECIFIC USE OF COSMETICS OR SIMILAR TOILET PREPARATIONS

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A - HUMAN NECESSITIES A61 - MEDICAL OR VETERINARY SCIENCE A61K - PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES

A61K2800/596 - Mixtures of surface active compounds
A61K8/375 - {the alcohol moiety containing more than one hydroxy group}
A61K8/416 - {Quaternary ammonium compounds
A61K8/42 - Amides
A61K8/466 - {containing sulfonic acid derivatives
A61K8/608 - {Derivatives containing from 2 to 10 oxyalkylene groups}

A - HUMAN NECESSITIES A61 - MEDICAL OR VETERINARY SCIENCE A61Q - SPECIFIC USE OF COSMETICS OR SIMILAR TOILET PREPARATIONS

A61Q11/00 - Preparations for care of the teeth, of the oral cavity or of dentures
A61Q19/10 - Washing or bathing preparations
A61Q5/02 - Preparations for cleaning the hair

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C305/04 - being acyclic and saturated
C07C305/06 - Hydrogenosulfates
C07C69/533 - Monocarboxylic acid esters having only one carbon-to-carbon double bond
C07C69/675 - of saturated hydroxy-carboxylic acids
C07C69/708 - Ethers

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DOE Contract Number:  

AC52-07NA27344

Resource Type:

Patent

Resource Relation:

Patent File Date: 02/08/2018

Country of Publication:

United States

Language:

English