Molecularly tunable heterogeneous catalysts by edge functionalization of graphitic carbons
Abstract
Disclosed are surface immobilized (electro)catalysts that may be prepared by a condensation reaction that generates an aromatic unit that is robust to acid and base and elevated temperatures. Among their many desirable characteristics, the catalysts are far less prone to the bimolecular deactivation pathways commonly observed for homogeneous catalysts, and may be used in solvents with a range of polarities and dielectric strengths. The catalysts are suitable for a wide array of thermal catalytic reactions (polymerization, oxidation, hydrogenation, cross-coupling etc.) and as anodes and/or cathodes in fuel cells, electrolyzers, and in batteries and supercapacitors.
- Inventors:
- Issue Date:
- Research Org.:
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1823950
- Patent Number(s):
- 11005108
- Application Number:
- 15/236,963
- Assignee:
- Massachusetts Institute of Technology (Cambridge, MA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- DOE Contract Number:
- SC0014176
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 08/15/2016
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Surendranath, Yogesh, Fukushima, Tomohiro, O'Reilly, Matthew E., Oh, Seokjoon, Murray, Alexander T., Kaminsky, Corey Jarin, Chu, Sterling Ben, and Jackson, Jr., Megan N.. Molecularly tunable heterogeneous catalysts by edge functionalization of graphitic carbons. United States: N. p., 2021.
Web.
Surendranath, Yogesh, Fukushima, Tomohiro, O'Reilly, Matthew E., Oh, Seokjoon, Murray, Alexander T., Kaminsky, Corey Jarin, Chu, Sterling Ben, & Jackson, Jr., Megan N.. Molecularly tunable heterogeneous catalysts by edge functionalization of graphitic carbons. United States.
Surendranath, Yogesh, Fukushima, Tomohiro, O'Reilly, Matthew E., Oh, Seokjoon, Murray, Alexander T., Kaminsky, Corey Jarin, Chu, Sterling Ben, and Jackson, Jr., Megan N.. Tue .
"Molecularly tunable heterogeneous catalysts by edge functionalization of graphitic carbons". United States. https://www.osti.gov/servlets/purl/1823950.
@article{osti_1823950,
title = {Molecularly tunable heterogeneous catalysts by edge functionalization of graphitic carbons},
author = {Surendranath, Yogesh and Fukushima, Tomohiro and O'Reilly, Matthew E. and Oh, Seokjoon and Murray, Alexander T. and Kaminsky, Corey Jarin and Chu, Sterling Ben and Jackson, Jr., Megan N.},
abstractNote = {Disclosed are surface immobilized (electro)catalysts that may be prepared by a condensation reaction that generates an aromatic unit that is robust to acid and base and elevated temperatures. Among their many desirable characteristics, the catalysts are far less prone to the bimolecular deactivation pathways commonly observed for homogeneous catalysts, and may be used in solvents with a range of polarities and dielectric strengths. The catalysts are suitable for a wide array of thermal catalytic reactions (polymerization, oxidation, hydrogenation, cross-coupling etc.) and as anodes and/or cathodes in fuel cells, electrolyzers, and in batteries and supercapacitors.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2021},
month = {5}
}
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