Lithium metal—seawater battery cells having protected lithium electrodes
Abstract
Active metal and active metal intercalation electrode structures and battery cells having ionically conductive protective architecture including an active metal (e.g., lithium) conductive impervious layer separated from the electrode (anode) by a porous separator impregnated with a non-aqueous electrolyte (anolyte). This protective architecture prevents the active metal from deleterious reaction with the environment on the other (cathode) side of the impervious layer, which may include aqueous or non-aqueous liquid electrolytes (catholytes) and/or a variety electrochemically active materials, including liquid, solid and gaseous oxidizers. Safety additives and designs that facilitate manufacture are also provided.
- Inventors:
- Issue Date:
- Research Org.:
- PolyPlus Battery Co., Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1805500
- Patent Number(s):
- 10916753
- Application Number:
- 16/695,054
- Assignee:
- PolyPlus Battery Company (Berkeley, CA)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01G - CAPACITORS
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- DOE Contract Number:
- AR0000349
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 11/25/2019
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Visco, Steven J., Katz, Bruce D., Nimon, Yevgeniy S., and DeJonghe, Lutgard C. Lithium metal—seawater battery cells having protected lithium electrodes. United States: N. p., 2021.
Web.
Visco, Steven J., Katz, Bruce D., Nimon, Yevgeniy S., & DeJonghe, Lutgard C. Lithium metal—seawater battery cells having protected lithium electrodes. United States.
Visco, Steven J., Katz, Bruce D., Nimon, Yevgeniy S., and DeJonghe, Lutgard C. Tue .
"Lithium metal—seawater battery cells having protected lithium electrodes". United States. https://www.osti.gov/servlets/purl/1805500.
@article{osti_1805500,
title = {Lithium metal—seawater battery cells having protected lithium electrodes},
author = {Visco, Steven J. and Katz, Bruce D. and Nimon, Yevgeniy S. and DeJonghe, Lutgard C.},
abstractNote = {Active metal and active metal intercalation electrode structures and battery cells having ionically conductive protective architecture including an active metal (e.g., lithium) conductive impervious layer separated from the electrode (anode) by a porous separator impregnated with a non-aqueous electrolyte (anolyte). This protective architecture prevents the active metal from deleterious reaction with the environment on the other (cathode) side of the impervious layer, which may include aqueous or non-aqueous liquid electrolytes (catholytes) and/or a variety electrochemically active materials, including liquid, solid and gaseous oxidizers. Safety additives and designs that facilitate manufacture are also provided.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2021},
month = {2}
}
Works referenced in this record:
Methods and reagents for enhancing the cycling efficiency of lithium polymer batteries
patent, January 2000
- Nimon, Yevgeniy S.; Chu, May-Ying; Visco, Steven J.
- US Patent Document 6,017,651
Electrochemical timer
patent, March 2001
- De Jonghe, Lutgard C.; Chu, May-Ying
- US Patent Document 6,198,701
Lithium secondary battery
patent, December 2002
- Ichihashi, Akira; Ohshita, Ryuji; Fujitani, Shin
- US Patent Document 6,489,055
Means for improving contact between Li and the anode current collector
patent, July 1979
- Dey, Arabinda N.
- US Patent Document 4,162,202
Protected Active Metal Electrodes
patent-application, July 2017
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Application 15/423458; 20170214055
Electrochemical cell having an electrode with a phosphonate additive in the electrode active mixture
patent, March 2003
- Gan, Hong; Takeuchi, Esther S.
- US Patent Document 6,537,698
Reinforced Microporous FIlm
patent, July 1972
- Zimmerman, Daniel; Wolfowitz, Stanley
- US Patent Document 3,679,540
Phosphate additives for nonaqueous electrolyte rechargeable electrochemical cells
patent, March 2001
- Gan, Hong; Takeuchi, Esther S.
- US Patent Document 6,203,942
Ionically conductive composites for protection of active metal anodes
patent, October 2007
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,282,296
In situ formed ionically conductive membranes for protection of active metal anodes and battery cells
patent, February 2012
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 8,114,171
Plating metal negative electrodes under protective coatings
patent-application, November 2001
- Chu, May-Ying; Visco, Steven J.; De Jonghe, Lutgard C.
- US Patent Application 09/901970; 20010041294
Ionically conductive membranes for protection of active metal anodes and battery cells
patent-application, March 2008
- Visco, Steven; Nimon, Yevgeniy; Katz, Bruce
- US Patent Application 11/824574; 20080057386
HIGH IONIC CONDUCTIVITY ELECTROLYTES FROM BLOCK COPOLYMERS OF GRAFTED POLY(SILOXANES-CO-ETHYLENE OXIDE)
patent-application, December 2011
- Eitouni, Hany Basam; Hsieh, Bing R.
- US Patent Application 13/255090; 20110318648
Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
patent, October 2007
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 7,282,295
Method for making an electrochemical cell
patent, October 1996
- Bates, John B.; Dudney, Nancy J.
- US Patent Document 5,567,210
Active Metal Fuel Cells
patent-application, November 2011
- Visco, Steven; Nimon, Yevgeniy; Katz, Bruce
- US Patent Application 13/182322; 20110269031
Electrolyte for an electrochemical cell
patent, January 1997
- Bates, John B.; Dudney, Nancy J.
- US Patent Document 5,597,660
Long cycle-life alkali metal battery
patent, March 2001
- Peled, Emanuel; Golodnitsky, Diana; Strauss, Ela
- US Patent Document 6,203,947
Alkali ion conductive glass-ceramics and electric cells and gas sensors using the same
patent, May 2007
- Fu, Jie
- US Patent Document 7,211,532
Solid polymer electrolyte-based oxygen batteries
patent, April 1996
- Abraham, Kuzhikalail M.; Jiang, Zhiping
- US Patent Document 5,510,209
Active metal/aqueous electrochemical cells and systems
patent-application, October 2004
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Application 10/772157; 20040197641
Integrated battery
patent-application, September 2004
- Iwamoto, Kazuya
- US Patent Application 10/802911; 20040185334
Phosphonate additives for nonaqueous electrolyte in rechargeable electrochemical cells
patent, December 2002
- Gan, Hong; Takeuchi, Esther S.
- US Patent Document 6,495,285
CATHODES AND RESERVOIRS FOR AQUEOUS LITHIUM/AIR BATTERY CELLS
patent-application, December 2009
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Application 12/484079; 20090311605
Active metal / aqueous electrochemical cells and systems
patent, November 2011
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 8,048,571
Sulfur/aluminum electrochemical batteries
patent, November 1996
- Licht, Stuart
- US Patent Document 5,571,600
Electrolytes with strong oxidizing additives for lithium/sulfur batteries
patent-application, April 2004
- Nimon, Yevgeniy; Chu, May-Ying; Visco, Steven
- US Patent Application 10/645193; 20040081894
Ionically conductive composites for protection of active metal anodes
patent-application, March 2008
- Visco, Steven; Nimon, Yevgeniy; Katz, Bruce
- US Patent Application 11/824579; 20080057387
Rechargeable lithium battery for use in applications requiring a low to high power output
patent, October 1996
- Bates, John B.
- US Patent Document 5,569,520
Protective composite battery separator and electrochemical device component with red phosphorus
patent, November 2010
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,838,144
Batteries
patent-application, June 2007
- Anglin, David L.; Yoppolo, Robert
- US Patent Application 11/317432; 20070148533
Protective coating for separators for electrochemical cells
patent, February 2001
- Ying, Qicong; Carlson, Steven A.; Skotheim, Terje A.
- US Patent Document 6,183,901
Lakyer for stabilization of lithium anode
patent, August 1994
- Koksbang, Rene
- US Patent Document 5,342,710
Lithium anodes for electrochemical cells
patent, September 2004
- Skotheim, Terje A.; Sheehan, Christopher J.; Mikhaylik, Yuriy V.
- US Patent Document 6,797,428
Sealed lithium electrochemical cell with sodium beta-alumina electrolyte
patent, May 1978
- Farrington, Gregory C.; Roth, Walter L.
- US Patent Document 4,091,182
Active metal electrolyzer
patent, October 2009
- De Jonghe, Lutgard C.; Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 7,608,178
Separator material for electrochemical cells
patent, March 1991
- Cieslak, Wendy R.; Storz, Leonard J.
- US Patent Document 5,002,843
Metal-air battery with ion-conducting inorganic glass electrolyte
patent-application, March 2006
- Jang, Bor Z.
- US Patent Application 10/944667; 20060063051
Renewable, energetic, nanodimensional dispersion
patent-application, October 2003
- Rendina, David
- US Patent Application 10/409911; 20030190501
Aluminum and sulfur electrochemical batteries and cells
patent, May 1995
- Licht, Stuart; Peramunage, Dharmasena
- US Patent Document 5,413,881
Fluid conduction utilizing a reversible unsaturated siphon with tubarc porosity action
patent, July 2004
- da Silva, Elson Dias
- US Patent Document 6,766,817
Active metal fuel cells
patent, August 2011
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,998,626
Composite coating for electrochemical electrode and method
patent, January 1991
- de Neufville, John P.; Rajoria, Dalbir; Ovshinsky, Stanford R.
- US Patent Document 4,981,672
Safety enhanced li-ion and lithium metal battery cells having protected lithium electrodes with enhanced separator safety against dendrite shorting
patent, January 2020
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 10,529,971
COMPOSITE SOLID ELECTROLYTE FOR PROTECTION OF ACTIVE METAL ANODES
patent-application, July 2007
- Visco, Steven J.; DeJonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Application 11/612741; 20070172739
In Situ Formed Ionically Conductive Membranes For Protection Of Active Metal Anodes And Battery Cells
patent-application, February 2011
- Visco, Steven; Nimon, Yevgeniy; Katz, Bruce
- US Patent Application 12/907819; 20110039144
Overcharge protection systems for rechargeable batteries
patent, March 1999
- Visco, Steven J.; Chu, May-Ying; De Jonghe, Lutgard C.
- US Patent Document 5,882,812
Ionically Conductive Membranes For Protection Of Active Metal Anodes And Battery Cells
patent-application, December 2009
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Application 12/475403; 20090297935
Anodization of magnesium and magnesium based alloys
patent, August 2001
- Barton, Thomas F.; Macculloch, John Arnold; Ross, Philip
- US Patent Document 6,280,598
Method for electrochemically producing an alkali metal from an aqueous solution
patent, August 2004
- Putter, Hermann; Huber, GĂĽnther; Schierle-Arndt, Kerstin
- US Patent Document 6,770,187
Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
patent, November 2010
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 7,829,212
Process for producing porous products
patent, April 1976
- Gore, Robert W.
- US Patent Document 3,953,566
Compositions and methods for protection of active metal anodes and polymer electrolytes
patent, October 2008
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,432,017
Metal-air semi-fuel cell with an aqueous acid based cathode
patent-application, November 2007
- Chua, David; Salomon, Mark; Kowalczyk, Ian
- US Patent Application 11/418629; 20070259234
Solid gel membrane separator in electrochemical cells
patent-application, August 2002
- Chen, Muguo; Li, Lin-Feng; Tsai, Tsepin
- US Patent Application 10/013016; 20020102465
Membrane-electrode structure for electrochemical cells
patent, August 1994
- Tsou, Yu-Min; McMichael, James W.; Beaver, Richard N.
- US Patent Document 5,336,384
Electrochemical device separator structures with barrier layer on non-swelling membrane
patent, July 2006
- Visco, Steven J.; Katz, Bruce D.
- US Patent Document 7,070,632
Protected lithium electrodes having a polymer electrolyte interlayer and battery cells thereof
patent, August 2013
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 8,501,339
Catholytes for aqueous lithium/air battery cells
patent, February 2014
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,658,304
Method of making an electrolyte for an electrochemical cell
patent, April 1996
- Bates, John B.; Dudney, Nancy J.
- US Patent Document 5,512,147
Mixed ionic electronic conductor coatings for redox electrodes
patent, April 2001
- Visco, Steven J.; Chu, May-Ying
- US Patent Document 6,210,832
Chemical protection of a lithium surface
patent-application, August 2005
- De Jonghe, Lutgard; Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Application 11/092781; 20050186469
Substantially impervious lithium super ion conducting membranes
patent, February 2014
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,652,686
Plating metal negative electrodes under protective coatings
patent, April 2004
- Chu, May-Ying; Visco, Steven J.; De Jonghe, Lutgard C.
- US Patent Document 6,723,140
Non-aqueous electrolyte and electrochemical device comprising the same
patent-application, March 2002
- Sonoda, Kumiko; Ueda, Atsushi; Iwamoto, Kazuya
- US Patent Application 09/901945; 20020028389
Cell for making secondary batteries
patent, November 1992
- Visco, Steven J.; Liu, Meilin; DeJonghe, Lutgard C.
- US Patent Document 5,162,175
Active metal fuel cells
patent-application, May 2005
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Application 10/825587; 20050100792
Composite Sheet and Production Method Thereof
patent-application, July 2012
- Hisano, Hirokazu; Manabe, Hiroshi; Zenitani, Norimasa
- US Patent Application 13/141783; 20120169016
Microporous materials incorporating a nucleating agent and methods for making same
patent, February 1988
- Mrozinski, James S.
- US Patent Document 4,726,989
Electrochemical cell and negative electrode therefor
patent-application, June 2002
- Wyler, Mark D.; Hoesman, Thomas R.; Golovin, M. Neal
- US Patent Application 09/730300; 20020068220
Metal-sulfur type cell having improved positive electrode
patent, May 1989
- DeJonghe, Lutgard C.; Visco, Steven J.; Mailhe, Catherine C.
- US Patent Document 4,833,048
Solid composite electrolyte membrane and method of making
patent-application, May 2007
- Kumar, Binod; Thokchom, Joykumar Singh
- US Patent Application 11/601965; 20070117026
Primary Sodium-Water Battery
patent, November 1972
- Mitoff, Stephan P.; Will, Fritz G.
- US Patent Document 3,703,415
Method and electrode for electrochemical recovery of lithium value from aqueous solution
patent, March 1993
- Kanoh, Hirofumi; Ooi, Kenta; Miyai, Yoshitaka
- US Patent Document 5,198,081
Lithium anodes for electrochemical cells
patent-application, January 2002
- Skotheim, Terje A.; Sheehan, Christopher J.; Mikhaylik, Yuriy V.
- US Patent Application 09/864890; 20020012846
Lithium battery having a protected lithium electrode and an ionic liquid catholyte
patent, September 2014
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 8,828,580
Lithium anodes for electrochemical cells
patent, July 2007
- Skotheim, Terje A.; Sheehan, Christopher J.; Mikhaylik, Yuriy V.
- US Patent Document 7,247,408
Sealed lithium-type electrochemical cell
patent, July 1980
- Farrington, Gregory C.
- US Patent Document 4,210,707
Protected Active Metal Electrode And Battery Cell Structures With Non-Aqueous Interlayer Architecture
patent-application, January 2015
- Visco, Steven; Katz, Bruce; Nimon, Yevgeniy
- US Patent Application 14/449040; 20150024251
Polymer adhesive seals for protected anode architectures
patent-application, March 2007
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 11/514678; 20070051620
Protected Lithium Electrodes Having a Porous Electrolyte Interlayer and Associated Battery Cells
patent-application, December 2016
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Application 15/150231; 20160351879
Electrochemical cell having an electrode with a phosphate additive in the electrode active mixture
patent, January 2003
- Gan, Hong; Takeuchi, Esther S.
- US Patent Document 6,511,772
Advanced Lithium Ion Batteries Based on Solid State Protected Lithium Electrodes
patent-application, December 2016
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Application 15/149012; 20160351878
High Energy Density Vanadium Electrolyte Solutions, Methods of Preparation Thereof and All-Vanadium Redox Cells and Batteries Containing High Energy Vanadium Electrolyte Solutions
patent-application, October 2001
- Kazacos, Michael; Kazacos, Maria Skyllas
- US Patent Application 08/945869; 20010028977
Manufacturing method for electrode
patent, March 1994
- Izuchi, Syuichi; Noda, Toshiharu; Yoshihisa, Youetsu
- US Patent Document 5,290,592
Parasitic corrosion resistant anode for use in metal/air or metal/O.sub.2 cells
patent, November 1983
- Joy, Richard W.; Smith, David F.
- US Patent Document 4,414,293
Lithium ion-conductive solid electrolyte containing lithium titanium phosphate
patent, January 1991
- Adachi, Ginya; Imanaka, Nobuhito; Aono, Hiromichi
- US Patent Document 4,985,317
Lithium/air batteries with LiPON as separator and protective barrier and method
patent, May 2007
- Klaassen, Jody J.
- US Patent Document 7,211,351
Ionically conductive composites for protection of active metal anodes
patent-application, March 2008
- Visco, Steven; Nimon, Yevgeniy; Katz, Bruce
- US Patent Application 11/823847; 20080057399
Methods and reagents for enhancing the cycling efficiency of lithium polymer batteries
patent, December 2000
- Nimon, Yevgeniy S.; Chu, May-Ying; Visco, Steven J.
- US Patent Document 6,165,644
CERAMIC MATERIAL AND PREPARATION METHOD THEREFOR
patent-application, March 2011
- Yamamura, Yoshihiko; Hattori, Tatsuya; Yoshida, Toshihiro
- US Patent Application 12/873393; 20110053002
Encapsulated alloy electrodes
patent, January 2006
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 6,991,662
Solid multi-component membranes, electrochemical reactor components, electrochemical reactors and use of membranes, reactor components, and reactor for oxidation reactions
patent, December 1997
- Mazanec, Terry; Cable, Thomas L.; Frye, Jr., John G.
- US Patent Document 5,693,212
Li/Air non-aqueous batteries
patent, February 2014
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 8,652,692
Liquid fuel cell
patent-application, February 2002
- Suda, Seijirau
- US Patent Application 09/917630; 20020015869
Electrolyte compositions
patent, August 1976
- Tsai, Keh-Chi; Littauer, Ernest L.
- US Patent Document 3,976,509
Organic electrolytic solution and lithium secondary battery employing the same
patent-application, July 2003
- Kim, Ju-yup; Seung, Do-young; Ryu, Young-gyoon
- US Patent Application 10/283334; 20030124433
Forming an impermeable sintered ceramic electrolyte layer on a metallic foil substrate for solid oxide fuel cell
patent-application, December 2003
- Steele, Brian; Atkinson, Alan; Kilner, John
- US Patent Application 10/382471; 20030224234
Method for forming encapsulated lithium electrodes having glass protective layers
patent, April 2001
- Visco, Steven J.; Tsang, Floris Y.
- US Patent Document 6,214,061
Lithium ion conductive glass-ceramics and electric cells and gas sensors using the same
patent, November 2002
- Fu, Jie
- US Patent Document 6,485,622
POLYMER COMPOSITIONS BASED ON PXE
patent-application, March 2013
- Yang, Jin; Eitouni, Hany Basam; Singh, Mohit
- US Patent Application 13/698664; 20130066025
Method for forming encapsulated lithium electrodes having glass protective layers
patent, August 2002
- Visco, Steven J.; Tsang, Floris Y.
- US Patent Document 6,432,584
CATHOLYTES FOR AQUEOUS LITHIUM/AIR BATTERY CELLS
patent-application, December 2009
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Application 12/484063; 20090311596
Encapsulated lithium alloy electrodes having barrier layers
patent, July 2002
- Chu, May-Ying; Visco, Steven J.; DeJonghe, Lutgard C.
- US Patent Document 6,413,284
Layered arrangements of lithium electrodes
patent, July 2002
- Chu, May-Ying; Visco, Steven J.; DeJonghe, Lutgard C.
- US Patent Document 6,413,285
Encapsulated lithium alloy electrodes having barrier layers
patent, May 2004
- Chu, May-Ying; Visco, Steven J.; DeJonghe, Lutgard C.
- US Patent Document 6,737,197
Solid State Battery
patent-application, April 2012
- Visco, Steven; Nimon, Yevgeniy; Katz, Bruce
- US Patent Application 13/336459; 20120094188
Non-aqueous safe secondary cell
patent, April 1996
- Dan, Pnina; Geronov, Jordan; Luski, Shalom
- US Patent Document 5,506,068
Rechargeable lithium battery for use in applications requiring a low to high power output
patent, March 1997
- Bates, John B.
- US Patent Document 5,612,152
Battery Cell
patent, September 1971
- McRae, Wayne A.; Bockris, John O'M.
- US Patent Document 3,607,417
Active Metal Fuel Cells
patent-application, November 2009
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Application 12/334116; 20090286114
Lithium ion conductive glass-ceramics and electric cells and gas sensors using the same
patent, February 2000
- Fu, Jie
- US Patent Document 6,030,909
Ion Conductor Having a Garnet Structure
patent-application, August 2010
- Weppner, Werner
- US Patent Application 12/667400; 20100203383
Solid polymer battery electrolyte and reactive metal-water battery
patent, November 2000
- Harrup, Mason K.; Peterson, Eric S.; Stewart, Frederick F.
- US Patent Document 6,146,787
Electrolyte compositions and methods
patent, April 1992
- Shuster, Nicholas
- US Patent Document 5,108,856
Battery
patent-application, September 2009
- Katoh, Takashi
- US Patent Application 12/383048; 20090239152
Lithium ion conductive solid electrolyte and method for manufacturing the same
patent-application, April 2007
- Inda, Yasushi
- US Patent Application 11/453919; 20070087269
Electrolytes with strong oxidizing additives for lithium/sulfur batteries
patent, October 2003
- Nimon, Yevgeniy S.; Chu, May-Ying; Visco, Steven J.
- US Patent Document 6,632,573
Negative active material for rechargeable lithium battery and method of preparing the same
patent-application, January 2002
- Choi, Wan-Uk; Sheem, Kyou-Yoon; Kim, Sang-Jin
- US Patent Application 09/880634; 20020012845
Coated lithium electrodes
patent, October 2005
- Nimon, Yevgeniy S.; Chu, May-Ying; Visco, Steven J.
- US Patent Document 6,955,866
Composite solid electrolyte for protection of active metal anodes
patent, May 2012
- Visco, Steven J.; DeJonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,182,943
Battery cells with lithium ion conducting tape-cast ceramic, glass and glass-ceramic membranes
patent, August 2016
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 9,419,299
Electrode protection in both aqueous and non-aqueous electrochemical cells, including rechargeable lithium batteries
patent, August 2010
- Affinito, John D.; Mikhaylik, Yuriy V.; Geronov, Yordan M.
- US Patent Document 7,771,870
Substantially impervious lithium super ion conducting membranes
patent, December 2012
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,334,075
Active metal/aqueous electrochemical cells and systems
patent-application, March 2008
- Visco, Steven; Nimon, Yevgeniy
- US Patent Application 11/824548; 20080052898
Protected Lithium Electrodes Based on Ceramic Membranes
patent-application, September 2014
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Application 14/292699; 20140272524
Air-Depolarized Cells Utilizing a Cyanate or Thiocyanate-Containing Electrolyte
patent, January 1974
- Kordesch, Karl V.
- US Patent Document 3,783,016
CATHOLYTES FOR AQUEOUS LITHIUM/AIR BATTERY CELLS
patent-application, May 2013
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Application 13/663224; 20130122380
GARNET-TYPE LITHIUM ION-CONDUCTING OXIDE AND ALL-SOLID-STATE LITHIUM ION SECONDARY BATTERY CONTAINING THE SAME
patent-application, October 2011
- Ohta, Shingo; Kobayashi, Tetsuro; Asaoka, Takahiko
- US Patent Application 13/132795; 20110244337
Active metal/aqueous electrochemical cells and systems
patent, June 2012
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 8,202,649
Solid electrolytes based on lithium hafnium phosphate for active metal anode protection
patent-application, April 2006
- Nimon, Yevgeniy S.; De Jonghe, Lutgard C.; Visco, Steven J.
- US Patent Application 11/245472; 20060078790
Glass-polymer composite electrolyte and a method of preparing the same
patent, May 2000
- Cho, Jae-Phil; Kim, Geun-Bae
- US Patent Document 6,066,417
Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
patent, September 2015
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 9,123,941
Solid polymer electrolyte composite membrane comprising porous ceramic support
patent-application, August 2006
- Mittelsteadt, Cortney K.; LaConti, Anthony B.
- US Patent Application 11/239647; 20060183011
Method of preparing electrodes having evenly distributed component mixtures
patent, August 2000
- Tsang, Floris Y.; Visco, Steven J.; Chu, May-Ying
- US Patent Document 6,110,236
Safety enhanced Li-ion and lithium metal battery cells having protected lithium electrodes with enhanced separator safety against dendrite shorting
patent, May 2017
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 9,666,850
Ionically conductive membranes for protection of active metal anodes and battery cells
patent-application, September 2004
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Application 10/772228; 20040191617
Organic phosphate additives for nonaqueous electrolyte in alkali metal electrochemical cells
patent, May 2000
- Gan, Hong; Takuchi, Esther S.
- US Patent Document 6,068,950
Lithium oxygen batteries and method of producing same
patent-application, September 2005
- Johnson, Lonnie G.
- US Patent Application 11/059942; 20050208353
Electra-optical device including a nitrogen containing electrolyte
patent, October 1995
- Bates, John B.; Dudney, Nancy J.; Gruzalski, Greg R.
- US Patent Document 5,455,126
Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
patent-application, August 2005
- Visco, Steven J.; , Bruce D
- US Patent Application 10/824944; 20050175894
Lithium anodes for electrochemical cells
patent, May 2004
- Skotheim, Terje A.; Sheehan, Christopher J.; Mikhaylik, Yuriy V.
- US Patent Document 6,733,924
Inactive electrochemical cell having an ionically nonconductive polymeric composition activated by electrolyte salt solution
patent, April 1995
- Bailey, John C.
- US Patent Document 5,409,786
Molten salt lithium cells
patent, September 1983
- Raistrick, Ian D.; Poris, Jaime; Huggins, Robert A.
- US Patent Document 4,405,416
Electrodes for rechargeable lithium batteries
patent, February 1995
- Koksbang, Rene
- US Patent Document 5,387,479
Liquid electrolyte lithium-sulfur batteries
patent, March 2002
- Katz, Bruce D.; Chu, May-Ying; DeJonghe, Lutgard C.
- US Patent Document 6,358,643
Active Metal Fuel Cells
patent-application, January 2014
- Visco, Steven; Nimon, Yevgeniy; Katz, Bruce
- US Patent Application 13/717255; 20140004447
Lithium/air batteries with LiPON as separator and protective barrier and method
patent, March 2008
- Klaassen, Jody J.
- US Patent Document 7,344,804
Lithium/air batteries with LiPON as separator and protective barrier and method
patent-application, May 2005
- Klaassen, Jody
- US Patent Application 10/895445; 20050095506
Bi-Polar Protected Electrodes and Multi-Cell Stacks
patent-application, November 2014
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 14/289502; 20140335392
Safety Enhanced Li-ion and Lithium Metal Battery Cells Having Protected Lithium Electrodes with Enhanced Separator Safety Against Dendrite Shorting
patent-application, November 2017
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Application 15/487364; 20170346060
Metal-air battery with improved air supply
patent, July 1997
- Shuster, Nicholas; Harney, David E.
- US Patent Document 5,652,068
Active metal fuel cells
patent, August 2010
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,781,108
Protective coatings for negative electrodes
patent, February 2000
- Visco, Steven J.; Chu, May-Ying
- US Patent Document 6,025,094
Battery electrode and manufacturing method thereof
patent, February 2000
- Kawamura, Hiroshi
- US Patent Document 6,025,095
Battery Cells with Lithium Ion Conducting Tape-cast Ceramic, Glass and Glass-ceramic Membranes
patent-application, November 2015
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Application 14/815672; 20150340720
HIGH RATE SEAWATER ACTIVATED LITHIUM BATTERY CELLS BI-POLAR PROTECTED ELECTRODES AND MULTI-CELL STACKS
patent-application, November 2011
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 12/973779; 20110269007
ACTIVE METAL / AQUEOUS ELECTROCHEMICAL CELLS AND SYSTEMS
patent-application, March 2012
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Application 13/236428; 20120009469
Thermoelectric Device and Method of Manufacture
patent, September 1970
- Ovshinsky, Stanford R.
- US Patent Document 3,528,856
Protective lithium ion conducting ceramic coating for lithium metal anodes and associate method
patent, May 1994
- Bates, John B.
- US Patent Document 5,314,765
Solid gel membrane separator in rechargeable electrochemical cells
patent, March 2002
- Chen, Muguo; Li, Lin-Feng; Tsai, Tsepin
- US Patent Document 6,358,651
Stabilized anode for lithium-polymer batteries
patent, October 1999
- Skotheim, Terje A.; Soloveichik, Grigorii Lev; Gavrilov, Alexei B.
- US Patent Document 5,961,672
Ionically conductive membranes for protection of active metal anodes and battery cells
patent, June 2008
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,390,591
Compliant seal structures for protected active metal anodes
patent-application, February 2007
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 11/501676; 20070037058
High temperature rechargeable molten salt battery
patent, July 1991
- Plichta, Edward J.; Behl, Wishvander
- US Patent Document 5,035,963
Phosphonate additives for nonaqueous electrolyte in rechargeable cells
patent, March 2001
- Gan, Hong; Takeuchi, Esther S.
- US Patent Document 6,200,701
ION CONDUCTIVE LAMINATE AND PRODUCTION METHOD AND USE THEREOF
patent-application, August 2001
- TAKEUCHI, MASATAKA; NAIJO, SHUICHI; OHKUBO, TAKASHI
- US Patent Application 08/946850; 20010014420
Process for producing permeable membranes
patent, July 1978
- Shinomura, Toshihiko
- US Patent Document 4,100,238
Alkali metal carbon dioxide electrochemical system for energy storage and/or conversion of carbon dioxide to oxygen
patent, May 1993
- Hagedorn, Norman H.
- US Patent Document 5,213,908
Cell comprising an alkali metal and aqueous electrolyte
patent, February 1977
- Littauer, Ernest L.; Hollandsworth, Roger Paul; Tsai, Keh-Chi
- US Patent Document 4,007,057
Negative electrode for solid electrolyte cells
patent, October 1975
- Galli, Riccardo; Olivani, Franco
- US Patent Document 3,912,536
High capacity/high discharge rate rechargeable positive electrode
patent, March 2001
- Katz, Bruce D.; De Jonghe, Lutgard C.; Chu, May-Ying
- US Patent Document 6,200,704
Battery cells with lithium ion conducting tape-cast ceramic, glass and glass-ceramic membranes
patent, March 2017
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 9,601,779
Lithium ion conductive solid electrolyte and production process thereof
patent-application, October 2007
- Inda, Yasushi
- US Patent Application 11/727489; 20070231704
Metal-air battery
patent, September 1997
- Shuster, Nicholas; Seiger, Harvey N.; Spak, Daniel J.
- US Patent Document 5,665,481
ELECTROCHEMICAL DEVICE WITH PROTECTIVE MEMBRANE ARCHITECTURE
patent-application, February 2014
- Visco, Steven J.; Nimon, Yevgeniy S; Katz, Bruce D.
- US Patent Application 13/938029; 20140050994
Semiconductor memory drive
patent, September 1983
- Shirai, Kazunari; Tanaka, Izumi
- US Patent Document 4,405,995
Ionically conductive composites for protection of active metal anodes
patent-application, July 2004
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Application 10/686189; 20040126653
Microporous sheet material, method of making and articles made therewith
patent, September 1985
- Shipman, Gene H.
- US Patent Document 4,539,256
Stabilized anode for lithium-polymer batteries
patent, July 1997
- Skotheim, Terje A.
- US Patent Document 5,648,187
Magnesium solution phase catholyte seawater electrochemical system
patent, May 2001
- Medeiros, Maria G.; Tucker, Steven P.; Cichon, James M.
- US Patent Document 6,228,527
LI/AIR NON-AQUEOUS BATTERIES
patent-application, May 2007
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Application 11/562883; 20070117007
Catholytes for aqueous lithium/air battery cells
patent, December 2012
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,323,820
Electrochemical device component with protected alkali metal electrode
patent, December 2010
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,858,223
Process for forming an argentic oxide containing bipolar electrode and product produced thereby and deferred actuated battery assembly employing same
patent, November 1992
- Rao, Bhaskara M. L.; Kobasz, William
- US Patent Document 5,166,011
Hydrogels for aqueous lithium/air battery cells
patent, March 2013
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,389,147
Method for reducing voltage delay in alkali metal electrochemical cells activated with a nonaqueous electrolyte having a phosphate additive
patent, August 2001
- Gan, Hong; Takeuchi, Esther S.
- US Patent Document 6,274,269
Overcharge protection systems for rechargeable batteries
patent, June 2001
- Visco, Steven J.; Chu, May-Ying; De Jonghe, Lutgard C.
- US Patent Document 6,248,481
Active metal/aqueous electrochemical cells and systems
patent, February 2010
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 7,666,233
Protected active metal electrode and battery cell structures with non-aqueous interplayer architecture
patent-application, February 2008
- Visco, Steven; Katz, Bruce; Nimon, Yevgeniy
- US Patent Application 11/824597; 20080038641
Coated lithium electrodes
patent, March 2003
- Nimon, Yevgeniy S.; Chu, May-Ying; Visco, Steven J.
- US Patent Document 6,537,701
Ionically conductive composites for protection of active metal anodes
patent-application, July 2004
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Application 10/731771; 20040142244
Secondary cell using organosulfur/metal charge transfer materials as positive electrode
patent, May 1996
- Visco, Steven J.; Takemoto, Jiro; Chu, May-Ying
- US Patent Document 5,516,598
Lithium battery having a protected lithium electrode and an ionic liquid catholyte
patent-application, February 2014
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Application 13/929653; 20140057153
Dioxolane as a proctector for lithium electrodes
patent, May 2001
- Nimon, Yevgeniy S.; Visco, Steven J.; Chu, May-Ying
- US Patent Document 6,225,002
HIGH ENERGY DENSITY AQUEOUS LITHIUM/AIR BATTERY CELLS
patent-application, December 2009
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Application 12/484065; 20090311603
Phosphonate additives for nonaqueous electrolyte in alkali metal electrochemical cells
patent, August 2000
- Gan, Hong; Takuchi, Esther S.
- US Patent Document 6,096,447
Ionically conductive composites for protection of active metal anodes
patent, October 2007
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,282,302
Active Metal / Aqueous Electrochemical Cells and Systems
patent-application, April 2010
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Application 12/649245; 20100104934
Liquid electrolyte lithium-sulfur batteries
patent, February 2000
- Chu, May-Ying; De Jonghe, Lutgard C.; Visco, Steven J.
- US Patent Document 6,030,720
Aluminum and sulfur electrochemical batteries and cells
patent, July 1997
- Licht, Stuart; Peramunage, Dharmasena
- US Patent Document 5,648,183
Encapsulated lithium alloy electrodes having barrier layers
patent-application, March 2002
- Chu, May-Ying; Visco, Steven J.; DeJonghe, Lutgard C.
- US Patent Application 09/999673; 20020034688
Method for forming lithium metal anode protective layer for lithium battery and lithium battery having such protective layer
patent, December 2004
- Cho, Chung Kun; Seung, Do-young
- US Patent Document 6,835,492
Solid electrolyte composite for electrochemical reaction apparatus
patent, June 2001
- Mushiake, Naofumi
- US Patent Document 6,242,135
Use of amorphous carbon to promote adhesion between electroactive polymer films and conductive substrates
patent, March 1992
- Helms, Jeffrey H.; Plummer, Jr., H. Kiel; Tamor, Michael Alan
- US Patent Document 5,100,523
Protected Active Metal Electrode and Battery Cell Structures with Non-Aqueous Interlayer Architecture
patent-application, January 2016
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Application 14/809083; 20160028063
Non-aqueous electrolyte secondary cell
patent-application, August 2002
- Okawa, Tsuyoshi; Hosoya, Mamoru; Kuyama, Junji
- US Patent Application 09/972375; 20020106563
Composition useful in electrolytes of secondary battery cells
patent, October 1999
- Boguslavsky, Leonid I.; Mikhaylik, Yuriy V.; Gavrilov, Alexei B.
- US Patent Document 5,962,171
Thin film battery and method for making same
patent, August 1994
- Bates, John B.; Dudney, Nancy J.; Gruzalski, Greg R.
- US Patent Document 5,338,625
Sound and heat insulation having little odor
patent, December 1997
- Cavalloni, Carlo; La Grotteria, Antonio; Freyer, Harald
- US Patent Document 5,696,201
Chemical protection of a lithium surface
patent, June 2005
- De Jonghe, Lutgard C.; Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 6,911,280
Active metal fuel cells
patent, April 2014
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 8,709,679
Refuelable electrochemical power source capable of being maintained in a substantially constant full condition and method of using the same
patent, October 2001
- Pinto, Martin; Smedley, Stuart; Colborn, Jeffrey A.
- US Patent Document 6,296,958
Active metal electrolyzer
patent-application, May 2005
- Jonghe, Lutgard De; Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Application 10/986441; 20050100793
Solid electrolyte and battery employing the same
patent-application, May 2004
- Park, Young-Sin; Lee, Seok-Soo; Jin, Young-Gu
- US Patent Application 10/656180; 20040101761
Glass-ceramic composite electrolyte and lithium secondary cell
patent, November 2002
- Inda, Yasushi; Ohara, Kazuo
- US Patent Document 6,475,677
PROTECTED ACTIVE METAL ELECTRODE AND BATTERY CELL WITH IONICALLY CONDUCTIVE PREOTECTIVE ARCHITECTURE
patent-application, January 2011
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Application 12/888154; 20110014522
Plating metal negative electrodes under protective coatings
patent, June 2002
- Chu, May-Ying; Visco, Steven J.; De Jonghe, Lutgard C.
- US Patent Document 6,402,795
SMALL DOMAIN-SIZE MULTIBLOCK COPOLYMER ELECTROLYTES
patent-application, October 2013
- Pistorino, Jonathan; Eitouni, Hany Basam
- US Patent Application 13/862442; 20130273419
Active metal fuel cells
patent, February 2009
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,491,458
Cathodes and reservoirs for aqueous lithium/air battery cells
patent, June 2013
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,455,131
Electric cells and gas sensors using alkali ion conductive glass ceramic
patent, November 2001
- Fu, Jie
- US Patent Document 6,315,881
Electrochemically stable cathode
patent, July 1979
- Tsai, Keh-Chi; Littauer, Ernest L.
- US Patent Document 4,163,084
Porous products and process therefor
patent, February 1980
- Gore, Robert W.
- US Patent Document 4,187,390
HYDROGELS FOR AQUEOUS LITHIUM/AIR BATTERY CELLS
patent-application, December 2009
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Application 12/484081; 20090311567
Secondary battery
patent, May 2002
- Kawakami, Soichiro; Mishina, Shinya; Kobayashi, Naoya
- US Patent Document 6,391,492
Lithium/organosulfur redox cell having protective solid electrolyte barrier formed on anode and method of making same
patent, April 1990
- De Jonghe, Lutgard C.; Visco, Steven J.; Liu, Meilin
- US Patent Document 4,917,974
Active metal/aqueous electrochemical cells and systems
patent, January 2010
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 7,645,543
Organic/inorganic composite porous film and electrochemical device prepared thereby
patent-application, March 2006
- Yong, Hyun Hang; Lee, Sang Young; Kim, Seok Koo
- US Patent Application 11/217918; 20060046149
Moisture-permeable waterproof coated fabric and method of making the same
patent, January 1984
- Naka, Yasushi; Kawakami, Kiyoshi
- US Patent Document 4,429,000
Methods of fabricating rechargeable positive electrodes
patent, December 1996
- Chu, May-Ying
- US Patent Document 5,582,623