Solvent-free, solid phase synthesis of hybrid lead halide perovskites with superior purity
Abstract
A method of synthesizing a mixed-halide perovskite is disclosed herein. The method includes the steps of mixing a first single-halide perovskite and a second single-halide perovskite to form a solid phase mixture and heating the solid phase mixture at a temperature below a first decomposition temperature of the first single-halide perovskite and below a second decomposition temperature of the second single-halide perovskite for a time sufficient to form the mixed-halide perovskite. During the mixing, the first and second single-halide perovskite are both in the solid phase. A mixed-halide perovskite made according to the method is also disclosed herein. The mixed-halide perovskite is free of amorphous and/or semicrystalline phases. The mixed-halide perovskite can be utilized in a photovoltaic cell in a solar panel.
- Inventors:
- Issue Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1771749
- Patent Number(s):
- 10872734
- Application Number:
- 15/854,596
- Assignee:
- Iowa State University Research Foundation, Inc. (Ames, IA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01G - CAPACITORS
- DOE Contract Number:
- AC02-07CH11358
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 12/26/2017
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Vela-Becerra, Javier, and Rosales, Bryan A. Solvent-free, solid phase synthesis of hybrid lead halide perovskites with superior purity. United States: N. p., 2020.
Web.
Vela-Becerra, Javier, & Rosales, Bryan A. Solvent-free, solid phase synthesis of hybrid lead halide perovskites with superior purity. United States.
Vela-Becerra, Javier, and Rosales, Bryan A. Tue .
"Solvent-free, solid phase synthesis of hybrid lead halide perovskites with superior purity". United States. https://www.osti.gov/servlets/purl/1771749.
@article{osti_1771749,
title = {Solvent-free, solid phase synthesis of hybrid lead halide perovskites with superior purity},
author = {Vela-Becerra, Javier and Rosales, Bryan A.},
abstractNote = {A method of synthesizing a mixed-halide perovskite is disclosed herein. The method includes the steps of mixing a first single-halide perovskite and a second single-halide perovskite to form a solid phase mixture and heating the solid phase mixture at a temperature below a first decomposition temperature of the first single-halide perovskite and below a second decomposition temperature of the second single-halide perovskite for a time sufficient to form the mixed-halide perovskite. During the mixing, the first and second single-halide perovskite are both in the solid phase. A mixed-halide perovskite made according to the method is also disclosed herein. The mixed-halide perovskite is free of amorphous and/or semicrystalline phases. The mixed-halide perovskite can be utilized in a photovoltaic cell in a solar panel.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Dec 22 00:00:00 EST 2020},
month = {Tue Dec 22 00:00:00 EST 2020}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Hybrid Perovskite Resulting from the Solid-State Reaction between the Organic Cations and Perovskite Layers of α1-(Br-(CH 2 ) 2 -NH 3 ) 2 PbI 4
journal, July 2007
- Sourisseau, Sebastien; Louvain, Nicolas; Bi, Wenhua
- Inorganic Chemistry, Vol. 46, Issue 15
Mixed halide hybrid perovskites: a paradigm shift in photovoltaics
journal, January 2018
- Zarick, Holly F.; Soetan, Naiya; Erwin, William R.
- Journal of Materials Chemistry A, Vol. 6, Issue 14
Persistent Dopants and Phase Segregation in Organolead Mixed-Halide Perovskites
journal, August 2016
- Rosales, Bryan A.; Men, Long; Cady, Sarah D.
- Chemistry of Materials, Vol. 28, Issue 19
Multinuclear NMR as a tool for studying local order and dynamics in CH 3 NH 3 PbX 3 (X = Cl, Br, I) hybrid perovskites
journal, January 2016
- Roiland, Claire; Trippé-Allard, Gaelle; Jemli, Khaoula
- Physical Chemistry Chemical Physics, Vol. 18, Issue 39
Mixed-halide Cs2SnI3Br3 perovskite as low resistance hole-transporting material in dye-sensitized solar cells
journal, December 2015
- Kaltzoglou, Andreas; Antoniadou, Maria; Perganti, Dorothea
- Electrochimica Acta, Vol. 184