Catalysts and process for liquid hydrocarbon fuel production

White, Mark G.; Liu, Shetian

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A - human necessities
A01 - agriculture
A21 - baking
A22 - butchering
A23 - foods or foodstuffs
A24 - tobacco
A41 - wearing apparel
A42 - headwear
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A44 - haberdashery
A45 - hand or travelling articles
A46 - brushware
A47 - furniture
A61 - medical or veterinary science
A62 - life-saving
A63 - sports
A99 - subject matter not otherwise provided for in this section
B - performing operations
B01 - physical or chemical processes or apparatus in general
B02 - crushing, pulverising, or disintegrating
B03 - separation of solid materials using liquids or using pneumatic tables or jigs
B04 - centrifugal apparatus or machines for carrying-out physical or chemical processes
B05 - spraying or atomising in general
B06 - generating or transmitting mechanical vibrations in general
B07 - separating solids from solids
B08 - cleaning
B09 - disposal of solid waste
B21 - mechanical metal-working without essentially removing material
B22 - casting
B23 - machine tools
B24 - grinding
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B27 - working or preserving wood or similar material
B28 - working cement, clay, or stone
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B33 - additive manufacturing technology
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B43 - writing or drawing implements
B44 - decorative arts
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B61 - railways
B62 - land vehicles for travelling otherwise than on rails
B63 - ships or other waterborne vessels
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B66 - hoisting
B67 - opening, closing {or cleaning} bottles, jars or similar containers
B68 - saddlery
B81 - microstructural technology
B82 - nanotechnology
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C01 - inorganic chemistry
C02 - treatment of water, waste water, sewage, or sludge
C03 - glass
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C22 - metallurgy
C23 - coating metallic material
C25 - electrolytic or electrophoretic processes
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D01 - natural or man-made threads or fibres
D02 - yarns
D03 - weaving
D04 - braiding
D05 - sewing
D06 - treatment of textiles or the like
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E01 - construction of roads, railways, or bridges
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F - mechanical engineering
F01 - machines or engines in general
F02 - combustion engines
F03 - machines or engines for liquids
F04 - positive - displacement machines for liquids
F05 - indexing schemes relating to engines or pumps in various subclasses of classes f01-f04
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F16 - engineering elements and units
F17 - storing or distributing gases or liquids
F21 - lighting
F22 - steam generation
F23 - combustion apparatus
F24 - heating
F25 - refrigeration or cooling
F26 - drying
F27 - furnaces
F28 - heat exchange in general
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F42 - ammunition
F99 - subject matter not otherwise provided for in this section
G - physics
G01 - measuring
G02 - optics
G03 - photography
G04 - horology
G05 - controlling
G06 - computing
G07 - checking-devices
G08 - signalling
G09 - education
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G12 - instrument details
G16 - information and communication technology [ict] specially adapted for specific application fields
G21 - nuclear physics
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H - electricity
H01 - basic electric elements
H02 - generation
H03 - basic electronic circuitry
H04 - electric communication technique
H05 - electric techniques not otherwise provided for
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Y02 - technologies or applications for mitigation or adaptation against climate change
Y04 - information or communication technologies having an impact on other technology areas
Y10 - technical subjects covered by former uspc

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Title: Catalysts and process for liquid hydrocarbon fuel production

Abstract

The present invention provides a novel process and system in which a mixture of carbon monoxide and hydrogen synthesis gas, or syngas, is converted into hydrocarbon mixtures composed of high quality gasoline components, aromatic compounds, and lower molecular weight gaseous olefins in one reactor or step. The invention utilizes a novel molybdenum-zeolite catalyst in high pressure hydrogen for conversion, as well as a novel rhenium-zeolite catalyst in place of the molybdenum-zeolite catalyst, and provides for use of the novel catalysts in the process and system of the invention.

Inventors:: White, Mark G.; Liu, Shetian

Issue Date:: 2020-12-01

Research Org.:: Mississippi State Univ., Starkville, MS (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1771681

Patent Number(s):: 10850266

Application Number:: 15/714,238

Assignee:: The University of Southern Mississippi (Starkville, MS)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2229/18 - to introduce other elements into or onto the molecular sieve itself
B01J23/28 - Molybdenum
B01J29/0341 - {containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium}
B01J29/076 - containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B01J29/084 - {Y-type faujasite}
B01J29/166 - {Y-type faujasite}
B01J29/26 - containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B01J29/48 - containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B01J29/78 - containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B01J29/7815 - {Zeolite Beta}
B01J29/7876 - {MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25}
B01J37/0201 - {Impregnation}

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2/334 - {containing molecular sieve catalysts}
C10G2400/30 - Aromatics

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10L - FUELS NOT OTHERWISE PROVIDED FOR
C10L1/08 - for compression ignition
C10L3/12 - Liquefied petroleum gas {

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DOE Contract Number:: FG36-06GO86025

Resource Type:: Patent

Resource Relation:: Patent File Date: 09/25/2017

Country of Publication:: United States

Language:: English

Citation Formats


                    White, Mark G., and Liu, Shetian. Catalysts and process for liquid hydrocarbon fuel production.  United States: N. p., 2020. 
        Web.

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                    White, Mark G., & Liu, Shetian. Catalysts and process for liquid hydrocarbon fuel production.  United States.

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                    White, Mark G., and Liu, Shetian. Tue .  
        "Catalysts and process for liquid hydrocarbon fuel production".  United States.  https://www.osti.gov/servlets/purl/1771681.

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@article{osti_1771681,

  title        = {Catalysts and process for liquid hydrocarbon fuel production},

  author       = {White, Mark G. and Liu, Shetian},

  abstractNote = {The present invention provides a novel process and system in which a mixture of carbon monoxide and hydrogen synthesis gas, or syngas, is converted into hydrocarbon mixtures composed of high quality gasoline components, aromatic compounds, and lower molecular weight gaseous olefins in one reactor or step. The invention utilizes a novel molybdenum-zeolite catalyst in high pressure hydrogen for conversion, as well as a novel rhenium-zeolite catalyst in place of the molybdenum-zeolite catalyst, and provides for use of the novel catalysts in the process and system of the invention.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {12}

}

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Works referenced in this record:

Catalysts for the conversion of methanol to ethylene plus gasoline
patent, October 1984

Brennan, James A.; Lucki, Stanley J.; Schoennagel, Hans J.
US Patent Document 4,480,145
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Conversion of Carbohydrates to Levulinic Acid Esters
patent-application, July 2005

Saravanamurugan, Shunmugavel; Riisager, Anders
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Screening of Alkali-Promoted Vapor-Phase-Synthesized Molybdenum Sulfide Catalysts for the Production of Alcohols from Synthesis Gas
journal, August 1997

Liu, Zhenyu; Li, Xianguo; Close, Michael R.
Industrial & Engineering Chemistry Research, Vol. 36, Issue 8
https://doi.org/10.1021/ie960648d

Hybrid catalyst for the deep catalytic cracking of petroleum naphthas and other hydrocarbon feedstocks
patent-application, January 2004

Le Van Mao, Raymond
US Patent Application 10/352770; 20040014593
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Methods of isomerizing xylenes with a catalyst reduced in the presence of hydrogen and a base
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Brown, Scott H.; Cheung, Tin Tack
US Patent Application 11/959872; 20090163752
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The effect of calcination temperature on the catalytic performance of 2 wt.% Mo/HZSM-5 in methane aromatization
journal, March 2002

Tan, P. L.; Leung, Y. L.; Lai, S. Y.
Applied Catalysis A: General, Vol. 228, Issue 1-2
https://doi.org/10.1016/S0926-860X(01)00955-3

Process comprising reforming, synthesis, and hydrocracking
patent, May 1986

Minderhoud, Johannes K.; Post, Martin F. M.; Sie, Swan T.
US Patent Document 4,587,008
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Synthesis of gasoline-range hydrocarbons over Mo/HZSM-5 catalysts
journal, March 2009

Liu, Shetian; Gujar, Amit C.; Thomas, Peter
Applied Catalysis A: General, Vol. 357, Issue 1, p. 18-25
https://doi.org/10.1016/j.apcata.2008.12.033

Process for Production of Aromatic Hydrocarbon
patent-application, March 2009

Ichikawa, Masaru; Kojima, Ryoichi; Kikuchi, Satoshi
US Patent Application 11/816068; 20090076316
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Direct synthesis of HZSM-5 from natural clay
journal, January 2015

Pan, Feng; Lu, Xuchen; Zhu, Qingshan
Journal of Materials Chemistry A, Vol. 3, Issue 7
https://doi.org/10.1039/C4TA05791K

Reactions of methanol and higher alcohols over H-ZSM-5
journal, July 2009

Gujar, Amit C.; Guda, Vamshi Krishna; Nolan, Michael
Applied Catalysis A: General, Vol. 363, Issue 1-2, p. 115-121
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Aromatization of methane over zeolite supported molybdenum: active sites and reaction mechanism
journal, March 2002

Ha, V.
Journal of Molecular Catalysis A: Chemical, Vol. 181, Issue 1-2
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Process for the isomerization of a vinylidene olefin
patent-application, January 2003

Doll, Michael Joseph; Murray, Brendan Dermot
US Patent Application 10/166402; 20030009071
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Synthesis promotion and product distribution for HZSM-5 and modified Zn/HZSM-5 catalysts for MTG process
journal, October 2016

Fattahi, Maryam; Behbahani, Reza Mosayebi; Hamoule, Touba
Fuel, Vol. 181
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A short review of heterogeneous catalytic process for mixed alcohols synthesis via syngas
journal, September 2009

Fang, Kegong; Li, Debao; Lin, Minggui
Catalysis Today, Vol. 147, Issue 2, p. 133-138
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Raman and X-Ray Absorption Studies of Mo Species in Mo/H-ZSM5 Catalysts for Non-Oxidative CH4 Reactions
journal, April 2000

Li, Wei; Meitzner, George D.; Borry, Richard W.
Journal of Catalysis, Vol. 191, Issue 2
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Enhanced catalyst for conversion of syngas to liquid motor fuels
patent, December 1985

Coughlin, Peter K.; Rabo, Jule A.
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Stability, structure, and oxidation state of Mo/H-ZSM-5 catalysts during reactions of CH4 and CH4–CO2 mixtures
journal, February 2005

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Journal of Catalysis, Vol. 230, Issue 1
https://doi.org/10.1016/j.jcat.2004.11.037

Absorptive Hydrogen Scavenging for Enhanced Aromatics Yield During Non‐oxidative Methane Dehydroaromatization on Mo/H‐ZSM‐5 Catalysts
journal, November 2018

Kumar, Anurag; Song, Kepeng; Liu, Lingmei
Angewandte Chemie, Vol. 130, Issue 47
https://doi.org/10.1002/ange.201809433

Process to separate 1,3-propanediol or glycerol, or a mixture thereof from a biological mixture
patent, August 2003

Corbin, David Richard; Norton, Tucker
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Similar Records

Title: Catalysts and process for liquid hydrocarbon fuel production

Abstract

Citation Formats

Catalysts for the conversion of methanol to ethylene plus gasoline patent, October 1984

Conversion of Carbohydrates to Levulinic Acid Esters patent-application, July 2005

Screening of Alkali-Promoted Vapor-Phase-Synthesized Molybdenum Sulfide Catalysts for the Production of Alcohols from Synthesis Gas journal, August 1997

Hybrid catalyst for the deep catalytic cracking of petroleum naphthas and other hydrocarbon feedstocks patent-application, January 2004

Methods of isomerizing xylenes with a catalyst reduced in the presence of hydrogen and a base patent-application, June 2009

The effect of calcination temperature on the catalytic performance of 2 wt.% Mo/HZSM-5 in methane aromatization journal, March 2002

Process comprising reforming, synthesis, and hydrocracking patent, May 1986

Synthesis of gasoline-range hydrocarbons over Mo/HZSM-5 catalysts journal, March 2009

Process for Production of Aromatic Hydrocarbon patent-application, March 2009

Direct synthesis of HZSM-5 from natural clay journal, January 2015

Reactions of methanol and higher alcohols over H-ZSM-5 journal, July 2009

Aromatization of methane over zeolite supported molybdenum: active sites and reaction mechanism journal, March 2002

Process for the isomerization of a vinylidene olefin patent-application, January 2003

Synthesis promotion and product distribution for HZSM-5 and modified Zn/HZSM-5 catalysts for MTG process journal, October 2016

A short review of heterogeneous catalytic process for mixed alcohols synthesis via syngas journal, September 2009

Raman and X-Ray Absorption Studies of Mo Species in Mo/H-ZSM5 Catalysts for Non-Oxidative CH4 Reactions journal, April 2000

Enhanced catalyst for conversion of syngas to liquid motor fuels patent, December 1985

Stability, structure, and oxidation state of Mo/H-ZSM-5 catalysts during reactions of CH4 and CH4–CO2 mixtures journal, February 2005

Absorptive Hydrogen Scavenging for Enhanced Aromatics Yield During Non‐oxidative Methane Dehydroaromatization on Mo/H‐ZSM‐5 Catalysts journal, November 2018

Process to separate 1,3-propanediol or glycerol, or a mixture thereof from a biological mixture patent, August 2003

Catalysts for the conversion of methanol to ethylene plus gasoline
patent, October 1984

Conversion of Carbohydrates to Levulinic Acid Esters
patent-application, July 2005

Screening of Alkali-Promoted Vapor-Phase-Synthesized Molybdenum Sulfide Catalysts for the Production of Alcohols from Synthesis Gas
journal, August 1997

Hybrid catalyst for the deep catalytic cracking of petroleum naphthas and other hydrocarbon feedstocks
patent-application, January 2004

Methods of isomerizing xylenes with a catalyst reduced in the presence of hydrogen and a base
patent-application, June 2009

The effect of calcination temperature on the catalytic performance of 2 wt.% Mo/HZSM-5 in methane aromatization
journal, March 2002

Process comprising reforming, synthesis, and hydrocracking
patent, May 1986

Synthesis of gasoline-range hydrocarbons over Mo/HZSM-5 catalysts
journal, March 2009

Process for Production of Aromatic Hydrocarbon
patent-application, March 2009

Direct synthesis of HZSM-5 from natural clay
journal, January 2015

Reactions of methanol and higher alcohols over H-ZSM-5
journal, July 2009

Aromatization of methane over zeolite supported molybdenum: active sites and reaction mechanism
journal, March 2002

Process for the isomerization of a vinylidene olefin
patent-application, January 2003

Synthesis promotion and product distribution for HZSM-5 and modified Zn/HZSM-5 catalysts for MTG process
journal, October 2016

A short review of heterogeneous catalytic process for mixed alcohols synthesis via syngas
journal, September 2009

Raman and X-Ray Absorption Studies of Mo Species in Mo/H-ZSM5 Catalysts for Non-Oxidative CH4 Reactions
journal, April 2000

Enhanced catalyst for conversion of syngas to liquid motor fuels
patent, December 1985

Stability, structure, and oxidation state of Mo/H-ZSM-5 catalysts during reactions of CH4 and CH4–CO2 mixtures
journal, February 2005

Absorptive Hydrogen Scavenging for Enhanced Aromatics Yield During Non‐oxidative Methane Dehydroaromatization on Mo/H‐ZSM‐5 Catalysts
journal, November 2018

Process to separate 1,3-propanediol or glycerol, or a mixture thereof from a biological mixture
patent, August 2003