Encapsulated sulfide glass solid electrolytes and solid-state laminate electrode assemblies
Abstract
Nanofilm-encapsulated sulfide glass solid electrolyte structures and methods for making the encapsulated glass structures involve a lithium ion conducting sulfide glass sheet encapsulated on its opposing major surfaces by a continuous and conformal nanofilm made by atomic layer deposition (ALD). During manufacture, the reactive surfaces of the sulfide glass sheet are protected from deleterious reaction with ambient moisture, and the nanofilm can be configured to provide additional performance advantages, including enhanced mechanical strength and improved chemical resistance.
- Inventors:
- Issue Date:
- Research Org.:
- PolyPlus Battery Co., Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- OSTI Identifier:
- 1771651
- Patent Number(s):
- 10840547
- Application Number:
- 16/341,872
- Assignee:
- PolyPlus Battery Company (Berkeley, CA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
- DOE Contract Number:
- AR0000772
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 06/27/2018
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Visco, Steven J., Nimon, Vitaliy, Nimon, Yevgeniy S., and Katz, Bruce D. Encapsulated sulfide glass solid electrolytes and solid-state laminate electrode assemblies. United States: N. p., 2020.
Web.
Visco, Steven J., Nimon, Vitaliy, Nimon, Yevgeniy S., & Katz, Bruce D. Encapsulated sulfide glass solid electrolytes and solid-state laminate electrode assemblies. United States.
Visco, Steven J., Nimon, Vitaliy, Nimon, Yevgeniy S., and Katz, Bruce D. Tue .
"Encapsulated sulfide glass solid electrolytes and solid-state laminate electrode assemblies". United States. https://www.osti.gov/servlets/purl/1771651.
@article{osti_1771651,
title = {Encapsulated sulfide glass solid electrolytes and solid-state laminate electrode assemblies},
author = {Visco, Steven J. and Nimon, Vitaliy and Nimon, Yevgeniy S. and Katz, Bruce D.},
abstractNote = {Nanofilm-encapsulated sulfide glass solid electrolyte structures and methods for making the encapsulated glass structures involve a lithium ion conducting sulfide glass sheet encapsulated on its opposing major surfaces by a continuous and conformal nanofilm made by atomic layer deposition (ALD). During manufacture, the reactive surfaces of the sulfide glass sheet are protected from deleterious reaction with ambient moisture, and the nanofilm can be configured to provide additional performance advantages, including enhanced mechanical strength and improved chemical resistance.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Nov 17 00:00:00 EST 2020},
month = {Tue Nov 17 00:00:00 EST 2020}
}
Works referenced in this record:
Characterization of Li2S?P2S5 glass-ceramics as a solid electrolyte for lithium secondary batteries
journal, November 2004
- Hayashi, A.
- Solid State Ionics, Vol. 175, Issue 1-4
Lithium ion conductive glass-ceramics and electric cells and gas sensors using the same
patent, February 2000
- Fu, Jie
- US Patent Document 6,030,909
Inorganic solid electrolyte and lithium cell component
patent-application, January 2004
- Kugai, Hirokazu; Ota, Nobuhiro
- US Patent Application 10/380839; 20040005504
Lithium ion conductive solid electrolyte and method for manufacturing the same
patent-application, April 2007
- Inda, Yasushi
- US Patent Application 11/453919; 20070087269
Encapsulated Sulfide Glass Solid Electrolytes and Solid-state Laminate Electrode Assemblies
patent-application, August 2020
- Visco, Steven J.; Nimon, Vitaliy; Nimon, Yevgeniy S.
- US Patent Application 16/781713; 20200251773
Solid-state Laminate Electrode Assembly Fabrication and Making Thin Extruded Lithium Metal Foils
patent-application, August 2019
- Visco, Steven J.; Nimon, Vitaliy; NImon, Yevgeniy S.
- US Patent Application 16/341874; 20190237810
Ionically conductive composites for protection of active metal anodes
patent, October 2007
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,282,296
Devices and Methods for Reducing Battery Defects
patent-application, December 2015
- Neudecker, Bernd Jurgen; Snyder, Shawn William; Ishikawa, Tetsuya
- US Patent Application 14/722077; 20150349371
Preparation and Conductivity Measurements of SiS[sub 2]-Li[sub 2]S-LiBr Lithium Ion Conductive Glasses
journal, January 1985
- Sahami, Saeed
- Journal of The Electrochemical Society, Vol. 132, Issue 4
In situ formed ionically conductive membranes for protection of active metal anodes and battery cells
patent, February 2012
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 8,114,171
Glass Containers with Delamination Resistance and Improved Strength
patent-application, June 2014
- Chang, Theresa; Danielson, Paul Stephen; DeMartino, Steven Edward
- US Patent Application 14/075605; 20140151371
Methods of Making Lithium Ion Conducting Sulfide Glass
patent-application, January 2020
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 16/556736; 20200028209
Ionically conductive membranes for protection of active metal anodes and battery cells
patent-application, March 2008
- Visco, Steven; Nimon, Yevgeniy; Katz, Bruce
- US Patent Application 11/824574; 20080057386
Lithium ion conducting solid electrolytes prepared from Li2S, elemental P and S
journal, October 2006
- Mizuno, F.; Ohtomo, T.; Hayashi, A.
- Solid State Ionics, Vol. 177, Issue 26-32
Cyclic voltammetry studies of the lithiumthioborate glass—indium interface
journal, November 1989
- Rudolph, B.; Burckhardt, W.; Staikov, G.
- Electrochimica Acta, Vol. 34, Issue 11
Preparation and conductivity measurements of SiS2Li2S glasses doped with LiBr and LiCl
journal, January 1986
- Kennedy, J.; Sahami, S.; Shea, S.
- Solid State Ionics, Vol. 18-19
Vitreous Solid Electrolyte Sheets of Li Ion Conducting Sulfur-based Glass and Associated Structures, Cells and Methods
patent-application, June 2016
- Visco, Steven J.; NImon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 14/954812; 20160190640
Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
patent, October 2007
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 7,282,295
Protected Lithium Electrodes Having A Porous Electrolyte Interlayer And Associated Battery Cells
patent-application, June 2014
- Visco, Steven; Katz, Bruce; Nimon, Yevgeniy
- US Patent Application 14/156267; 20140170465
Method for making an electrochemical cell
patent, October 1996
- Bates, John B.; Dudney, Nancy J.
- US Patent Document 5,567,210
Electrolyte for an electrochemical cell
patent, January 1997
- Bates, John B.; Dudney, Nancy J.
- US Patent Document 5,597,660
Alkali ion conductive glass-ceramics and electric cells and gas sensors using the same
patent, May 2007
- Fu, Jie
- US Patent Document 7,211,532
Composite solid electrolyte for protection of active metal anodes
patent, May 2012
- Visco, Steven J.; DeJonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,182,943
Vitreous materials with ionic conductivity, the preparation of same and the electrochemical applications thereof
patent, April 1985
- Carette, Brigitte; Kone, Ali; Souquet, Jean-Louis
- US Patent Document 4,513,070
Substantially impervious lithium super ion conducting membranes
patent, December 2012
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,334,075
Lithium/sulfur battery with hermetically sealed anode
patent, May 2013
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Document 8,445,136
Compliant seal structures for protected active metal anodes
patent, September 2015
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Document 9,130,198
Electrode Active Material Layer, All Solid State battery, Manufacturing Method for Electrode Active Material Layer, and Manufacturing Method for All Solid State Battery
patent-application, March 2011
- Kamiya, Masato; Ueno, Yukiyoshi; Hama, Shigenori
- US Patent Application 12/877382; 20110065007
Glass–ceramic Li2S–P2S5 electrolytes prepared by a single step ball billing process and their application for all-solid-state lithium–ion batteries
journal, September 2009
- Trevey, James; Jang, Jum Suk; Jung, Yoon Seok
- Electrochemistry Communications, Vol. 11, Issue 9
Bonded Intermediate Substrate and Method of Making Same
patent-application, May 2011
- Pinnington, Thomas Henry; Zahler, James M.; Park, Young-Bae
- US Patent Application 13/012336; 20110117726
Sulfide Solid Electrolyte Material, Lithium Solid-State Battery and Method for Producing Sulfide Solid Electrolyte Material
patent-application, May 2014
- Ohtomo, Takamasa; Kawamoto, Koji; Hama, Shigenori
- US Patent Application 14/130105; 20140141341
Active metal/aqueous electrochemical cells and systems
patent, June 2012
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 8,202,649
Sulfide Solid Electrolyte Glass, Method for Producing Sulfide Solid Electrolyte Glass, and Lithium Solid State Battery
patent-application, June 2013
- Kato, Yuki; Kawamoto, Koji; Hama, Shigenori
- US Patent Application 13/811052; 20130164632
Individually Encapsulated Solar Cells And Solar Cell Strings Having A Substantially Inorganic Protective Layer
patent-application, December 2007
- Sheats, James; Capps, Philip; Adriani, Paul
- US Patent Application 11/460617; 20070295385
Solid-state Laminate Electrode Assemblies and Methods of Making
patent-application, November 2017
- Visco, Steven J.; Nimon, Vitaliy; Ian, Wogan
- US Patent Application 15/592102; 20170331156
Compliant seal structures for protected active metal anodes
patent, November 2011
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Document 8,048,570
Active metal / aqueous electrochemical cells and systems
patent, November 2011
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 8,048,571
Sulfide Solid Electrolyte Material and Lithium Solid State Battery
patent-application, June 2013
- Ohtomo, Takamasa; Kawamoto, Koji; Hama, Higenori
- US Patent Application 13/818495; 20130164631
Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
patent, September 2015
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 9,123,941
Aqueous Electrolyte Lithium Sulfur Batteries
patent-application, October 2014
- Visco, Steven; Nimon, Yevgeniy; Katz, Bruce
- US Patent Application 14/334573; 20140322584
Ionically conductive composites for protection of active metal anodes
patent-application, March 2008
- Visco, Steven; Nimon, Yevgeniy; Katz, Bruce
- US Patent Application 11/824579; 20080057387
Glassy materials based on Li2S for all-solid-state lithium secondary batteries
journal, November 2004
- Tatsumisago, M.
- Solid State Ionics, Vol. 175, Issue 1-4
Rechargeable lithium battery for use in applications requiring a low to high power output
patent, October 1996
- Bates, John B.
- US Patent Document 5,569,520
Protective composite battery separator and electrochemical device component with red phosphorus
patent, November 2010
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,838,144
Solid State Battery
patent-application, May 2018
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 15/726302; 20180131040
Lithium battery with hermetically sealed anode
patent, April 2014
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Document 8,691,444
High energy density aqueous lithium/air-battery cells
patent, March 2014
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,673,477
Sulfide Solid Electrolyte Material
patent-application, February 2012
- Tatsumisago, Masahiro; Hayashi, Akitoshi; Hama, Shigenori
- US Patent Application 13/203379; 20120034529
Advanced lithium ion batteries based on solid state protected lithium electrodes
patent, June 2016
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 9,362,538
Cell containing alkali metal anode, cathode and alkali metal-metal-chalcogenide compound solid electrolyte
patent, June 1980
- Jacobson, Allan J.; Silbernagel, Bernard G.
- US Patent Document 4,208,474
Lithium anodes for electrochemical cells
patent, September 2004
- Skotheim, Terje A.; Sheehan, Christopher J.; Mikhaylik, Yuriy V.
- US Patent Document 6,797,428
Protected lithium electrodes having tape cast ceramic and glass-ceramic membranes
patent, September 2015
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 9,136,568
Electra-optical device including a nitrogen containing electrolyte
patent, October 1995
- Bates, John B.; Dudney, Nancy J.; Gruzalski, Greg R.
- US Patent Document 5,455,126
Lithium anodes for electrochemical cells
patent, May 2004
- Skotheim, Terje A.; Sheehan, Christopher J.; Mikhaylik, Yuriy V.
- US Patent Document 6,733,924
Isostatic compression method for producing solid state electrochemical cells
patent, October 1984
- Akridge, James R.; Vourlis, Harry
- US Patent Document 4,477,545
Standalone sulfide based lithium ion-conducting glass solid electrolyte and associated structures, cells and methods
patent, December 2018
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Document 10,147,968
Aluminum and sulfur electrochemical batteries and cells
patent, May 1995
- Licht, Stuart; Peramunage, Dharmasena
- US Patent Document 5,413,881
New lithium ion conductors based on Li2S-SiS2 system
journal, July 1992
- Kondo, S.; Takada, K.; Yamamura, Y.
- Solid State Ionics, Vol. 53-56
COMPOSITE SOLID ELECTROLYTE FOR PROTECTION OF ACTIVE METAL ANODES
patent-application, July 2007
- Visco, Steven J.; DeJonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Application 11/612741; 20070172739
Preparation and ionic conductivity of Li7P3S11−z glass-ceramic electrolytes
journal, October 2010
- Hayashi, Akitoshi; Minami, Keiichi; Ujiie, Satoshi
- Journal of Non-Crystalline Solids, Vol. 356, Issue 44-49, p. 2670-2673
Ionically conductive glasses based on SiS2
journal, August 1989
- Kennedy, J. H.
- Materials Chemistry and Physics, Vol. 23, Issue 1-2
Standalone Sulfide Based Lithium Ion-conducting Glass Solid Electrolyte and Associated Structures, Cells and Methods
patent-application, May 2019
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 56079746; 20190148768
Ionically Conductive Membranes For Protection Of Active Metal Anodes And Battery Cells
patent-application, December 2009
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Application 12/475403; 20090297935
Standalone Sulfide Based Lithium Ion-conducting Glass Solid Electrolyte and Associated Structures, Cells and Methods
patent-application, June 2016
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 14/954816; 20160156065
Lithium ion-conductive solid electrolyte and method for producing the same
patent, September 1999
- Takada, Kazunori; Iwamoto, Kazuya; Kondo, Shigeo
- US Patent Document 5,958,281
Battery Cells with Lithium Ion Conducting Tape-cast Ceramic, Glass and Glass-ceramic Membranes
patent-application, November 2015
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Application 14/815672; 20150340720
Preparation and characterization of lithium ion-conducting oxysulfide glasses
journal, November 2000
- Minami, T.
- Solid State Ionics, Vol. 136-137, Issue 1-2
Methods of Making and Inspecting a Web of Vitreous Lithium Sulfide Separator Sheet and Lithium Electrode Assemblies
patent-application, July 2020
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 16/784162; 20200243902
Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
patent, November 2010
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 7,829,212
Vitreous solid lithium cation conductive electrolyte
patent, August 1984
- Akridge, James R.
- US Patent Document 4,465,746
Method for Producing Solid Electrolyte Material-containing Sheet
patent-application, July 2012
- Nakamoto, Hirofumi; Ueno, Yukiyoshi; Hama, Shigenori
- US Patent Application 12/673131; 20120177997
Protective lithium ion conducting ceramic coating for lithium metal anodes and associate method
patent, May 1994
- Bates, John B.
- US Patent Document 5,314,765
Method and Apparatus for Manufacturing Member for Secondary Battery and Secondary Battery Using the Same
patent-application, July 2010
- Fukumoto, Yusuke; Hayashi, Tstsuya; Kubota, Kazunori
- US Patent Application 11/916170; 20100190063
Sulfide Solid Electrolyte Glass, Lithium Solid State Battery and Producing Method of Sulfide Solid Electrolyte Glass
patent-application, October 2013
- Hama, Shigenori; Ohtomo, Takamasa; Kato, Yuki
- US Patent Application 13/814364; 20130288134
A thin-film solid-state microbattery
journal, April 1993
- Jones, Steven D.; Akridge, James R.
- Journal of Power Sources, Vol. 44, Issue 1-3
Electrical properties of lithium conductive silicon sulfide glasses prepared by twin roller quenching
journal, January 1986
- Pradel, A.; Ribes, M.
- Solid State Ionics, Vol. 18-19
Lithium cell having a solid electrolyte constituted by a conductive vitreous compound
patent, October 1984
- Gabano, Jean-Paul; Duchange, Jean-Pierre
- US Patent Document 4,478,920
Stabilized anode for lithium-polymer batteries
patent, October 1999
- Skotheim, Terje A.; Soloveichik, Grigorii Lev; Gavrilov, Alexei B.
- US Patent Document 5,961,672
Preparation and characterization of lithium ion conducting Li2S–P2S5–GeS2 glasses and glass-ceramics
journal, October 2010
- Minami, Keiichi; Hayashi, Akitoshi; Tatsumisago, Masahiro
- Journal of Non-Crystalline Solids, Vol. 356, Issue 44-49
Ionically conductive membranes for protection of active metal anodes and battery cells
patent, June 2008
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,390,591
Compliant seal structures for protected active metal anodes
patent-application, February 2007
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 11/501676; 20070037058
Solid State Battery and Method of Producing the Same
patent-application, February 2010
- Kimura, Kenji; Tatsumisago, Masahiro; Hayashi, Akitoshi
- US Patent Application 12/532546; 20100040952
Lithium sulfur batteries and electrolytes and sulfur cathodes thereof
patent, May 2017
- Visco, Steven J.; Goncharenko, Nikolay; Nimon, Vitaliy
- US Patent Document 9,660,265
Method of Producing Solid Sulfide Electrolyte Material and Solid Sulfide Electrolyte Material
patent-application, April 2014
- Sugiura, Koichi; Kawamoto, Koji; Koyama, Takayuki
- US Patent Application 14/117784; 20140093785
Recent Advances in Inorganic Solid Electrolytes for Lithium Batteries
journal, June 2014
- Cao, Can; Li, Zhuo-Bin; Wang, Xiao-Liang
- Frontiers in Energy Research, Vol. 2
Ionically conductive sulfide-based lithium glasses
journal, August 1990
- Kennedy, John H.; Zhang, Zhengming; Eckert, Hellmut
- Journal of Non-Crystalline Solids, Vol. 123, Issue 1-3
Method of Producing negative electrode for lithium secondary cell
patent-application, March 2002
- Kugai, Hirokazu; Ota, Nobuhiro; Yamanaka, Shosaku
- US Patent Application 09/884633; 20020036131
Positive-Electrode Active Material Particle for All-Solid Battery and Method for Production Thereof
patent-application, March 2014
- Uchiyama, Takayuki
- US Patent Application 14/116253; 20140072875
Encapsulated Lithium Particles and Methods of Making and Use thereof
patent-application, March 2016
- Gadkaree, Kishor Purushottam; Kadam, Rahul Suryakant; Husted, Andrew Fleitz
- US Patent Application 14/493886; 20160087263
Sulfide Solid Electrolyte with Favorable Mechanical Property for All-Solid-State Lithium Battery
journal, July 2013
- Sakuda, Atsushi; Hayashi, Akitoshi; Tatsumisago, Masahiro
- Scientific Reports, Vol. 3, Issue 1
Complex Plane and 7Li NMR Studies of Arsenic Sulfide-Based Lithium Glasses
journal, January 1985
- Visco, Steven J.
- Journal of The Electrochemical Society, Vol. 132, Issue 7
Fast Li+ Ion Conduction in Li2O-Al2O3-TiO2-SiO2-P2O2 Glass-Ceramics
journal, July 1997
- Fu, Jie
- Journal of the American Ceramic Society, Vol. 80, Issue 7, p. 1901-1903
Crystalline solid lithium cation conductive electrolyte
patent, August 1984
- Akridge, James R.
- US Patent Document 4,465,745
Lithium ion conductive solid electrolyte and production process thereof
patent-application, October 2007
- Inda, Yasushi
- US Patent Application 11/727489; 20070231704
Protected lithium electrodes having a polymer electrolyte interlayer and battery cells thereof
patent, August 2013
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 8,501,339
Improved stability for the SiS2-P2S5-Li2S-LiI glass system
journal, September 1988
- Kennedy, John H.; Zhang, Zhengming
- Solid State Ionics, Vol. 28-30
Catholytes for aqueous lithium/air battery cells
patent, February 2014
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,658,304
Method of making an electrolyte for an electrochemical cell
patent, April 1996
- Bates, John B.; Dudney, Nancy J.
- US Patent Document 5,512,147
Electrical properties of new glasses based on the Li2S–SiS2 system
journal, October 1999
- Bartholomew, Roger F.; Young, Dianna M.; Ellison, Adam J. G.
- Journal of Non-Crystalline Solids, Vol. 256-257, p. 242-247
Substantially impervious lithium super ion conducting membranes
patent, February 2014
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,652,686
Lithium battery cell with protective membrane having a garnet like structure
patent, March 2016
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 9,287,573
Plating metal negative electrodes under protective coatings
patent, April 2004
- Chu, May-Ying; Visco, Steven J.; De Jonghe, Lutgard C.
- US Patent Document 6,723,140
Solid state batteries using vitreous solid electrolytes
journal, January 1986
- Akridge, J.; Vourlis, H.
- Solid State Ionics, Vol. 18-19
Sulfide-Based Lithium-Io-Conducting Solid Electrolyte Glass, All-Solid Lithium Secondary Battery, and Method for Manufacturing All-Solid Lithium Secondary Battery
patent-application, June 2009
- Shiohara, Yuji; Kawase, Takeo; Kondo, Shigeo
- US Patent Application 12/327343; 20090142669
Stabilized anode for lithium-polymer batteries
patent, July 1997
- Skotheim, Terje A.
- US Patent Document 5,648,187
Encapsulated Sulfide Glass Solid Electrolytes and Solid-state Laminate Electrode Assemblies
patent-application, January 2019
- Visco, Steven J.; Nimon, Vitaliy; Nimon, Yevgeniy S.
- US Patent Application 16/012588; January 10, 2019
Treating Sulfide Glass Surfaces and Making Solid State Laminate Electrode Assemblies
patent-application, April 2020
- Visco, Steven J.; Nimon, Vitaliy; Nimon, Yevgeniy S.
- US Patent Application 16/663177; 20200127275
Catholytes for aqueous lithium/air battery cells
patent, December 2012
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,323,820
Electrochemical device component with protected alkali metal electrode
patent, December 2010
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,858,223
Making and Inspecting a Web of Vitreous Lithium Sulfide Separator Sheet and Lithium Electrode Assemblies and Battery Cells
patent-application, June 2019
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 16/174058; 20190173128
Preparation and Structure of Lithium-Ion-Conducting Mixed-Anion Glasses in the System LiBO2-LiBS2
journal, September 1988
- Tatsumisago, Masahiro; Yoneda, Kazuya; Minami, Tsutomu
- Journal of the American Ceramic Society, Vol. 71, Issue 9
Hydrogels for aqueous lithium/air battery cells
patent, March 2013
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,389,147
Lithium Ion Conductive Sulfide-Based Solid Electrolyte and All-Solid Lithium Battery Using Same
patent-application, June 2009
- Seino, Yoshikatsu; Nakagawa, Masaru; Senga, Minoru
- US Patent Application 12/096481; 20090159839
Protected Lithium Electrodes with Protective Membrane Having a Garnet Like Structure and Lithium Battery Cells Thereof
patent-application, July 2016
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Application 14/994011; 20160197326
Quaternary vitreous solid lithium cation conductive electrolyte
patent, April 1986
- Akridge, James R.
- US Patent Document 4,585,714
Alkaline cation conductive vitreous composition and a method of preparing such a composition
patent, May 1982
- Malugani, Jean-Pierre; Robert, Guy
- US Patent Document 4,331,750
Active metal/aqueous electrochemical cells and systems
patent, February 2010
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 7,666,233
High-Performance All-Solid Lithium Battery
patent-application, October 2007
- Seimo, Yoshikatsu; Takada, Kazunori
- US Patent Application 11/628030; 20070248888
Mechanochemical synthesis of lithium ion conducting glasses and glass–ceramics in the system Li2S–P–S
journal, October 2005
- Ohtomo, Takamasa; Mizuno, Fuminori; Hayashi, Akitoshi
- Solid State Ionics, Vol. 176, Issue 31-34
Sulfide Solid Electrolyte
patent-application, July 2012
- Tatsumisago, Masahiro; Hayashi, Akitoshi; Hama, Shigenori
- US Patent Application 13/389129; 20120189918
Fast Li+ ion transport in iodine-thioborate glasses
journal, August 1984
- Burckhardt, W.; Makyta, M.; Levasseur, A.
- Materials Research Bulletin, Vol. 19, Issue 8
Process for Producing Sulfide-based Solid Electrolyte
patent-application, May 2011
- Hama, Shigenori; Hayashi, Mitsuhiko
- US Patent Application 13/001708; 20110108642
Superionic conduction in Li 2 S - P 2 S 5 - LiI - glasses
journal, October 1981
- Mercier, René; Malugani, Jean-Pierre; Fahys, Bernard
- Solid State Ionics, Vol. 5
Study on visco-elastic properties enhancement of MWCNT based polypropylene nanocomposites
journal, January 2020
- Sonawane, Shriram S.; Thakur, Parag P.; Paul, Ritesh
- Materials Today: Proceedings, Vol. 29
Substituted lithium orthosilicates and solid electrolytes therefrom
patent, August 1977
- Shannon, Robert D.; Taylor, Barry Edward
- US Patent Document 4,042,482
Electrode structures for aqueous electrolyte lithium sulfur batteries
patent, September 2014
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 8,828,573
Ionically conductive composites for protection of active metal anodes
patent, October 2007
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,282,302
Aqueous electrolyte lithium sulfur batteries
patent, September 2014
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 8,828,575
Lithium anodes for electrochemical cells
patent-application, January 2002
- Skotheim, Terje A.; Sheehan, Christopher J.; Mikhaylik, Yuriy V.
- US Patent Application 09/864890; 20020012846
Electrolyte compositions for aqueous electrolyte lithium sulfur batteries
patent, September 2014
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 8,828,574
Lithium battery having a protected lithium electrode and an ionic liquid catholyte
patent, September 2014
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 8,828,580
Lithium anodes for electrochemical cells
patent, July 2007
- Skotheim, Terje A.; Sheehan, Christopher J.; Mikhaylik, Yuriy V.
- US Patent Document 7,247,408
All-solid-state lithium secondary batteries using the 75Li2S·25P2S5 glass and the 70Li2S·30P2S5 glass–ceramic as solid electrolytes
journal, July 2013
- Ohtomo, Takamasa; Hayashi, Akitoshi; Tatsumisago, Masahiro
- Journal of Power Sources, Vol. 233
Lithium Ion Conducting Sulfide Glass Fabrication
patent-application, August 2020
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Application 16/721787; 20200259212
Sulfide-based lithium-ion-conducting solid electrolyte glass, all-solid lithium secondary battery, and method for manufacturing all-solid lithium secondary battery
patent, July 2014
- Shinohara, Yuji; Kawase, Takeo; Kondo, Shigeo
- US Patent Document 8,778,543
Compositions and Methods for Protection of Active Metal Anodes and Polymer Electrolytes
patent-application, December 2008
- Visco, Steven J.; Nimon, Yevgeniy S,; Katz, Bruce D.
- US Patent Application 12/201264; 20080318132
Methods of Making and Inspecting a Web of Vitreous Lithium Sulfide Separator Sheet and LIthium Electrode Assemblies
patent-application, August 2017
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 15/380989; 20170229731
Mechanochemical synthesis of amorphous solid electrolytes using SiS2 and various lithium compounds
journal, November 2004
- Hayashi, A.
- Solid State Ionics, Vol. 175, Issue 1-4
Electrical and electrochemical properties of Li2S–P2S5–P2O5 glass–ceramic electrolytes
journal, August 2005
- Ohtomo, Takamasa; Mizuno, Fuminori; Hayashi, Akitoshi
- Journal of Power Sources, Vol. 146, Issue 1-2, p. 715-718
Polymer adhesive seals for protected anode architectures
patent, March 2012
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Document 8,129,052
Protected Lithium Electrodes Having a Porous Electrolyte Interlayer and Associated Battery Cells
patent-application, December 2016
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Application 15/150231; 20160351879
Protected Active Metal Electrode and Battery Cell Structures with Non-Aqueous Interlayer Architecture
patent-application, January 2016
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Application 14/809083; 20160028063
Vitreous phosphorus oxide-sulfide solid lithium electrolyte
patent, July 1986
- Akridge, James R.
- US Patent Document 4,599,284
Vitreous solid electrolyte sheets of Li ion conducting sulfur-based glass and associated structures, cells and methods
patent, December 2018
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Document 10,164,289
Battery Unit
patent-application, March 2010
- Kimura, Kenji; Tatsumisago, Masahiro; Hayashi, Akitoshi
- US Patent Application 12/550447; 20100075209
Advanced Lithium Ion Batteries Based on Solid State Protected Lithium Electrodes
patent-application, December 2016
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Application 15/149012; 20160351878
Thin-film rechargeable lithium batteries
journal, March 1995
- Bates, J. B.; Dudney, N. J.; Lubben, D. C.
- Journal of Power Sources, Vol. 54, Issue 1, p. 58-62
Solid electrolyte, method for preparing the same, and battery using the same
patent, September 2007
- Park, Young-sin; Lee, Jong-heun; Jin, Young-gu
- US Patent Document 7,273,682
Electrical properties of amorphous lithium electrolyte thin films
journal, July 1992
- Bates, J. B.; Dudney, N. J.; Gruzalski, G. R.
- Solid State Ionics, Vol. 53-56, Issue Part 1, p. 647-654
Solid State Electrolyte Layer, Electrode Active Material Layer, All Solid State Lithium Battery, Manufacturing Method for Solid State Electrolyte Layer, And Manufacturing Method for Electrode Active Material Layer
patent-application, March 2011
- Hama, Shigenori; Kawamoto, Koji; Wakasugi, Satoshi
- US Patent Application 12/891242; 20110076570
Recent development of sulfide solid electrolytes and interfacial modification for all-solid-state rechargeable lithium batteries
journal, March 2013
- Tatsumisago, Masahiro; Nagao, Motohiro; Hayashi, Akitoshi
- Journal of Asian Ceramic Societies, Vol. 1, Issue 1
Electrochemical cell including a solid electrolyte made from a cation conductive vitreous compound
patent, April 1984
- Duchange, Jean-Pierre; Gabano, Jean-Paul
- US Patent Document 4,444,857
Thin film battery and method for making same
patent, August 1994
- Bates, John B.; Dudney, Nancy J.; Gruzalski, Greg R.
- US Patent Document 5,338,625
Lithium ion-conductive solid electrolyte containing lithium titanium phosphate
patent, January 1991
- Adachi, Ginya; Imanaka, Nobuhito; Aono, Hiromichi
- US Patent Document 4,985,317
Ionically conductive composites for protection of active metal anodes
patent-application, March 2008
- Visco, Steven; Nimon, Yevgeniy; Katz, Bruce
- US Patent Application 11/823847; 20080057399
Lithium Battery with Hermetically Sealed Anode
patent-application, June 2014
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgar
- US Patent Application 14/181423; 20140162108
Compliant Seal Structures for Protected Active Metal Anodes
patent-application, January 2016
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 14/811550; 20160028053
Multilayer Material Based on Active Lithium, Method of Preparation and Applications in Electrochemical Generators
patent-application, May 2013
- Zaghib, Karim; Dontigny, Martin; Petitclerc, Michel
- US Patent Application 13/724058; 20130122365
Electrical and electrochemical properties of glass–ceramic electrolytes in the systems Li2S–P2S5–P2S3 and Li2S–P2S5–P2O5
journal, June 2011
- Minami, Keiichi; Hayashi, Akitoshi; Ujiie, Satoshi
- Solid State Ionics, Vol. 192, Issue 1
Vitreous Solid Electrolyte Sheets of Li Ion Conducting Sulfur-based Glass and Associated Structures, Cells and Methods
patent-application, June 2019
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 16/179803; 20190181496
Fast Li+ ion conducting glass-ceramics in the system Li2O–Al2O3–GeO2–P2O5
journal, December 1997
- Fu, J.
- Solid State Ionics, Vol. 104, Issue 3-4
Protected active metal electrode and battery cell with ionically conductive protective architecture
patent, October 2012
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 8,293,398
Lithium Sulfur Batteries and Electrolytes and Sulfur Cathodes Thereof
patent-application, July 2015
- Visco, Steven J.; Goncharenko, Nikolay; Nimon, Vitaliy
- US Patent Application 14/657695; 20150214555
Mechanochemical synthesis of Li2S–P2S5 glass electrolytes with lithium salts
journal, October 2010
- Minami, Keiichi; Hayashi, Akitoshi; Tatsumisago, Masahiro
- Solid State Ionics, Vol. 181, Issue 33-34
Plating metal negative electrodes under protective coatings
patent, June 2002
- Chu, May-Ying; Visco, Steven J.; De Jonghe, Lutgard C.
- US Patent Document 6,402,795
Cathodes and reservoirs for aqueous lithium/air battery cells
patent, June 2013
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,455,131
Superionic conductivity of glass-ceramics in the system Li 2 O- Al 2 O 3 -TiO 2 -P 2 O 5
journal, April 1997
- Fu, Jie
- Solid State Ionics, Vol. 96, Issue 3-4
Membranes in Lithium Ion Batteries
journal, July 2012
- Yang, Min; Hou, Junbo
- Membranes, Vol. 2, Issue 3, p. 367-383
Electric cells and gas sensors using alkali ion conductive glass ceramic
patent, November 2001
- Fu, Jie
- US Patent Document 6,315,881
Methods of Making Lithium Ion Conducting Sulfide Glass
patent-application, January 2020
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Application 16/509385; 20200014063
Formation of superionic crystals from mechanically milled Li2S–P2S5 glasses
journal, February 2003
- Hayashi, Akitoshi; Hama, Shigenori; Minami, Tsutomu
- Electrochemistry Communications, Vol. 5, Issue 2
Electrode Body for Lithium Battery, and Lithium Battery
patent-application, March 2016
- Ichikawa, Sukenori; Hokari, Hirofumi
- US Patent Application 14/847729; 20160072153
Method for forming encapsulated lithium electrodes having glass protective layers
patent, April 2001
- Visco, Steven J.; Tsang, Floris Y.
- US Patent Document 6,214,061
Lithium ion conductive glass-ceramics and electric cells and gas sensors using the same
patent, November 2002
- Fu, Jie
- US Patent Document 6,485,622
Method for forming encapsulated lithium electrodes having glass protective layers
patent, August 2002
- Visco, Steven J.; Tsang, Floris Y.
- US Patent Document 6,432,584
Fabrication of electrode–electrolyte interfaces in all-solid-state rechargeable lithium batteries by using a supercooled liquid state of the glassy electrolytes
journal, January 2011
- Kitaura, Hirokazu; Hayashi, Akitoshi; Ohtomo, Takamasa
- J. Mater. Chem., Vol. 21, Issue 1
Complex Plane and 7Li NMR Studies of Highly Conductive Sulfide-Based Lithium Glasses
journal, January 1985
- Visco, Steven J.
- Journal of The Electrochemical Society, Vol. 132, Issue 4
Compliant seal structures for protected active metal anodes
patent, November 2010
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Document 7,824,806
Protected lithium electrodes based on sintered ceramic or glass ceramic membranes
patent, July 2014
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 8,778,522
Lithium Sulfur Batteries and Electrolytes and Sulfur Cathodes Thereof
patent-application, December 2017
- Visco, Steven J.; Goncharenko, Nikolay; Nimon, Vitaliy
- US Patent Application 15/582343; 20170365853
Solid-Electrolyte Battery
patent-application, July 2012
- Kanda, Ryoko; Yoshida, Kentaro; Uemura, Takashi
- US Patent Application 13/497059; 20120183834
Solid State Battery
patent-application, April 2012
- Visco, Steven; Nimon, Yevgeniy; Katz, Bruce
- US Patent Application 13/336459; 20120094188
Chemical Protection of a Lithium Surface
patent-application, May 2008
- De Jonghe, Lutgard; Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Application 11/944906; 20080113261
Rechargeable lithium battery for use in applications requiring a low to high power output
patent, March 1997
- Bates, John B.
- US Patent Document 5,612,152
Active metal/aqueous electrochemical cells and systems
patent, January 2010
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 7,645,543