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Title: Metal phosphide nanomaterials prepared from single source metal amides

Abstract

The present invention provides a novel solution or route for metal phosphide (MPx) nanomaterials from the thermal decomposition of metal bis[bis(diisopropylphosphino)amide], M[N(PPri2)2]2, and/or single-source precursors. Synthetic routes to MPx nanomaterials may be used in energy applications including batteries, semiconductors, magnets, catalyst, lasers, inks, electrocatalysts and photodiodes.

Inventors:
; ; ;
Issue Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1771629
Patent Number(s):
10836638
Application Number:
15/565,670
Assignee:
UNM Rainforest Innovations (Albuquerque, NM)
Patent Classifications (CPCs):
C - CHEMISTRY C22 - METALLURGY C22C - ALLOYS
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
DOE Contract Number:  
AC04-94AL85000
Resource Type:
Patent
Resource Relation:
Patent File Date: 04/08/2016
Country of Publication:
United States
Language:
English

Citation Formats

Kemp, Richard Alan, Dickie, Diane, Hernandez-Sanchez, Bernadette A., and Lambert, Timothy N. Metal phosphide nanomaterials prepared from single source metal amides. United States: N. p., 2020. Web.
Kemp, Richard Alan, Dickie, Diane, Hernandez-Sanchez, Bernadette A., & Lambert, Timothy N. Metal phosphide nanomaterials prepared from single source metal amides. United States.
Kemp, Richard Alan, Dickie, Diane, Hernandez-Sanchez, Bernadette A., and Lambert, Timothy N. Tue . "Metal phosphide nanomaterials prepared from single source metal amides". United States. https://www.osti.gov/servlets/purl/1771629.
@article{osti_1771629,
title = {Metal phosphide nanomaterials prepared from single source metal amides},
author = {Kemp, Richard Alan and Dickie, Diane and Hernandez-Sanchez, Bernadette A. and Lambert, Timothy N.},
abstractNote = {The present invention provides a novel solution or route for metal phosphide (MPx) nanomaterials from the thermal decomposition of metal bis[bis(diisopropylphosphino)amide], M[N(PPri2)2]2, and/or single-source precursors. Synthetic routes to MPx nanomaterials may be used in energy applications including batteries, semiconductors, magnets, catalyst, lasers, inks, electrocatalysts and photodiodes.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {11}
}

Works referenced in this record:

Synthesis and Characterization of Supported Co 2 P Nanoparticles by Grafting of Molecular Clusters into Mesoporous Silica Matrixes
journal, November 2002


A Novel Solvothermal Route to Nanocrystalline Sn4P3 with Red Phosphorous as Raw Material
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Stoichiometric molecular single source precursors to cobalt phosphides
journal, January 2014


Hexanuclear Gold(I) Phosphide Complexes as Platforms for Multiple Redox-Active Ferrocenyl Units
journal, December 2013


Au 19 Nanocluster Featuring a V-Shaped Alkynyl–Gold Motif
journal, January 2015