Polymeric membranes for separation of gases
Abstract
Membranes, methods of making the membranes, and methods of using the membranes are described herein. The membranes can comprise a gas permeable support layer, optionally an inorganic layer disposed on the support, and a selective polymer layer disposed on the inorganic layer. In some cases, the selective polymer layer can comprise an amine-containing polymer and an amino acid salt dispersed within the amine-containing polymer. In other cases, the selective polymer layer comprises a sterically hindered amine-containing polymer, such as a sterically hindered derivative of polyvinylamine. The membranes can be used, for example, to separate gaseous mixtures, such as flue gas.
- Inventors:
- Issue Date:
- Research Org.:
- The Ohio State Univ., Columbus, OH (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1771626
- Patent Number(s):
- 10835847
- Application Number:
- 15/577,954
- Assignee:
- Ohio State Innovation Foundation (Columbus, OH)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
- DOE Contract Number:
- FE0007632; FE0026919
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 05/31/2016
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Ho, W.S. Winston, and Chen, Yuanxin. Polymeric membranes for separation of gases. United States: N. p., 2020.
Web.
Ho, W.S. Winston, & Chen, Yuanxin. Polymeric membranes for separation of gases. United States.
Ho, W.S. Winston, and Chen, Yuanxin. Tue .
"Polymeric membranes for separation of gases". United States. https://www.osti.gov/servlets/purl/1771626.
@article{osti_1771626,
title = {Polymeric membranes for separation of gases},
author = {Ho, W.S. Winston and Chen, Yuanxin},
abstractNote = {Membranes, methods of making the membranes, and methods of using the membranes are described herein. The membranes can comprise a gas permeable support layer, optionally an inorganic layer disposed on the support, and a selective polymer layer disposed on the inorganic layer. In some cases, the selective polymer layer can comprise an amine-containing polymer and an amino acid salt dispersed within the amine-containing polymer. In other cases, the selective polymer layer comprises a sterically hindered amine-containing polymer, such as a sterically hindered derivative of polyvinylamine. The membranes can be used, for example, to separate gaseous mixtures, such as flue gas.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {11}
}
Works referenced in this record:
Facilitated transport of CO2 through various ion exchange membranes prepared by plasma graft polymerization
journal, August 1996
- Matsuyama, Hideto; Teramoto, Masaaki; Sakakura, Hiroshi
- Journal of Membrane Science, Vol. 117, Issue 1-2
Membranes comprising aminoacid salts in polyamine polymers and blends
patent, August 2000
- Ho, W. S. Winston
- US Patent Document 6,099,621
The reaction of CO2 with ethanolamines
journal, January 1979
- Danckwerts, P. V.
- Chemical Engineering Science, Vol. 34, Issue 4
Facilitated transport in ion-exchange membranes
journal, January 1980
- LeBlanc, Oliver H.; Ward, William J.; Matson, Stephen L.
- Journal of Membrane Science, Vol. 6
PVAm-PIP/PS Composite Membrane with High Performance for CO 2 /N 2 Separation
journal, March 2012
- Qiao, Zhihua; Wang, Zhi; Zhang, Chenxin
- AIChE Journal, Vol. 59, Issue 1
Membranes comprising of alkanolamines incorporated into poly(vinyl alcohol) matrix for CO2/N2 separation
journal, October 2007
- Francisco, Gil J.; Chakma, Amit; Feng, Xianshe
- Journal of Membrane Science, Vol. 303, Issue 1-2
Carbon Dioxide Capture Using a CO 2 -Selective Facilitated Transport Membrane
journal, February 2008
- Huang, Jin; Zou, Jian; Ho, W. S. Winston
- Industrial & Engineering Chemistry Research, Vol. 47, Issue 4
Steric hindrance effect on amine demonstrated in solid polymer membranes for CO2 transport
journal, October 2012
- Zhao, Yanan; Winston Ho, W. S.
- Journal of Membrane Science, Vol. 415-416
Kinetics of carbamate formation and breakdown
journal, November 1968
- Caplow, Michael.
- Journal of the American Chemical Society, Vol. 90, Issue 24
CO 2 -Selective Membranes Containing Sterically Hindered Amines for CO 2 /H 2 Separation
journal, September 2012
- Zhao, Yanan; Ho, W. S. Winston
- Industrial & Engineering Chemistry Research, Vol. 52, Issue 26
Improvement of CO2/N2 separation characteristics of polyvinylamine by modifying with ethylenediamine
journal, August 2011
- Yuan, Shuangjie; Wang, Zhi; Qiao, Zhihua
- Journal of Membrane Science, Vol. 378, Issue 1-2
A theoretical comparison of facilitated transport and solution-diffusion membrane modules for gas separation
journal, June 1988
- Gottschlich, D. E.; Roberts, D. L.; Way, J. D.
- Gas Separation & Purification, Vol. 2, Issue 2
Facilitated transport of CO2 in novel PVAm/PVA blend membrane
journal, September 2009
- Deng, Liyuan; Kim, Taek-Joong; Hägg, May-Britt
- Journal of Membrane Science, Vol. 340, Issue 1-2, p. 154-163
Hybrid Membrane, Method For Producing the Same and Use of Said Membrane
patent-application, April 2005
- Hennige, Volker; Hying, Christian; Horpel, Gerhard
- US Patent Application 10/498501; 20050087491
Facilitated transport of CO2 through polyethylenimine/poly(vinyl alcohol) blend membrane
journal, November 1999
- Matsuyama, Hideto; Terada, Akihiro; Nakagawara, Tadashi
- Journal of Membrane Science, Vol. 163, Issue 2
Fabrication of dual-layer polyethersulfone (PES) hollow fiber membranes with an ultrathin dense-selective layer for gas separation
journal, December 2004
- Li, Yi; Cao, Chun; Chung, Tai-Shung
- Journal of Membrane Science, Vol. 245, Issue 1-2
Ceramic Membrane Based on a Substrate Containing Polymer or Natural Fibres, Method for the Production and Use Thereof
patent-application, March 2005
- Hennige, Volker; Hying, Christsian; Horpel, Gerhard
- US Patent Application 10/501713; 20050070193
Multiwalled carbon nanotube mixed matrix membranes containing amines for high pressure CO2/H2 separation
journal, June 2014
- Zhao, Yanan; Jung, Benson T.; Ansaloni, Luca
- Journal of Membrane Science, Vol. 459
An empirical correlation of gas permeability and permselectivity in polymers and its theoretical basis
journal, September 2009
- Robeson, L. M.; Freeman, B. D.; Paul, D. R.
- Journal of Membrane Science, Vol. 341, Issue 1-2
Selective separation of CO2 by using novel facilitated transport membrane at elevated temperatures and pressures
journal, March 2007
- Yegani, R.; Hirozawa, H.; Teramoto, M.
- Journal of Membrane Science, Vol. 291, Issue 1-2, p. 157-164
Novel fixed-site-carrier polyvinylamine membrane for carbon dioxide capture: PVAm Membrane for CO
journal, October 2004
- Kim, Taek-Joong; Li, Baoan; Hägg, May-Britt
- Journal of Polymer Science Part B: Polymer Physics, Vol. 42, Issue 23
Absorption of carbon dioxide through hollow fiber membranes using various aqueous absorbents
journal, November 2000
- Kim, Young-Seok; Yang, Seung-Man
- Separation and Purification Technology, Vol. 21, Issue 1-2
Membranes comprising salts of aminoacids in hydrophilic polymers
patent, March 1997
- Ho, W. S. Winston
- US Patent Document 5,611,843
CO2-selective polymeric membranes containing amines in crosslinked poly(vinyl alcohol)
journal, December 2006
- Zou, Jian; Ho, W. S. Winston
- Journal of Membrane Science, Vol. 286, Issue 1-2, p. 310-321
Sterically-Hindered Amines for Acid-Gas Absorption
journal, January 1987
- Sartori, G.; Ho, W. S.; Savage, D. W.
- Separation and Purification Methods, Vol. 16, Issue 2