Stable bromine charge storage in porous carbon electrodes using tetraalkylammonium bromides for reversible solid complexation
Abstract
Electrolytes for use in electric double-layer capacitors (EDLCs; often referred as supercapacitors or ultracapacitors) are disclosed. In one example, the electrolyte comprises viologen in both the anolyte and the catholyte (with bromide). In another example, the electrolyte comprises viologen (in the anolyte) and tetraalkylammonium with bromide (in the catholyte), wherein the tetraalkylammonium is used to achieve solid complexation of bromine in the activated carbon of the cathode. In a third example, a zinc bromine/tetraalkylammonium supercapacitor/battery hybrid is disclosed. Also disclosed is a corrosion resistant bipolar pouch cell that can be used with the electrolyte embodiments described herein.
- Inventors:
- Issue Date:
- Research Org.:
- Univ. of California, Oakland, CA (United States); Oregon State Univ., Corvallis, OR (United States); Univ. of Oregon, Eugene, OR (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1735248
- Patent Number(s):
- 10770699
- Application Number:
- 15/601,811
- Assignee:
- The Regents of the University of California (Oakland, CA); Oregon State University (Corvallis, OR); University of Oregon (Eugene, OR)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08K - Use of inorganic or non-macromolecular organic substances as compounding ingredients
- DOE Contract Number:
- AR0000344
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 05/22/2017
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Stucky, Galen D., Evanko, Brian, Yoo, Seung-Joon, Lipton, Jason, Boettcher, Shannon W., Ji, David Xiulei, and Wang, Xingfeng. Stable bromine charge storage in porous carbon electrodes using tetraalkylammonium bromides for reversible solid complexation. United States: N. p., 2020.
Web.
Stucky, Galen D., Evanko, Brian, Yoo, Seung-Joon, Lipton, Jason, Boettcher, Shannon W., Ji, David Xiulei, & Wang, Xingfeng. Stable bromine charge storage in porous carbon electrodes using tetraalkylammonium bromides for reversible solid complexation. United States.
Stucky, Galen D., Evanko, Brian, Yoo, Seung-Joon, Lipton, Jason, Boettcher, Shannon W., Ji, David Xiulei, and Wang, Xingfeng. Tue .
"Stable bromine charge storage in porous carbon electrodes using tetraalkylammonium bromides for reversible solid complexation". United States. https://www.osti.gov/servlets/purl/1735248.
@article{osti_1735248,
title = {Stable bromine charge storage in porous carbon electrodes using tetraalkylammonium bromides for reversible solid complexation},
author = {Stucky, Galen D. and Evanko, Brian and Yoo, Seung-Joon and Lipton, Jason and Boettcher, Shannon W. and Ji, David Xiulei and Wang, Xingfeng},
abstractNote = {Electrolytes for use in electric double-layer capacitors (EDLCs; often referred as supercapacitors or ultracapacitors) are disclosed. In one example, the electrolyte comprises viologen in both the anolyte and the catholyte (with bromide). In another example, the electrolyte comprises viologen (in the anolyte) and tetraalkylammonium with bromide (in the catholyte), wherein the tetraalkylammonium is used to achieve solid complexation of bromine in the activated carbon of the cathode. In a third example, a zinc bromine/tetraalkylammonium supercapacitor/battery hybrid is disclosed. Also disclosed is a corrosion resistant bipolar pouch cell that can be used with the electrolyte embodiments described herein.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {9}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Material for polarizable electrode
patent, January 1992
- Tsuzuki, Yasushi; Tanaka, Toshio; Iizuka, Yasuhiro
- US Patent Document 5,082,594
Electric Double-Layer Capacitor
patent-application, May 2011
- Watenabe, Hiroyuki; Horikoshi, Ron
- US Patent Application 12/674515; 20110116211
High performance carbon nano-tube composites for electrochemical energy storage devices
patent-application, November 2011
- Lu, Wen; Buettner-Garrett, Joshua; Krysiak, Michael
- US Patent Application 13/113971; 20110287316
Power Efficient Flow Through Capacitor System
patent-application, July 2007
- Andelman, Marc D.; Kuran, Shihab; Zulkiewicz, Jon
- US Patent Application 10/567415; 20070158185
High energy capacitors boosted by both catholyte and anolyte
patent, November 2015
- Stucky, Galen D.; Ji, Xiulei
- US Patent Document 9,196,425
High Energy Capacitors Boosted by both Catholyte and Anolyte
patent-application, May 2015
- Stucky, Galen; Ji, Xiulei
- US Patent Application 14/102164; 20150062777
Electrode and battery
patent-application, November 2014
- Ho, Bryan; Ng, Bryan
- US Patent Application 14/333390; 20140329126
Graphite/DSA assembled electrode for redox flow battery, method of manufacturing the same and redox flow battery including the same
patent, August 2013
- Kim, Hyung Sun; Cho, Byung Won; Kim, Young Jun
- US Patent Document 8,518,572
Package Containing Roll of Long Electrode Plate
patent-application, March 2005
- Goishihara, Satoshi
- US Patent Application 10/899973; 2005/0058889