Nanostructured composite metal hydrides

Christensen, Steven Thomas; Gennett, Thomas; Marius, Noemie; Gross, Karl Joseph

Title: Nanostructured composite metal hydrides

Abstract

The present disclosure relates to a composition that includes a solid core having an outer surface and a coating layer, where the coating layer covers at least a portion of the outer surface, the coating layer is permeable to hydrogen (H₂), and the solid core is capable of reversibly absorbing and desorbing hydrogen.

Inventors:: Christensen, Steven Thomas; Gennett, Thomas; Marius, Noemie; Gross, Karl Joseph

Issue Date:: 2020-08-25

Research Org.:: National Renewable Energy Lab. (NREL), Golden, CO (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1735177

Patent Number(s):: 10751795

Application Number:: 15/982,232

Assignee:: Alliance for Sustainable Energy, LLC (Golden, CO)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B22 - CASTING B22F - WORKING METALLIC POWDER

C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL

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B - PERFORMING OPERATIONS B22 - CASTING B22F - WORKING METALLIC POWDER
B22F1/02 - comprising coating of the powder {
B22F2304/054 - Particle size between 1 and 100 nm

C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
C23C16/45555 - {applied in non-semiconductor technology}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B3/0078 - {Composite solid storage mediums, i.e. coherent or loose mixtures of different solid constituents, chemically or structurally heterogeneous solid masses, coated solids or solids having a chemically modified surface region}

B - PERFORMING OPERATIONS B22 - CASTING B22F - WORKING METALLIC POWDER
B22F2301/25 - Noble metals, i.e. Ag Au, Ir, Os, Pd, Pt, Rh, Ru
B22F2302/253 - Aluminum oxide

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/32 - Hydrogen storage

B - PERFORMING OPERATIONS B22 - CASTING B22F - WORKING METALLIC POWDER
B22F1/0048 - {Spherical powder}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B3/0031 - {Intermetallic compounds

B - PERFORMING OPERATIONS B22 - CASTING B22F - WORKING METALLIC POWDER
B22F1/0025 - {Nanofibres or nanotubes}
B22F2303/20 - Coating by means of particles

C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
C23C16/403 - {of aluminium, magnesium or beryllium}
C23C16/405 - {of refractory metals or yttrium}

B - PERFORMING OPERATIONS B22 - CASTING B22F - WORKING METALLIC POWDER
B22F2304/058 - Particle size above 300 nm up to 1 micrometer

C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
C23C16/45525 - {Atomic layer deposition [ALD]}
C23C16/4417 - {Methods specially adapted for coating powder}

B - PERFORMING OPERATIONS B22 - CASTING B22F - WORKING METALLIC POWDER
B22F2301/10 - Copper

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B3/0068 - {the other metal being nickel}

B - PERFORMING OPERATIONS B22 - CASTING B22F - WORKING METALLIC POWDER
B22F2304/10 - Micron size particles, i.e. above 1 micrometer up to 500 micrometer
B22F1/0018 - {Nanometer sized particles}
B22F2302/256 - Silicium oxide

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B3/0026 - {of one single metal or a rare earth metal

B - PERFORMING OPERATIONS B22 - CASTING B22F - WORKING METALLIC POWDER
B22F2302/40 - Carbon, graphite

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DOE Contract Number:: AC36-08GO28308

Resource Type:: Patent

Resource Relation:: Patent File Date: 05/17/2018

Country of Publication:: United States

Language:: English

Citation Formats


                    Christensen, Steven Thomas, Gennett, Thomas, Marius, Noemie, and Gross, Karl Joseph. Nanostructured composite metal hydrides.  United States: N. p., 2020. 
        Web.

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                    Christensen, Steven Thomas, Gennett, Thomas, Marius, Noemie, & Gross, Karl Joseph. Nanostructured composite metal hydrides.  United States.

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                    Christensen, Steven Thomas, Gennett, Thomas, Marius, Noemie, and Gross, Karl Joseph. Tue .  
        "Nanostructured composite metal hydrides".  United States.  https://www.osti.gov/servlets/purl/1735177.

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@article{osti_1735177,

  title        = {Nanostructured composite metal hydrides},

  author       = {Christensen, Steven Thomas and Gennett, Thomas and Marius, Noemie and Gross, Karl Joseph},

  abstractNote = {The present disclosure relates to a composition that includes a solid core having an outer surface and a coating layer, where the coating layer covers at least a portion of the outer surface, the coating layer is permeable to hydrogen (H2), and the solid core is capable of reversibly absorbing and desorbing hydrogen.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {8}

}

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Similar Records

Title: Nanostructured composite metal hydrides

Abstract

Citation Formats

Alumina coated nickel nanoparticles as a highly active catalyst for dry reforming of methane journal, December 2015

Ammonia as a possible element in an energy infrastructure: catalysts for ammonia decomposition journal, January 2012

Porous Alumina Protective Coatings on Palladium Nanoparticles by Self-Poisoned Atomic Layer Deposition journal, May 2012

Enhancing the stability of copper chromite catalysts for the selective hydrogenation of furfural with ALD overcoating (II) – Comparison between TiO2 and Al2O3 overcoatings journal, June 2015

Uncovering the intrinsic size dependence of hydriding phase transformations in nanocrystals journal, August 2013

Recent Advances in Atomic Layer Deposition journal, March 2016

Synthesis of Nanosized Gold−Silica Core−Shell Particles journal, January 1996

First-Principles Predictions and in Situ Experimental Validation of Alumina Atomic Layer Deposition on Metal Surfaces journal, November 2014

Improved Thermal Stability and Methane-Oxidation Activity of Pd/Al 2 O 3 Catalysts by Atomic Layer Deposition of ZrO 2 journal, August 2015

Chemical bridges for enhancing hydrogen storage by spillover and methods for forming the same patent, December 2012

Atomic layer deposition of perovskite oxides and their epitaxial integration with Si, Ge, and other semiconductors journal, December 2015

Atomic Layer Deposition of Metal Sulfide Materials journal, January 2015

Nanoengineering of Inorganic and Hybrid Hollow Spheres by Colloidal Templating journal, November 1998

Enhancing catalytic activity of nanoporous materials patent, March 2014

Hybrid nanomaterials through molecular and atomic layer deposition: Top down, bottom up, and in-between approaches to new materials journal, January 2016

Heterogeneous Catalyst Deactivation and Regeneration: A Review journal, February 2015

Catalyst synthesis and evaluation using an integrated atomic layer deposition synthesis–catalysis testing tool journal, August 2015

Stabilization of Copper Catalysts for Liquid-Phase Reactions by Atomic Layer Deposition journal, November 2013

Stabilizing Ni Catalysts by Molecular Layer Deposition for Harsh, Dry Reforming Conditions journal, July 2014

Air-stable magnesium nanocomposites provide rapid and high-capacity hydrogen storage without using heavy-metal catalysts journal, March 2011

Atomic Layer Deposition Overcoating: Tuning Catalyst Selectivity for Biomass Conversion journal, September 2014

Surface Chemistry of Trimethylaluminum on Pd(111) and Pt(111) journal, August 2015

Improving Heterogeneous Catalyst Stability for Liquid-phase Biomass Conversion and Reforming journal, October 2015

Stabilization of Supported Metal Nanoparticles Using an Ultrathin Porous Shell journal, August 2011

Catalyst Design with Atomic Layer Deposition journal, February 2015

Atomic Layer Deposition of Alumina Passivation Layers in High-Aspect-Ratio Tubular Reactors for Coke Suppression during Thermal Cracking of Hydrocarbon Fuels journal, April 2015

Tuning Acid–Base Properties Using Mg–Al Oxide Atomic Layer Deposition journal, July 2015

Synthesis of Pt–Pd Core–Shell Nanostructures by Atomic Layer Deposition: Application in Propane Oxidative Dehydrogenation to Propylene journal, September 2012

Coking- and Sintering-Resistant Palladium Catalysts Achieved Through Atomic Layer Deposition journal, March 2012

Growth and Characterization of Al 2 O 3 Atomic Layer Deposition Films on sp 2 -Graphitic Carbon Substrates Using NO 2 /Trimethylaluminum Pretreatment journal, May 2015

Alumina Over-coating on Pd Nanoparticle Catalysts by Atomic Layer Deposition: Enhanced Stability and Reactivity journal, January 2011

Alumina coated nickel nanoparticles as a highly active catalyst for dry reforming of methane
journal, December 2015

Ammonia as a possible element in an energy infrastructure: catalysts for ammonia decomposition
journal, January 2012

Porous Alumina Protective Coatings on Palladium Nanoparticles by Self-Poisoned Atomic Layer Deposition
journal, May 2012

Enhancing the stability of copper chromite catalysts for the selective hydrogenation of furfural with ALD overcoating (II) – Comparison between TiO2 and Al2O3 overcoatings
journal, June 2015

Uncovering the intrinsic size dependence of hydriding phase transformations in nanocrystals
journal, August 2013

Recent Advances in Atomic Layer Deposition
journal, March 2016

Synthesis of Nanosized Gold−Silica Core−Shell Particles
journal, January 1996

First-Principles Predictions and in Situ Experimental Validation of Alumina Atomic Layer Deposition on Metal Surfaces
journal, November 2014

Improved Thermal Stability and Methane-Oxidation Activity of Pd/Al ₂ O ₃ Catalysts by Atomic Layer Deposition of ZrO ₂
journal, August 2015

Chemical bridges for enhancing hydrogen storage by spillover and methods for forming the same
patent, December 2012

Atomic layer deposition of perovskite oxides and their epitaxial integration with Si, Ge, and other semiconductors
journal, December 2015

Atomic Layer Deposition of Metal Sulfide Materials
journal, January 2015

Nanoengineering of Inorganic and Hybrid Hollow Spheres by Colloidal Templating
journal, November 1998

Enhancing catalytic activity of nanoporous materials
patent, March 2014

Hybrid nanomaterials through molecular and atomic layer deposition: Top down, bottom up, and in-between approaches to new materials
journal, January 2016

Heterogeneous Catalyst Deactivation and Regeneration: A Review
journal, February 2015

Catalyst synthesis and evaluation using an integrated atomic layer deposition synthesis–catalysis testing tool
journal, August 2015

Stabilization of Copper Catalysts for Liquid-Phase Reactions by Atomic Layer Deposition
journal, November 2013

Stabilizing Ni Catalysts by Molecular Layer Deposition for Harsh, Dry Reforming Conditions
journal, July 2014

Air-stable magnesium nanocomposites provide rapid and high-capacity hydrogen storage without using heavy-metal catalysts
journal, March 2011

Atomic Layer Deposition Overcoating: Tuning Catalyst Selectivity for Biomass Conversion
journal, September 2014

Surface Chemistry of Trimethylaluminum on Pd(111) and Pt(111)
journal, August 2015

Improving Heterogeneous Catalyst Stability for Liquid-phase Biomass Conversion and Reforming
journal, October 2015

Stabilization of Supported Metal Nanoparticles Using an Ultrathin Porous Shell
journal, August 2011

Catalyst Design with Atomic Layer Deposition
journal, February 2015

Atomic Layer Deposition of Alumina Passivation Layers in High-Aspect-Ratio Tubular Reactors for Coke Suppression during Thermal Cracking of Hydrocarbon Fuels
journal, April 2015

Tuning Acid–Base Properties Using Mg–Al Oxide Atomic Layer Deposition
journal, July 2015

Synthesis of Pt–Pd Core–Shell Nanostructures by Atomic Layer Deposition: Application in Propane Oxidative Dehydrogenation to Propylene
journal, September 2012

Coking- and Sintering-Resistant Palladium Catalysts Achieved Through Atomic Layer Deposition
journal, March 2012

Growth and Characterization of Al ₂ O ₃ Atomic Layer Deposition Films on sp ² -Graphitic Carbon Substrates Using NO ₂ /Trimethylaluminum Pretreatment
journal, May 2015

Alumina Over-coating on Pd Nanoparticle Catalysts by Atomic Layer Deposition: Enhanced Stability and Reactivity
journal, January 2011