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Title: Graphene-coated metal oxide spinel cathodes

Abstract

Disclosed herein are graphene-coated lithium manganese oxide spinels cathodes for high-performance batteries Li-ion batteries and methods for making thereof. A single-layer graphene coating is shown to significantly reduce manganese loss in the cathodes while concurrently promoting the formation of a well-defined solid electrolyte interphase layer.

Inventors:
; ; ;
Issue Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1735169
Patent Number(s):
10749170
Application Number:
15/293,909
Assignee:
Northwestern University (Evanston, IL); UChicago Argonne, LLC (Chicago, IL)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Patent
Resource Relation:
Patent File Date: 10/14/2016
Country of Publication:
United States
Language:
English

Citation Formats

Hersam, Mark C., Jaber Ansari, Laila, Puntambekar, Kanan P., and Thackeray, Michael M. Graphene-coated metal oxide spinel cathodes. United States: N. p., 2020. Web.
Hersam, Mark C., Jaber Ansari, Laila, Puntambekar, Kanan P., & Thackeray, Michael M. Graphene-coated metal oxide spinel cathodes. United States.
Hersam, Mark C., Jaber Ansari, Laila, Puntambekar, Kanan P., and Thackeray, Michael M. Tue . "Graphene-coated metal oxide spinel cathodes". United States. https://www.osti.gov/servlets/purl/1735169.
@article{osti_1735169,
title = {Graphene-coated metal oxide spinel cathodes},
author = {Hersam, Mark C. and Jaber Ansari, Laila and Puntambekar, Kanan P. and Thackeray, Michael M.},
abstractNote = {Disclosed herein are graphene-coated lithium manganese oxide spinels cathodes for high-performance batteries Li-ion batteries and methods for making thereof. A single-layer graphene coating is shown to significantly reduce manganese loss in the cathodes while concurrently promoting the formation of a well-defined solid electrolyte interphase layer.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {8}
}

Works referenced in this record:

Reversible anionic redox chemistry in high-capacity layered-oxide electrodes
journal, July 2013


Generalized Gradient Approximation Made Simple
journal, October 1996


A manganese oxyiodide cathode for rechargeable lithium batteries
journal, November 1997


Spinel Electrodes from the Li-Mn-O System for Rechargeable Lithium Battery Applications
journal, January 1992


Jahn–Teller distortion and electronic structure of LiMn2O4
journal, April 2009


Suppressing Manganese Dissolution from Lithium Manganese Oxide Spinel Cathodes with Single-Layer Graphene
journal, June 2015


Graphene-Sandwiched LiNi 0.5 Mn 1.5 O 4 Cathode Composites for Enhanced High Voltage Performance in Li Ion Batteries
journal, January 2013


Self-assembled lithium manganese oxide nanoparticles on carbon nanotube or graphene as high-performance cathode material for lithium-ion batteries
journal, January 2011


Preparation and characterization of lithium manganese oxide cubic spinel Li1.03Mn1.97O4 doped with Mg and Fe
journal, January 2010


Improved capacity retention in rechargeable 4 V lithium/lithium-manganese oxide (spinel) cells
journal, April 1994


Mn(II) deposition on anodes and its effects on capacity fade in spinel lithium manganate–carbon systems
journal, September 2013


Surface structure and equilibrium particle shape of the LiMn 2 O 4 spinel from first-principles calculations
journal, February 2013


Issues and challenges facing rechargeable lithium batteries
journal, November 2001


Graphene-modified LiFePO4 cathode for lithium ion battery beyond theoretical capacity
journal, April 2013


Spinel LiMn2O4/reduced graphene oxide hybrid for high rate lithium ion batteries
journal, January 2011


Enhanced cycling stability of spinel LiMn2O4 cathode by incorporating graphene sheets
journal, February 2015


LiMn2O4 nanoparticles anchored on graphene nanosheets as high-performance cathode material for lithium-ion batteries
journal, January 2014


Methane bond activation by Pt and Pd subnanometer clusters supported on graphene and carbon nanotubes
journal, May 2012


Electrochemical extraction of lithium from LiMn2O4
journal, February 1984


Improving Graphene Diffusion Barriers via Stacking Multiple Layers and Grain Size Engineering
journal, February 2013


Prediction of Quaternary Spinel Oxides as Li-Battery Cathodes: Cation Site Preference, Metal Mixing, Voltage and Phase Stability
journal, January 2014


Defect Evolution in Graphene upon Electrochemical Lithiation
journal, October 2014


ZrO2- and Li2ZrO3-stabilized spinel and layered electrodes for lithium batteries
journal, September 2003


Enhanced cycleability of LiMn2O4 cathodes by atomic layer deposition of nanosized-thin Al2O3 coatings
journal, January 2011


Improved tetrahedron method for Brillouin-zone integrations
journal, June 1994


Transfer of CVD-Grown Monolayer Graphene onto Arbitrary Substrates
journal, August 2011


Improved electrochemical performance of spinel LiMn 2 O 4 in situ coated with graphene-like membrane
journal, February 2014


Building better batteries
journal, February 2008


Special points for Brillouin-zone integrations
journal, June 1976


Lithium extraction from orthorhombic lithium manganese oxide and the phase transformation to spinel
journal, December 1993


Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study
journal, January 1998


A new one-pot hydrothermal synthesis and electrochemical characterization of Li1+xMn2−yO4 spinel structured compounds
journal, January 2010


Graphene in lithium ion battery cathode materials: A review
journal, October 2013


Effect of SEI on Capacity Losses of Spinel Lithium Manganese Oxide/Graphite Batteries Stored at 60°C
journal, January 2010


Oxidation state of cross-over manganese species on the graphite electrode of lithium-ion cells
journal, January 2014


Revisiting LiClO[sub 4] as an Electrolyte for Rechargeable Lithium-Ion Batteries
journal, January 2010


Oxidation States of Mn Atoms at Clean and Al 2 O 3 -Covered LiMn 2 O 4 (001) Surfaces
journal, March 2010


Electrochemical performance of the graphene/Y2O3/LiMn2O4 hybrid as cathode for lithium-ion battery
journal, January 2014


Using graphene nanosheets as a conductive additive to enhance the rate performance of spinel LiMn2O4 cathode material
journal, January 2013


Impermeable Atomic Membranes from Graphene Sheets
journal, August 2008


Density‐functional thermochemistry. III. The role of exact exchange
journal, April 1993


Doubling the Capacity of Lithium Manganese Oxide Spinel by a Flexible Skinny Graphitic Layer
journal, April 2014


In Situ X-ray Study of the Solid Electrolyte Interphase (SEI) Formation on Graphene as a Model Li-ion Battery Anode
journal, August 2012


Raman Microspectrometry Applied to the Study of Electrode Materials for Lithium Batteries
journal, March 2010


Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils
journal, May 2009


Graphene/LiMn2O4 nanocomposites for enhanced lithium ion batteries with high rate capability
journal, September 2015


Manganese oxides for lithium batteries
journal, January 1997


Ab initiomolecular dynamics for liquid metals
journal, January 1993


Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density
journal, January 1988


Generalized Gradient Approximation Made Simple [Phys. Rev. Lett. 77, 3865 (1996)]
journal, February 1997


From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999


Formation of Perpendicular Graphene Nanosheets on LiFePO 4 : A First-Principles Characterization
journal, August 2012


Raman spectroscopy as a versatile tool for studying the properties of graphene
journal, April 2013


Pressure dependence of magnetic transition temperature in Li[Li x Mn 2−x ]O 4 (0 ≤ x ≤ 1/3) studied by muon-spin rotation and relaxation
journal, February 2013


Enhancement of Thermal Stability of LiCoO[sub 2] by LiMn[sub 2]O[sub 4] Coating
journal, January 1999


A Truncated Manganese Spinel Cathode for Excellent Power and Lifetime in Lithium-Ion Batteries
journal, February 2012


Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996


Structural stability of LiMn2O4 electrodes for lithium batteries
journal, September 1997


Simulation of the surface structure of lithium manganese oxide spinel
journal, May 2011