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Title: Polymer composites for fused filament fabrication and methods of making the same

Abstract

Disclosed are compositions of a fused filament fabrication (FFF) composite filament having embedded functional materials in a thermoplastic matrix. Methods of making the composite filaments are also disclosed. In one example, a FFF composite filament incorporates a MOF, in an amount greater than 10% by mass, dispersed in a matrix polymer. One example of a method of synthesizing FFF composite filaments involves mixing a suspension that has a MOF with a matrix polymer solution to yield a polymer-MOF mixture. The mixture is cast and dried into a solid composite material, which is formed a FFF composite filament having the MOF in an amount greater than 10% by mass.

Inventors:
; ; ; ; ;
Issue Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1735150
Patent Number(s):
10744695
Application Number:
15/874,062
Assignee:
Battelle Memorial Institute (Richland, WA)
Patent Classifications (CPCs):
D - TEXTILES D01 - NATURAL OR MAN-MADE THREADS OR FIBRES D01F - CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
B - PERFORMING OPERATIONS B29 - WORKING OF PLASTICS B29C - SHAPING OR JOINING OF PLASTICS
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Patent
Resource Relation:
Patent File Date: 01/18/2018
Country of Publication:
United States
Language:
English

Citation Formats

Erikson, Rebecca L., Christ, Josef F., Kennedy, Zachary C., Evans, Kent A., Barrett, Christopher A., and Nune, Satish Kumar. Polymer composites for fused filament fabrication and methods of making the same. United States: N. p., 2020. Web.
Erikson, Rebecca L., Christ, Josef F., Kennedy, Zachary C., Evans, Kent A., Barrett, Christopher A., & Nune, Satish Kumar. Polymer composites for fused filament fabrication and methods of making the same. United States.
Erikson, Rebecca L., Christ, Josef F., Kennedy, Zachary C., Evans, Kent A., Barrett, Christopher A., and Nune, Satish Kumar. Tue . "Polymer composites for fused filament fabrication and methods of making the same". United States. https://www.osti.gov/servlets/purl/1735150.
@article{osti_1735150,
title = {Polymer composites for fused filament fabrication and methods of making the same},
author = {Erikson, Rebecca L. and Christ, Josef F. and Kennedy, Zachary C. and Evans, Kent A. and Barrett, Christopher A. and Nune, Satish Kumar},
abstractNote = {Disclosed are compositions of a fused filament fabrication (FFF) composite filament having embedded functional materials in a thermoplastic matrix. Methods of making the composite filaments are also disclosed. In one example, a FFF composite filament incorporates a MOF, in an amount greater than 10% by mass, dispersed in a matrix polymer. One example of a method of synthesizing FFF composite filaments involves mixing a suspension that has a MOF with a matrix polymer solution to yield a polymer-MOF mixture. The mixture is cast and dried into a solid composite material, which is formed a FFF composite filament having the MOF in an amount greater than 10% by mass.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {8}
}

Works referenced in this record:

3D-Printed Metal–Organic Framework Monoliths for Gas Adsorption Processes
journal, October 2017


Toward 3D printed hydrogen storage materials made with ABS-MOF composites
journal, October 2017


3D-Printed Zeolite Monoliths for CO 2 Removal from Enclosed Environments
journal, October 2016


High MOF loading in mixed-matrix membranes utilizing styrene/butadiene copolymers
journal, January 2016