Surface treatment for lithium battery electrode materials

Croy, Jason R.; Gutierrez, Arturo; Thackeray, Michael M.; He, Meinan

Title: Surface treatment for lithium battery electrode materials

Abstract

Electrode materials for electrochemical cells and batteries and methods of producing such materials are disclosed herein. A method of preparing an active lithium metal oxide material suitable for use in an electrode for a lithium electrochemical cell comprises the steps of: (a) contacting the lithium metal oxide material with an aqueous acidic solution containing one or more metal cations; and (b) heating the so-contacted lithium metal oxide from step (a) to dryness at a temperature below 200° C. The metal cations in the aqueous acidic solution comprise one or more metal cations selected from the group consisting of an alkaline earth metal ion, a transition metal ion, and a main group metal ion.

Inventors:: Croy, Jason R.; Gutierrez, Arturo; Thackeray, Michael M.; He, Meinan

Issue Date:: 2020-08-11

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1735144

Patent Number(s):: 10741839

Application Number:: 15/909,691

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G45/1257 - {containing lithium, e.g. Li2MnO3, Li2[MxMn1-xO3}
C01G53/50 - {of the type [MnO2]n- , e.g. Li

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2002/22 - layered hydroxide-type, e.g. of the hydrotalcite-type
C01P2002/32 - spinel-type
C01P2002/85 - by XPS, EDX or EDAX data
C01P2004/82 - two phases having the same anion, e.g. both oxidic phases
C01P2006/40 - Electric properties

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M10/0567 - characterised by the additives
H01M10/0568 - characterised by the solutes
H01M2004/028 - {Positive electrodes}
H01M2300/0025 - Organic electrolyte
H01M4/505 - of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M4/525 - of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 03/01/2018

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Croy, Jason R., Gutierrez, Arturo, Thackeray, Michael M., and He, Meinan. Surface treatment for lithium battery electrode materials.  United States: N. p., 2020. 
        Web.

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                    Croy, Jason R., Gutierrez, Arturo, Thackeray, Michael M., & He, Meinan. Surface treatment for lithium battery electrode materials.  United States.

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                    Croy, Jason R., Gutierrez, Arturo, Thackeray, Michael M., and He, Meinan. Tue .  
        "Surface treatment for lithium battery electrode materials".  United States.  https://www.osti.gov/servlets/purl/1735144.

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@article{osti_1735144,

  title        = {Surface treatment for lithium battery electrode materials},

  author       = {Croy, Jason R. and Gutierrez, Arturo and Thackeray, Michael M. and He, Meinan},

  abstractNote = {Electrode materials for electrochemical cells and batteries and methods of producing such materials are disclosed herein. A method of preparing an active lithium metal oxide material suitable for use in an electrode for a lithium electrochemical cell comprises the steps of: (a) contacting the lithium metal oxide material with an aqueous acidic solution containing one or more metal cations; and (b) heating the so-contacted lithium metal oxide from step (a) to dryness at a temperature below 200° C. The metal cations in the aqueous acidic solution comprise one or more metal cations selected from the group consisting of an alkaline earth metal ion, a transition metal ion, and a main group metal ion.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {8}

}

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Similar Records

Title: Surface treatment for lithium battery electrode materials

Abstract

Citation Formats

Optimization of Insertion Compounds Such as LiMn2O4 for Li-Ion Batteries journal, November 2002

Advances in Stabilizing ‘Layered-Layered’ xLi2MnO3·(1-x)LiMO2(M=Mn, Ni, Co) Electrodes with a Spinel Component journal, January 2014

Method for preparing positive active material for rechargeable lithium battery and positive active material prepared by same patent, February 2008

Methods for producing lithium metal oxide particles patent, November 2002

Surface and Bulk Modified High Capacity Layered Oxide Cathodes with Low Irreversible Capacity Loss patent-application, September 2009

Lithium manganese oxide compound patent, October 1992

Surface/chemically modified oxide cathodes for lithium-ion batteries patent-application, June 2003

Lithium metal oxide electrodes for lithium cells and batteries patent, January 2004

Positive electrode active material for lithium battery, method for producing the same, and lithium battery containing the same patent, November 1999

Improved capacity retention in rechargeable 4 V lithium/lithium-manganese oxide (spinel) cells journal, April 1994

Lithium metal oxide electrodes for lithium cells and batteries patent, December 2008

Ordering in Lix(Ni0.5Mn0.5)O2 and its relation to charge capacity and electrochemical behavior in rechargeable lithium batteries journal, October 2004

Prospects for spinel-stabilized, high-capacity lithium-ion battery cathodes journal, December 2016

Superior Capacity Retention Spinel Oxyfluoride Cathodes for Lithium-Ion Batteries journal, March 2006

Positive Electrode Passivation by LiDFOB Electrolyte Additive in High-Capacity Lithium-Ion Cells journal, January 2012

Anomalous capacity and cycling stability of xLi2MnO3·(1−x)LiMO2 electrodes (M=Mn, Ni, Co) in lithium batteries at 50°C journal, April 2007

Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries journal, March 2005

Electrochemical cell patent, May 1994

Effect of electrolyte composition on initial cycling and impedance characteristics of lithium-ion cells journal, May 2008

High-energy and high-power Li-rich nickel manganese oxide electrode materials journal, November 2010

Thin Film Battery Comprising Stacked Battery Cells and Methods patent-application, May 2009

Lithium metal oxide electrodes for lithium batteries patent, January 2008

The significance of the Li2MnO3 component in ‘composite’ xLi2MnO3·(1−x)LiMn0.5Ni0.5O2 electrodes journal, October 2004

Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries journal, January 2007

Assembled Battery and Battery System patent-application, August 2010

Electrode structures and surfaces for Li batteries patent, March 2017

Lithium–manganese oxide electrodes with layered–spinel composite structures xLi2MnO3·(1−x)Li1+yMn2−yO4 (0<x<1, 0⩽y⩽0.33) for lithium batteries journal, May 2005

Lithium metal oxide electrodes for lithium cells and batteries patent, January 2004

Conductive Lithium Storage Electrode patent-application, January 2004

Electrochemical and Structural Properties of xLi2M‘O3 ·(1− x )LiMn0.5Ni0.5O2 Electrodes for Lithium Batteries (M‘ = Ti, Mn, Zr; 0 ≤ x ⩽ 0.3) journal, May 2004

Positive Electrode Materials for Lithium Ion Batteries Having a Specific Discharge Capacity and Processes for the Synthesis of These Materials patent-application, April 2010

The Electrochemical Stability of Spinel Electrodes Coated with ZrO2, Al2O3, and SiO2 from Colloidal Suspensions journal, January 2004

Optimization of Insertion Compounds Such as LiMn₂O₄ for Li-Ion Batteries
journal, November 2002

Advances in Stabilizing ‘Layered-Layered’ xLi₂MnO₃·(1-x)LiMO₂(M=Mn, Ni, Co) Electrodes with a Spinel Component
journal, January 2014

Method for preparing positive active material for rechargeable lithium battery and positive active material prepared by same
patent, February 2008

Methods for producing lithium metal oxide particles
patent, November 2002

Surface and Bulk Modified High Capacity Layered Oxide Cathodes with Low Irreversible Capacity Loss
patent-application, September 2009

Lithium manganese oxide compound
patent, October 1992

Surface/chemically modified oxide cathodes for lithium-ion batteries
patent-application, June 2003

Lithium metal oxide electrodes for lithium cells and batteries
patent, January 2004

Positive electrode active material for lithium battery, method for producing the same, and lithium battery containing the same
patent, November 1999

Improved capacity retention in rechargeable 4 V lithium/lithium-manganese oxide (spinel) cells
journal, April 1994

Lithium metal oxide electrodes for lithium cells and batteries
patent, December 2008

Ordering in Li_x(Ni_0.5Mn_0.5)O₂ and its relation to charge capacity and electrochemical behavior in rechargeable lithium batteries
journal, October 2004

Prospects for spinel-stabilized, high-capacity lithium-ion battery cathodes
journal, December 2016

Superior Capacity Retention Spinel Oxyfluoride Cathodes for Lithium-Ion Batteries
journal, March 2006

Positive Electrode Passivation by LiDFOB Electrolyte Additive in High-Capacity Lithium-Ion Cells
journal, January 2012

Anomalous capacity and cycling stability of xLi₂MnO₃·(1−x)LiMO₂ electrodes (M=Mn, Ni, Co) in lithium batteries at 50°C
journal, April 2007

Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries
journal, March 2005

Electrochemical cell
patent, May 1994

Effect of electrolyte composition on initial cycling and impedance characteristics of lithium-ion cells
journal, May 2008

High-energy and high-power Li-rich nickel manganese oxide electrode materials
journal, November 2010

Thin Film Battery Comprising Stacked Battery Cells and Methods
patent-application, May 2009

Lithium metal oxide electrodes for lithium batteries
patent, January 2008

The significance of the Li₂MnO₃ component in ‘composite’ xLi₂MnO₃·(1−x)LiMn_0.5Ni_0.5O₂ electrodes
journal, October 2004

Li₂MnO₃-stabilized LiMO₂ (M = Mn, Ni, Co) electrodes for lithium-ion batteries
journal, January 2007

Assembled Battery and Battery System
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Electrode structures and surfaces for Li batteries
patent, March 2017

Lithium–manganese oxide electrodes with layered–spinel composite structures xLi₂MnO₃·(1−x)Li_1+yMn_2−yO₄ (0<x<1, 0⩽y⩽0.33) for lithium batteries
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Electrochemical and Structural Properties of xLi₂M‘O₃ ·(1− x )LiMn_0.5Ni_0.5O₂ Electrodes for Lithium Batteries (M‘ = Ti, Mn, Zr; 0 ≤ x ⩽ 0.3)
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The Electrochemical Stability of Spinel Electrodes Coated with ZrO₂, Al₂O₃, and SiO₂ from Colloidal Suspensions
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