Click-chemistry compatible structures, click-chemistry functionalized structures, and materials and methods for making the same

Campbell, Patrick; Duoss, Eric B.; Oakdale, James S.

Title: Click-chemistry compatible structures, click-chemistry functionalized structures, and materials and methods for making the same

Abstract

According to various embodiments, systems, methods, and computer program products for click-chemistry compatible structures, additive manufacturing resins for forming the same, and method of formation of such structures and resins, as well as techniques for functionalizing click-chemistry compatible structures are disclosed. The inventive structures generally include a plurality of photo polymerized molecules structurally arranged according to a three-dimensional pattern, while surfaces of the structure are functionalized with one or more click-chemistry compatible molecules each having one or more click-chemistry compatible functional groups. The structures may be formed from single- or dual-component resins, each having unique synthetic pathways. The resulting structures may be functionalized for utility in a wide range of applications by leveraging click chemistry to further functionalize the structure with organic additives also compatible with click-chemistry reaction schemes.

Inventors:: Campbell, Patrick; Duoss, Eric B.; Oakdale, James S.

Issue Date:: 2020-08-04

Research Org.:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1735110

Patent Number(s):: 10732502

Application Number:: 15/253,654

Assignee:: Lawrence Livermore National Security, LLC (Livermore, CA)

Patent Classifications (CPCs):: A - HUMAN NECESSITIES A01 - AGRICULTURE A01N - PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF

A - HUMAN NECESSITIES A61 - MEDICAL OR VETERINARY SCIENCE A61K - PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES

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A - HUMAN NECESSITIES A01 - AGRICULTURE A01N - PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF
A01N25/10 - Macromolecular compounds

A - HUMAN NECESSITIES A61 - MEDICAL OR VETERINARY SCIENCE A61K - PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
A61K47/58 - obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. poly[meth]acrylate, polyacrylamide, polystyrene, polyvinylpyrrolidone, polyvinylalcohol or polystyrene sulfonic acid resin

B - PERFORMING OPERATIONS B29 - WORKING OF PLASTICS B29C - SHAPING OR JOINING OF PLASTICS
B29C64/129 - characterised by the energy source therefor, e.g. by global irradiation combined with a mask

B - PERFORMING OPERATIONS B33 - ADDITIVE MANUFACTURING TECHNOLOGY B33Y - ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
B33Y10/00 - Processes of additive manufacturing
B33Y70/00 - Materials specially adapted for additive manufacturing
B33Y80/00 - Products made by additive manufacturing

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F2/50 - with sensitising agents
C08F2/60 - Polymerisation by the diene synthesis

C - CHEMISTRY C09 - DYES C09D - COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS
C09D5/08 - Anti-corrosive paints
C09D5/14 - Paints containing biocides, e.g. fungicides, insecticides or pesticides
C09D5/1662 - {Synthetic film-forming substance}

G - PHYSICS G03 - PHOTOGRAPHY G03F - PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES
G03F7/0037 - {Production of three-dimensional images}
G03F7/008 - Azides
G03F7/0085 - {characterised by the non-macromolecular additives}
G03F7/025 - Non-macromolecular photopolymerisable compounds having carbon-to-carbon triple bonds, e.g. acetylenic compounds
G03F7/027 - Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
G03F7/038 - Macromolecular compounds which are rendered insoluble or differentially wettable

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DOE Contract Number:: AC52-07NA27344

Resource Type:: Patent

Resource Relation:: Patent File Date: 08/31/2016

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats


                    Campbell, Patrick, Duoss, Eric B., and Oakdale, James S.. Click-chemistry compatible structures, click-chemistry functionalized structures, and materials and methods for making the same.  United States: N. p., 2020. 
        Web.

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                    Campbell, Patrick, Duoss, Eric B., & Oakdale, James S.. Click-chemistry compatible structures, click-chemistry functionalized structures, and materials and methods for making the same.  United States.

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                    Campbell, Patrick, Duoss, Eric B., and Oakdale, James S.. Tue .  
        "Click-chemistry compatible structures, click-chemistry functionalized structures, and materials and methods for making the same".  United States.  https://www.osti.gov/servlets/purl/1735110.

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@article{osti_1735110,

  title        = {Click-chemistry compatible structures, click-chemistry functionalized structures, and materials and methods for making the same},

  author       = {Campbell, Patrick and Duoss, Eric B. and Oakdale, James S.},

  abstractNote = {According to various embodiments, systems, methods, and computer program products for click-chemistry compatible structures, additive manufacturing resins for forming the same, and method of formation of such structures and resins, as well as techniques for functionalizing click-chemistry compatible structures are disclosed. The inventive structures generally include a plurality of photo polymerized molecules structurally arranged according to a three-dimensional pattern, while surfaces of the structure are functionalized with one or more click-chemistry compatible molecules each having one or more click-chemistry compatible functional groups. The structures may be formed from single- or dual-component resins, each having unique synthetic pathways. The resulting structures may be functionalized for utility in a wide range of applications by leveraging click chemistry to further functionalize the structure with organic additives also compatible with click-chemistry reaction schemes.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {8}

}

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