Nitride stabilized core/shell nanoparticles
Abstract
Nitride stabilized metal (M or Pt(M)) nanoparticles and methods for their manufacture are disclosed. In one embodiment the metal nanoparticles have a nonporous noble metal shell with a nitride-stabilized non-noble metal core. The nitride-stabilized core provides a stabilizing effect under high oxidizing conditions suppressing the noble metal dissolution during potential cycling. Introduction of nitrogen into the core by annealing produces metal nitride(s) that are less susceptible to dissolution during potential cycling under high oxidizing conditions.
- Inventors:
- Issue Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1651006
- Patent Number(s):
- 10680249
- Application Number:
- 16/271,496
- Assignee:
- Brookhaven Science Associates, LLC (Upton, NY)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AC02-98CH10886; SC0012704
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 02/08/2019
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY
Citation Formats
Kuttiyiel, Kurian Abraham, Sasaki, Kotaro, and Adzic, Radoslav R. Nitride stabilized core/shell nanoparticles. United States: N. p., 2020.
Web.
Kuttiyiel, Kurian Abraham, Sasaki, Kotaro, & Adzic, Radoslav R. Nitride stabilized core/shell nanoparticles. United States.
Kuttiyiel, Kurian Abraham, Sasaki, Kotaro, and Adzic, Radoslav R. Tue .
"Nitride stabilized core/shell nanoparticles". United States. https://www.osti.gov/servlets/purl/1651006.
@article{osti_1651006,
title = {Nitride stabilized core/shell nanoparticles},
author = {Kuttiyiel, Kurian Abraham and Sasaki, Kotaro and Adzic, Radoslav R.},
abstractNote = {Nitride stabilized metal (M or Pt(M)) nanoparticles and methods for their manufacture are disclosed. In one embodiment the metal nanoparticles have a nonporous noble metal shell with a nitride-stabilized non-noble metal core. The nitride-stabilized core provides a stabilizing effect under high oxidizing conditions suppressing the noble metal dissolution during potential cycling. Introduction of nitrogen into the core by annealing produces metal nitride(s) that are less susceptible to dissolution during potential cycling under high oxidizing conditions.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {6}
}
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