Magnetic field alignment of emulsions to produce porous articles

Li, Linsen; Sander, Jonathan Samuel; Chiang, Yet-Ming; Erb, Randall Morgan

Title: Magnetic field alignment of emulsions to produce porous articles

Abstract

The use of magnetic fields in the production of porous articles is generally described. Certain embodiments are related to methods of producing porous articles in which magnetic fields are applied to an emulsion to align emulsion droplets. In some embodiments, after the emulsion droplets have been aligned, the emulsion droplets and/or the medium surrounding the emulsion droplets can be removed to leave behind a porous article. According to certain embodiments, polyvinyl alcohol can be used, for example, to stabilize the emulsion droplets and/or bind together components of the porous article. In some embodiments, water-soluble liquid alcohol can be used, for example, to stabilize the suspension of electronically conductive material within a phase of the emulsion.

Inventors:: Li, Linsen; Sander, Jonathan Samuel; Chiang, Yet-Ming; Erb, Randall Morgan

Issue Date:: 2020-06-09

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1650983

Patent Number(s):: 10675819

Application Number:: 15/390,295

Assignee:: Massachusetts Institute of Technology (Cambridge, MA); Northeastern University (Boston, MA)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B03 - SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS B03C - MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS

B - PERFORMING OPERATIONS B29 - WORKING OF PLASTICS B29C - SHAPING OR JOINING OF PLASTICS

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B - PERFORMING OPERATIONS B03 - SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS B03C - MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS
B03C1/32 - acting on the medium containing the substance being separated, e.g. magnetogravimetric-, magnetohydrostatic-, or magnetohydrodynamic separation {

B - PERFORMING OPERATIONS B29 - WORKING OF PLASTICS B29C - SHAPING OR JOINING OF PLASTICS
B29C67/202 - {comprising elimination of a solid or a liquid ingredient}

B - PERFORMING OPERATIONS B29 - WORKING OF PLASTICS B29K - INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR {MOULDS, } REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
B29K2029/04 - {PVOH, i.e. polyvinyl alcohol
B29K2105/0064 - {Latex, emulsion or dispersion}
B29K2995/0005 - Conductive
B29K2995/0008 - Magnetic or paramagnetic

B - PERFORMING OPERATIONS B29 - WORKING OF PLASTICS B29L - INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
B29L2031/3468 - {Batteries, accumulators or fuel cells

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01F - MAGNETS
H01F1/447 - {characterised by magnetoviscosity, e.g. magnetorheological, magnetothixotropic, magnetodilatant liquids

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M2004/021 - {Physical characteristics, e.g. porosity, surface area}
H01M4/04 - Processes of manufacture in general
H01M4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M4/1391 - of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M4/505 - of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M4/525 - of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
H01M4/587 - for inserting or intercalating light metals
H01M4/623 - {fluorinated polymers}
H01M4/625 - {Carbon or graphite}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: AC02-05CH11231

Resource Type:: Patent

Resource Relation:: Patent File Date: 12/23/2016

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS

Citation Formats


                    Li, Linsen, Sander, Jonathan Samuel, Chiang, Yet-Ming, and Erb, Randall Morgan. Magnetic field alignment of emulsions to produce porous articles.  United States: N. p., 2020. 
        Web.

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                    Li, Linsen, Sander, Jonathan Samuel, Chiang, Yet-Ming, & Erb, Randall Morgan. Magnetic field alignment of emulsions to produce porous articles.  United States.

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                    Li, Linsen, Sander, Jonathan Samuel, Chiang, Yet-Ming, and Erb, Randall Morgan. Tue .  
        "Magnetic field alignment of emulsions to produce porous articles".  United States.  https://www.osti.gov/servlets/purl/1650983.

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@article{osti_1650983,

  title        = {Magnetic field alignment of emulsions to produce porous articles},

  author       = {Li, Linsen and Sander, Jonathan Samuel and Chiang, Yet-Ming and Erb, Randall Morgan},

  abstractNote = {The use of magnetic fields in the production of porous articles is generally described. Certain embodiments are related to methods of producing porous articles in which magnetic fields are applied to an emulsion to align emulsion droplets. In some embodiments, after the emulsion droplets have been aligned, the emulsion droplets and/or the medium surrounding the emulsion droplets can be removed to leave behind a porous article. According to certain embodiments, polyvinyl alcohol can be used, for example, to stabilize the emulsion droplets and/or bind together components of the porous article. In some embodiments, water-soluble liquid alcohol can be used, for example, to stabilize the suspension of electronically conductive material within a phase of the emulsion.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {6}

}

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Ion battery using high aspect ratio electrodes
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Battery electrolytic solution with fluoride-ion-dissociating salt and battery using the same
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Positive active material for rechargeable lithium batteries and method of preparing the same
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Non-crosslinked, amorphous, block copolymer electrolyte for batteries
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Current collector manufacture by arc spray deposition
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Electroactive material for secondary batteries and methods of preparation
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Rechargeable thin film battery and method for making the same
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Electrically-conducting adhesion-promoters
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Moulton, Russell D.; Golovin, Milton N.
US Patent Document 5,464,707
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Solid polymer electrolyte employing a crosslinking agent
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Nonaqueous battery having porous separator and production method thereof
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Coated metal sheet for dry cell positive electrode can and positive electrode can formed of such metal sheet
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Chiang, Yet-Ming; Chung, Sung-Yoon; Bloking, Jason T.
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Particulate electrode including electrolyte for a rechargeable lithium battery
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Dasgupta, Sankar; Jacobs, James K.; Bhola, Rakesh
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Abstract

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Electrolysis systems patent, December 1998

Electromechanical actuators patent, August 2006

Method for manufacturing thin-film lithium microbatteries
patent, July 2004

Flexible thin layer open electrochemical cell and applications of same
patent, April 1999

Carrier particles
patent, January 2003

Conducting polymer electrodes for energy storage devices and method of making same
patent, February 1998

Thin film battery and electrolyte therefor
patent, November 2004

All-solid-state electrochemical device and method of manufacturing
patent, December 2003

Cathode materials for secondary (rechargeable) lithium batteries
patent, June 1999

Phosphate powder compositions and methods for forming particles with complex anions
patent-application, December 2002

Piezoelectric actuators and method of making same
patent, May 2001

Apparatus for in situ x-ray study of electrochemical cells
patent, June 1997

Lithium secondary cell
patent, December 1996

Current collector having a conductive primer layer
patent, December 1995

Electrophoretic assembly of electrochemical devices
patent, February 2010

Powder coating compositions containing a carboxylic acid functional polyester
patent, May 2000

Non-sintered thin electrode for battery, battery using same and process for same
patent, October 2004

Method for producing anisotropic dielectric layer and devices including same
patent, April 2002

Hydrogen-absorbing alloy for battery, method of manufacturing the same, and secondary nickel-metal hydride battery
patent, August 1997

Sealed battery and method of manufacturing the same
patent, February 2001

Dry method for manufacturing hydrogen absorption alloy electrode
patent, March 1992

Current collectors for battery
patent, June 2002

Self-organizing battery structure with electrode particles that exert a repelling force on the opposite electrode
patent, June 2008

Current collector device and method of manufacturing same
patent, December 1996

Bipolar articles and related methods
patent-application, February 2005

Non-aqueous electrolyte secondary battery
patent, March 2002

Battery structures, self-organizing structures and related methods
patent-application, May 2003

Method for making laminated rechargeable battery cells
patent, November 1998

Batteries and electrodes for use thereof
patent-application, February 2009

Composite electrode for use in electrochemical cells
patent, February 1989

Novel macromolecular material for use in realizing electrolytes and/or electrodes
patent, July 1988

Current collector device
patent, November 1996

Polyether copolymer and crosslinked solid polymer electrolyte
patent, December 2000

Ion battery using high aspect ratio electrodes
patent-application, June 2002

Battery and process for preparing the same
patent-application, June 2001

Electrochemical storage cell containing at least one electrode formulated from a phenylene-thienyl based polymer
patent, September 2000

Electroluminescent device
patent, May 1999

Batteries And Electrodes For Use Thereof
patent-application, August 2009

Metallized multilayer packaging film
patent, October 1998

Battery and process for preparing the same
patent-application, July 2001

Non-aqueous electrolyte secondary battery
patent, August 2004

Electrochemical storage cell containing at least one electrode formulated from a fluorophenyl thiophene polymer
patent, March 1998

Negative electrode for secondary cell, negative plate for secondary cell, and secondary cell comprising the same
patent, April 2003

Conductive lithium storage electrode
patent, March 2008

Processible forms of electrically conductive polyaniline
patent, April 1997

Coated electrode particles for composite electrodes and electrochemical cells
patent, August 2006

Conductive-polymer-coated electrode particles
patent, January 2001

Composite coating LiPO3
patent, September 2002

Methods for making lithium vanadium oxide electrode materials
patent, October 2000

Polymers derived from fluorinated thiophenes, and conductive polymers derived therefrom
patent, April 1995

Lithium secondary battery and electrodes therefor and method of forming the same
patent, March 1999

Reticulated and controlled porosity battery structures
patent, October 2012

Battery structures, self-organizing structures and related methods
patent, August 2011

Bipolar articles and related methods
patent, July 2010

Current collector device
patent, January 1997

Controlled porosity in electrodes
patent, December 2018

Polycarbonate electrolyte, the preparation thereof and polymer lithium batteries containing the same
patent, October 2001

Thin film battery and method for making same
patent, August 1994

Process for preparing textured ceramic composites
patent, July 1997

Secondary battery and method of manufacturing the same
patent, December 1989

Method for fabricating carbon/lithium-ion electrode for rechargeable lithium cell
patent, July 1995

Process for making battery plate
patent, September 2002

Battery and process for preparing the same
patent-application, June 2001

Intercalation compounds and electrodes for batteries
patent, September 2004

Acidity reduction of adhesion promoter layer
patent, May 1996

Electrodes and related devices
patent-application, January 2004

Battery Structures and Related Methods
patent-application, January 2004

Reinforced consumable electrode, electrochemical cell and method
patent, November 1985

Photolithographic production of microprotrusions for use as a space separator in an electrical storage device
patent, October 1998

Method and system for charging rechargeable batteries
patent, September 1999

Material and method for low internal resistance LI-ion battery
patent, September 1996

Positive active material for rechargeable lithium batteries and method for preparing same
patent, June 2004

Battery
patent, January 2002

Rechargeable battery cell having surface-treated lithiated intercalation positive electrode
patent, January 1998

Grid placement in lithium ion bi-cell counter electrodes
patent, May 2000

Solid-state electrolytic capacitor
patent-application, February 2002

Polymer composition for encapsulation of electrode particles
patent-application, February 2005

Electrolysis systems
patent, December 1998

Electromechanical actuators
patent, August 2006

Battery structures, self-organizing structures and related methods
patent, May 2012

Active material for battery and method of preparing same
patent, April 2005

Controlled Porosity in Electronics
patent-application, December 2012