All-vanadium sulfate acid redox flow battery system

Nie, Zimin; Wang, Wei; Wei, Xiaoliang; Li, Bin; Liu, Jun; Sprenkle, Vincent L.

Title: All-vanadium sulfate acid redox flow battery system

Abstract

All-vanadium sulfate redox flow battery systems have a catholyte and an anolyte comprising an aqueous supporting solution including chloride ions and phosphate ions. The aqueous supporting solution stabilizes and increases the solubility of vanadium species in the electrolyte, allowing an increased vanadium concentration over a desired operating temperature range. According to one example, the chloride ions are provided by MgCl2, and the phosphate ions are provided by (NH4)2HPO4.

Inventors:: Nie, Zimin; Wang, Wei; Wei, Xiaoliang; Li, Bin; Liu, Jun; Sprenkle, Vincent L.

Issue Date:: 2020-06-02

Research Org.:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1650978

Patent Number(s):: 10673090

Application Number:: 14/875,565

Assignee:: Battelle Memorial Institute (Richland, WA)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

Show more

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M8/188 - {by recharging of redox couples containing fluids
H01M8/20 - Indirect fuel cells, e.g. fuel cells with redox couple being irreversible

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/50 - Fuel cells

Show less

DOE Contract Number:: AC05-76RL01830

Resource Type:: Patent

Resource Relation:: Patent File Date: 10/05/2015

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Nie, Zimin, Wang, Wei, Wei, Xiaoliang, Li, Bin, Liu, Jun, and Sprenkle, Vincent L. All-vanadium sulfate acid redox flow battery system.  United States: N. p., 2020. 
        Web.

Copy to clipboard


                    Nie, Zimin, Wang, Wei, Wei, Xiaoliang, Li, Bin, Liu, Jun, & Sprenkle, Vincent L. All-vanadium sulfate acid redox flow battery system.  United States.

Copy to clipboard


                    Nie, Zimin, Wang, Wei, Wei, Xiaoliang, Li, Bin, Liu, Jun, and Sprenkle, Vincent L. Tue .  
        "All-vanadium sulfate acid redox flow battery system".  United States.  https://www.osti.gov/servlets/purl/1650978.

Copy to clipboard


                    
@article{osti_1650978,

  title        = {All-vanadium sulfate acid redox flow battery system},

  author       = {Nie, Zimin and Wang, Wei and Wei, Xiaoliang and Li, Bin and Liu, Jun and Sprenkle, Vincent L.},

  abstractNote = {All-vanadium sulfate redox flow battery systems have a catholyte and an anolyte comprising an aqueous supporting solution including chloride ions and phosphate ions. The aqueous supporting solution stabilizes and increases the solubility of vanadium species in the electrolyte, allowing an increased vanadium concentration over a desired operating temperature range. According to one example, the chloride ions are provided by MgCl2, and the phosphate ions are provided by (NH4)2HPO4.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {6}

}

Copy to clipboard

Patent:

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Novel Vanadium Halide Redox Flow Battery
patent-application, November 2010

Kazacos, Michael; Skyllas-Kazacos, Maria; Kazacos, Nicholas
US Patent Document 12/843521; 20100291420
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100291420

Redox Flow Batteries Based on Supporting Solutions Containing Chloride
patent-application, August 2014

Li, Liyu; Kim, Soowhan; Yang, Zhenguo
US Patent Document 14/261262; 20140234753
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140234753

Flow Battery Systems
patent-application, March 2012

Wilson, Gregory J.; Hanson, Kyle M.
US Patent Document 12/868489; 20120052347
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120052347

Fe-V Redox Flow Batteries
patent-application, March 2012

Li, Liyu; Kim, Soowhan; Yang, Zhenguo
US Patent Document 12/892698; 20120077067
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120077067

Redox Flow Batteries Having Multiple Electroactive Elements
patent-application, March 2012

Wang, Wei; Li, Liyu; Yang, Zhenguo
US Patent Document 13/246444; 20120077068
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120077068

Instrumented fluid-surfaced electrode
patent-application, February 2011

Deane, Geoffrey F.; Ferren, Bran; Gates, William
US Patent Document 12/803122; 20110027629
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110027629

Modified vanadium compound, producing method thereof, redox flow battery electrolyte composite and redox flow battery electrolyte producing method
patent, March 2005

Tanaka, Yasuyuki; Mita, Muneo; Horikawa, Ken
US Patent Document 6,872,376
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6872376

Redox flow batteries based on supporting solutions containing chloride
patent, September 2015

Li, Liyu; Kim, Soowhan; Yang, Zhenguo
US Patent Document 9,123,931
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9123931

Novel vanadium halide redox flow battery
patent-application, August 2006

Kazacos, Michael; Skyllas-Kazacos, Maria; Kazacos, Nicholasl
US Patent Document 10/548555; 20060183016
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060183016

Redox flow batteries based on supporting solutions containing chloride
patent, July 2015

Li, Liyu; Kim, Soowhan; Yang, Zhenguo
US Patent Document 9,077,011
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9077011

Redox Flow Cell Rebalancing
patent-application, April 2011

Keshavarz, Majid; Karuppaiah, Chockkalingam; Zu, Ge
US Patent Document 12/790573; 20110086247
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110086247

High Energy Battery Materials
patent-application, September 2010

Adamson, George W.; Ortiz, Jr., Luis A.
US Patent Document 11/992378; 20100230632
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100230632

Redox flow batteries based on supporting solutions containing chloride
patent, January 2014

Li, Liyu; Kim, Soowhan; Yang, Zhenguo
US Patent Document 8,628,880
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8628880

Perfluorinated Membranes and Improved Electrolytes for Redox Cells and Batteries
patent-application, November 2008

Kazacos, George Christopher; Kazacos, Nicholas Michael
US Patent Document 11/917989; 20080292964
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080292964

Redox Flow Batteries Based On Supporting Solutions Containing Chloride
patent-application, July 2014

Li, Liyu; Kim, Soowhan; Yang, Zhenguo
US Patent Application 14/105823; 20140199607
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140199607

Stabilized vanadium electrolyte solutions for all-vanadium redox cells and batteries
patent, May 2003

Kazacos, Maria Skyllas; Kazacos, Michael
US Patent Document 6,562,514
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6562514

Method for Storing Electrical Energy in Ionic Liquids
patent-application, May 2012

Noack, Jens; Tubke, Jens; Pinkwart, Karsten
US Patent Application 13/201813; 20120115069
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120115069

Electrolytes for redox flow batteries
patent, March 1989

Nagashima, Ikuo; Fukui, Jun; Gotoh, Hidenori
US Patent Document 4,814,241
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4814241

Redox Flow Battery System for Distributed Energy Storage
patent-application, February 2011

Horne, Craig R.; Kinoshita, Kim; Hickey, Darren B.
US Patent Document 12/883511; 20110045332
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110045332

Redox battery including a bromine positive electrode and a chromium ion negative electrode, and method
patent, September 1984

Giner, Jose D.; Stark, Herbert
US Patent Document 4,469,760
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4469760

Redox Fuel Cell
patent, November 1970

Boeke, Jan
US Patent Document 3,540,933
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/3540933

Electrolyte for Redox Flow Battery and Redox Flow Battery
patent-application, August 2015

Sekine, Ryojun; Dong, Yongrong; Kubata, Michiru
US Patent Document 14/422792; 20150221969
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150221969

Redox Flow Batteries Based on Supporting Solutions Containing Chloride
patent-application, March 2012

Li, Liyu; Kim, Soowhan; Yang, Zhenguo
US Patent Document 12/892693; 20120077079
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120077079

High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions
patent, July 2006

Kazacos, Michael; Kazacos, Maria Skyllas
US Patent Document 7,078,123
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7078123

Fe-V redox flow batteries
patent, July 2014

Li, Liyu; Kim, Soowhan; Yang, Zhenguo
US Patent Document 8,771,856
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8771856

Fully flexible financial instrument pricing system with intelligent user interfaces
patent-application, January 2003

Lim, Cheong Kee Jeffrey
US Patent Document 10/182462; 20030014345
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030014345

Metal halide redox flow battery
patent-application, November 2005

Skyllas-Kazacos, Maria; Kazacos, Michael; Mousa, Asem
US Patent Document 10/512417; 20050244707
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050244707

Electrically rechargeable REDOX flow cell
patent, December 1976

Thaller, Lawrence H.
US Patent Document 3,996,064
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/3996064

Redox Flow Battery Based on Supporting Solutions Containing Chloride
patent, December 2015

Li, Liyu; Kim, Soowhan; Yang, Zhenguo
US Patent Document 14/815037; 20150380757
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150380757

High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions
patent-application, July 2003

Kazacos, Michael; Kazacos, Maria Skyllas
US Patent Document 10/226751; 20030143456
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030143456

Vanadium/polyhalide redox flow battery
patent, January 2008

Skyllas-Kazacos, Maria
US Patent Document 7,320,844
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7320844

All-vanadium redox battery
patent, November 1988

Skyllas-Kazacos, Maria; Rychick, Miron; Robins, Robert R.
US Patent Document 4,786,567
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4786567

High Energy Density Redox Flow Device
patent-application, September 2014

Chiang, Yet-Ming; Carter, W. Craig; Duduta, Mihai
US Patent Document 14/276723; 20140248521
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140248521

System Dongle
patent-application, February 2012

Parakulam, Gopalakrishnan R.
US Patent Document 12/855059; 20120040216
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120040216

Similar Records in DOE Patents and OSTI.GOV collections:

Method and system to maintain electrolyte stability for all-iron redox flow batteries

Patent Evans, Craig E.; Song, Yang

Methods and systems are provided which maintain the positive and negative electrolyte pH and stability of a redox flow battery through the use of electrochemical rebalancing cells. The electrochemical cells may be activated by applying an electrical load to affect changes to the pH of the electrolytes. The use of the electrochemical cells improves long term performance stability redox flow batteries by decreasing and/or eliminating Fe(OH)3 precipitation formation.
Full Text Available
Method and system to maintain electrolyte stability for all-iron redox flow batteries

Patent Evans, Craig E.; Song, Yang

Methods and systems are provided which maintain the positive and negative electrolyte pH and stability of a redox flow battery through the use of electrochemical rebalancing cells. The electrochemical cells may be activated by applying an electrical load to affect changes to the pH of the electrolytes. The use of the electrochemical cells improves long term performance stability redox flow batteries by decreasing and/or eliminating Fe(OH)3 precipitation formation.
Full Text Available
Redox and plating electrode systems for an all-iron hybrid flow battery

Patent Evans, Craig; Song, Yang

A system for a flow cell for a hybrid flow battery, comprising: a redox plate comprising a plurality of electrolyte flow channels; conductive inserts attached to the redox plate between adjacent electrolyte flow channels; a redox electrode attached to a surface of the redox plate; a plating electrode, comprising: a plurality of folded fins with an oscillating cross-section, the plurality of folded fins comprising: a first planar surface; a second planar surface, parallel to the first planar surface; a plurality of ridges intersecting the first and second planar surfaces such that the plurality of ridges divide the first planar surfacemore » « less
Full Text Available
Method and system for rebalancing electrolytes in a redox flow battery system

Patent Song, Yang; Evans, Craig E.

A method of rebalancing electrolytes in a redox flow battery system comprises directing hydrogen gas generated on the negative side of the redox flow battery system to a catalyst surface, and fluidly contacting the hydrogen gas with an electrolyte comprising a metal ion at the catalyst surface, wherein the metal ion is chemically reduced by the hydrogen gas at the catalyst surface, and a state of charge of the electrolyte and pH of the electrolyte remain substantially balanced.
Full Text Available
Method and system for rebalancing electrolytes in a redox flow battery system

Patent Song, Yang; Evans, Craig E.

A redox flow battery system is provided. The system includes a positive electrode in fluid communication with a positive electrolyte comprising a first metal ion and a negative electrode in fluid communication with a negative electrolyte comprising a second metal ion. An electrically insulating ion conducting surface is provided separating the positive electrode from the negative electrode. Further, the system includes a catalyst surface in fluid communication with the first metal ion, the second metal ion, or a combination thereof, and hydrogen gas, wherein the hydrogen gas and the first metal ion, the second metal ion, or a combination thereofmore » « less
Full Text Available

Similar Records

Title: All-vanadium sulfate acid redox flow battery system

Abstract

Citation Formats

Novel Vanadium Halide Redox Flow Battery patent-application, November 2010

Redox Flow Batteries Based on Supporting Solutions Containing Chloride patent-application, August 2014

Flow Battery Systems patent-application, March 2012

Fe-V Redox Flow Batteries patent-application, March 2012

Redox Flow Batteries Having Multiple Electroactive Elements patent-application, March 2012

Instrumented fluid-surfaced electrode patent-application, February 2011

Modified vanadium compound, producing method thereof, redox flow battery electrolyte composite and redox flow battery electrolyte producing method patent, March 2005

Redox flow batteries based on supporting solutions containing chloride patent, September 2015

Novel vanadium halide redox flow battery patent-application, August 2006

Redox flow batteries based on supporting solutions containing chloride patent, July 2015

Redox Flow Cell Rebalancing patent-application, April 2011

High Energy Battery Materials patent-application, September 2010

Redox flow batteries based on supporting solutions containing chloride patent, January 2014

Perfluorinated Membranes and Improved Electrolytes for Redox Cells and Batteries patent-application, November 2008

Redox Flow Batteries Based On Supporting Solutions Containing Chloride patent-application, July 2014

Stabilized vanadium electrolyte solutions for all-vanadium redox cells and batteries patent, May 2003

Method for Storing Electrical Energy in Ionic Liquids patent-application, May 2012

Electrolytes for redox flow batteries patent, March 1989

Redox Flow Battery System for Distributed Energy Storage patent-application, February 2011

Redox battery including a bromine positive electrode and a chromium ion negative electrode, and method patent, September 1984

Redox Fuel Cell patent, November 1970

Electrolyte for Redox Flow Battery and Redox Flow Battery patent-application, August 2015

Redox Flow Batteries Based on Supporting Solutions Containing Chloride patent-application, March 2012

High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions patent, July 2006

Fe-V redox flow batteries patent, July 2014

Fully flexible financial instrument pricing system with intelligent user interfaces patent-application, January 2003

Metal halide redox flow battery patent-application, November 2005

Electrically rechargeable REDOX flow cell patent, December 1976

Redox Flow Battery Based on Supporting Solutions Containing Chloride patent, December 2015

High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions patent-application, July 2003

Vanadium/polyhalide redox flow battery patent, January 2008

All-vanadium redox battery patent, November 1988

High Energy Density Redox Flow Device patent-application, September 2014

System Dongle patent-application, February 2012

Novel Vanadium Halide Redox Flow Battery
patent-application, November 2010

Redox Flow Batteries Based on Supporting Solutions Containing Chloride
patent-application, August 2014

Flow Battery Systems
patent-application, March 2012

Fe-V Redox Flow Batteries
patent-application, March 2012

Redox Flow Batteries Having Multiple Electroactive Elements
patent-application, March 2012

Instrumented fluid-surfaced electrode
patent-application, February 2011

Modified vanadium compound, producing method thereof, redox flow battery electrolyte composite and redox flow battery electrolyte producing method
patent, March 2005

Redox flow batteries based on supporting solutions containing chloride
patent, September 2015

Novel vanadium halide redox flow battery
patent-application, August 2006

Redox flow batteries based on supporting solutions containing chloride
patent, July 2015

Redox Flow Cell Rebalancing
patent-application, April 2011

High Energy Battery Materials
patent-application, September 2010

Redox flow batteries based on supporting solutions containing chloride
patent, January 2014

Perfluorinated Membranes and Improved Electrolytes for Redox Cells and Batteries
patent-application, November 2008

Redox Flow Batteries Based On Supporting Solutions Containing Chloride
patent-application, July 2014

Stabilized vanadium electrolyte solutions for all-vanadium redox cells and batteries
patent, May 2003

Method for Storing Electrical Energy in Ionic Liquids
patent-application, May 2012

Electrolytes for redox flow batteries
patent, March 1989

Redox Flow Battery System for Distributed Energy Storage
patent-application, February 2011

Redox battery including a bromine positive electrode and a chromium ion negative electrode, and method
patent, September 1984

Redox Fuel Cell
patent, November 1970

Electrolyte for Redox Flow Battery and Redox Flow Battery
patent-application, August 2015

Redox Flow Batteries Based on Supporting Solutions Containing Chloride
patent-application, March 2012

High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions
patent, July 2006

Fe-V redox flow batteries
patent, July 2014

Fully flexible financial instrument pricing system with intelligent user interfaces
patent-application, January 2003

Metal halide redox flow battery
patent-application, November 2005

Electrically rechargeable REDOX flow cell
patent, December 1976

Redox Flow Battery Based on Supporting Solutions Containing Chloride
patent, December 2015

High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions
patent-application, July 2003

Vanadium/polyhalide redox flow battery
patent, January 2008

All-vanadium redox battery
patent, November 1988

High Energy Density Redox Flow Device
patent-application, September 2014

System Dongle
patent-application, February 2012