Functionalized linear and cyclic polyolefins

Tuba, Robert; Grubbs, Robert H.

Title: Functionalized linear and cyclic polyolefins

Abstract

This invention relates to methods and compositions for preparing linear and cyclic polyolefins. More particularly, the invention relates to methods and compositions for preparing functionalized linear and cyclic polyolefins via olefin metathesis reactions. Polymer products produced via the olefin metathesis reactions of the invention may be utilized for a wide range of materials applications. The invention has utility in the fields of polymer and materials chemistry and manufacture.

Inventors:: Tuba, Robert; Grubbs, Robert H.

Issue Date:: 2020-04-14

Research Org.:: California Institute of Technology (CalTech), Pasadena, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1650760

Patent Number(s):: 10619003

Application Number:: 15/860,906

Assignee:: California Institute of Technology (Pasadena, CA)

Patent Classifications (CPCs):: C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08L - COMPOSITIONS OF MACROMOLECULAR COMPOUNDS

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C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G2261/142 - Side-chains containing oxygen
C08G2261/1422 - containing OH groups
C08G2261/3321 - derived from cyclopentene
C08G2261/3342 - derived from cycloolefins containing heteroatoms
C08G2261/418 - Ring opening metathesis polymerisation [ROMP]
C08G2261/419 - Acyclic diene metathesis [ADMET]
C08G2261/724 - Hydrogenation
C08G2261/80 - Functional group cleavage, e.g. removal of side-chains or protective groups
C08G61/08 - of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
C08G61/12 - Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08L - COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
C08L65/00 - Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain

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DOE Contract Number:: FG02-08ER15933

Resource Type:: Patent

Resource Relation:: Patent File Date: 01/03/2018

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Tuba, Robert, and Grubbs, Robert H. Functionalized linear and cyclic polyolefins.  United States: N. p., 2020. 
        Web.

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                    Tuba, Robert, & Grubbs, Robert H. Functionalized linear and cyclic polyolefins.  United States.

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                    Tuba, Robert, and Grubbs, Robert H. Tue .  
        "Functionalized linear and cyclic polyolefins".  United States.  https://www.osti.gov/servlets/purl/1650760.

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@article{osti_1650760,

  title        = {Functionalized linear and cyclic polyolefins},

  author       = {Tuba, Robert and Grubbs, Robert H.},

  abstractNote = {This invention relates to methods and compositions for preparing linear and cyclic polyolefins. More particularly, the invention relates to methods and compositions for preparing functionalized linear and cyclic polyolefins via olefin metathesis reactions. Polymer products produced via the olefin metathesis reactions of the invention may be utilized for a wide range of materials applications. The invention has utility in the fields of polymer and materials chemistry and manufacture.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {4}

}

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Title: Functionalized linear and cyclic polyolefins

Abstract

Citation Formats

Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization patent, May 1994

In-Mold Coating of Romp Polymers patent-application, December 2014

Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water patent, November 2002

Homobimetallic and heterobimetallic alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands patent, September 2004

Process for production of cyclic polyenes patent, June 1976

ABA triblock and diblock copolymers and methods of preparing the same patent, June 2002

Immobilised imidazoles and ruthenium catalysts patent-application, December 2006

Use of a phosphorus containing ligand and a cyclic organic ligand in a transition metal compound patent, March 2010

Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis patent, January 2010

Linear ethylene/vinyl alcohol and ethylene/vinyl acetate polymers and process for making same patent-application, May 2005

Ruthenium complexes, process for preparation thereof, and processes for producing open-ring polymer of cycloolefins and hydrogenation products thereof by using the complex as catalyst patent-application, January 2005

Process of olefin metathesis patent, April 1976

Metal complexes useful in metathesis and other reactions patent, March 2010

Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization patent, August 1994

Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis patent, May 2008

Process for preparing acyclic olefins using homobimetallic and heterobimetallic alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands patent, April 2003

Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis patent, October 2003

Schiff base derivatives of ruthenium and osmium olefin metathesis catalysts patent, November 1999

One-pot synthesis of group 8 transition metal carbene complexes useful as olefin metathesis catalysts patent, September 2003

Methods of Making Organic Compounds by Metathesis patent-application, October 2009

Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water patent, September 2001

Group 8 transition metal carbene complexes as enantioselective olefin metathesis catalysts patent-application, March 2003

Polyalkenamers and Process for the Preparation Thereof patent, June 1974

Methods for Preparing Purified Polypeptide Compositions patent-application, August 2010

Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis patent, November 2007

Multicoordinated Metal Complexes for Use in Metathesis Reactions patent-application, February 2007

Multicoordinated Metal Complexes for Use in Metathesis Reactions patent-application, November 2008

Catalysts for Ring-Closing Metathesis patent-application, July 2009

Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization
patent, May 1994

In-Mold Coating of Romp Polymers
patent-application, December 2014

Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water
patent, November 2002

Homobimetallic and heterobimetallic alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands
patent, September 2004

Process for production of cyclic polyenes
patent, June 1976

ABA triblock and diblock copolymers and methods of preparing the same
patent, June 2002

Immobilised imidazoles and ruthenium catalysts
patent-application, December 2006

Use of a phosphorus containing ligand and a cyclic organic ligand in a transition metal compound
patent, March 2010

Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis
patent, January 2010

Linear ethylene/vinyl alcohol and ethylene/vinyl acetate polymers and process for making same
patent-application, May 2005

Ruthenium complexes, process for preparation thereof, and processes for producing open-ring polymer of cycloolefins and hydrogenation products thereof by using the complex as catalyst
patent-application, January 2005

Process of olefin metathesis
patent, April 1976

Metal complexes useful in metathesis and other reactions
patent, March 2010

Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization
patent, August 1994

Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis
patent, May 2008

Process for preparing acyclic olefins using homobimetallic and heterobimetallic alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands
patent, April 2003

Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis
patent, October 2003

Schiff base derivatives of ruthenium and osmium olefin metathesis catalysts
patent, November 1999

One-pot synthesis of group 8 transition metal carbene complexes useful as olefin metathesis catalysts
patent, September 2003

Methods of Making Organic Compounds by Metathesis
patent-application, October 2009

Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water
patent, September 2001

Group 8 transition metal carbene complexes as enantioselective olefin metathesis catalysts
patent-application, March 2003

Polyalkenamers and Process for the Preparation Thereof
patent, June 1974

Methods for Preparing Purified Polypeptide Compositions
patent-application, August 2010

Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis
patent, November 2007

Multicoordinated Metal Complexes for Use in Metathesis Reactions
patent-application, February 2007

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