Mixed metal oxide extrudate catalyst

Zhao, Xianhui; Kuhn, John Norbert; Walker, Devin Mason; Joseph, Babu

Title: Mixed metal oxide extrudate catalyst

Abstract

Methods of making a Ce0.6Zr0.4O2 supported NiMg catalyst extrudate are provided. In some aspects, the methods include preparing a ceria-zirconia solution comprising Ce(NO3)3.6H2O, ZrO(NO3)2xH2O, and water; forming a precipitate; drying and calcining the precipitate to produce a Ce0.6Zr0.4O2; adding a nickel-magnesium solution to the Ce0.6Zr0.4O2 to produce the NiMg/Ce0.6Zr0.4O2; and drying and calcining a wet extrudate of the NiMg/Ce0.6Zr0.4O2 to produce the Ce0.6Zr0.4O2 supported NiMg catalyst extrudate. Ce0.6Zr0.4O2 supported NiMg catalyst extrudates made by the methods are also provided.

Inventors:: Zhao, Xianhui; Kuhn, John Norbert; Walker, Devin Mason; Joseph, Babu

Issue Date:: 2020-04-14

Research Org.:: Univ. of South Florida, Tampa, FL (United States); T2C-Energy, LLC, Tampa, FL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1650754

Patent Number(s):: 10618042

Application Number:: 15/994,813

Assignee:: University of South Florida (Tampa, FL); T2C-Energy, LLC (Tampa, FL)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

Show more

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J21/066 - {Zirconium or hafnium
B01J21/10 - Magnesium
B01J23/005 - {Spinels}
B01J23/755 - Nickel
B01J23/78 - with alkali- or alkaline earth metals
B01J23/83 - with rare earths or actinides
B01J2523/3712 - Cerium
B01J2523/48 - Zirconium
B01J35/002 - {Catalysts characterised by their physical properties}
B01J35/1014 - {10-100 m2/g}
B01J35/1038 - {less than 0.5 ml/g}
B01J35/1042 - {0.5-1.0 ml/g}
B01J35/1061 - {2-50 nm}
B01J37/0009 - {Use of binding agents
B01J37/0036 - {Grinding}
B01J37/031 - {Precipitation}
B01J37/08 - Heat treatment {

Show less

DOE Contract Number:: SC0015221

Resource Type:: Patent

Resource Relation:: Patent File Date: 05/31/2018

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Zhao, Xianhui, Kuhn, John Norbert, Walker, Devin Mason, and Joseph, Babu. Mixed metal oxide extrudate catalyst.  United States: N. p., 2020. 
        Web.

Copy to clipboard


                    Zhao, Xianhui, Kuhn, John Norbert, Walker, Devin Mason, & Joseph, Babu. Mixed metal oxide extrudate catalyst.  United States.

Copy to clipboard


                    Zhao, Xianhui, Kuhn, John Norbert, Walker, Devin Mason, and Joseph, Babu. Tue .  
        "Mixed metal oxide extrudate catalyst".  United States.  https://www.osti.gov/servlets/purl/1650754.

Copy to clipboard


                    
@article{osti_1650754,

  title        = {Mixed metal oxide extrudate catalyst},

  author       = {Zhao, Xianhui and Kuhn, John Norbert and Walker, Devin Mason and Joseph, Babu},

  abstractNote = {Methods of making a Ce0.6Zr0.4O2 supported NiMg catalyst extrudate are provided. In some aspects, the methods include preparing a ceria-zirconia solution comprising Ce(NO3)3.6H2O, ZrO(NO3)2xH2O, and water; forming a precipitate; drying and calcining the precipitate to produce a Ce0.6Zr0.4O2; adding a nickel-magnesium solution to the Ce0.6Zr0.4O2 to produce the NiMg/Ce0.6Zr0.4O2; and drying and calcining a wet extrudate of the NiMg/Ce0.6Zr0.4O2 to produce the Ce0.6Zr0.4O2 supported NiMg catalyst extrudate. Ce0.6Zr0.4O2 supported NiMg catalyst extrudates made by the methods are also provided.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {4}

}

Copy to clipboard

Patent:

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Ceria-based mixed-metal oxide structure, including method of making and use
patent-application, October 2003

Vanderspurt, Thomas Henry; Wijzen, Fabienne; Tang, Xia
US Patent Application 10/109161; 20030186805
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030186805

Partial oxidation catalyst
patent, August 2000

Krumpelt, Michael; Ahmed, Shabbir; Kumar, Romesh
US Patent Document 6,110,861
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6110861

Enteric coating, comprising alginic acid, for an oral preparation
patent, September 2002

Marcussen, Jørn; Brandsborg, Erik
US Patent Document 6,455,052
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6455052

Promoted nickel-magnesium oxide catalysts and process for producing synthesis gas
patent, May 2007

Ramani, Sriram; Allison, Joe D.; Minahan, David
US Patent Document 7,223,354
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7223354

Composition based on cerium oxide or on cerium and zirconium oxides, in the extruded form, process for the preparation thereof and use thereof as catalyst
patent, January 2003

Blanchard, Gilbert; Quemere, Eric
US Patent Document 6,506,705
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6506705

Moving bed process for carbothermally synthesizing nonoxide ceramic powders
patent, March 1997

Henley, John P.; Cochran, Gene A.; Dunn, David A.
US Patent Document 5,607,297
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5607297

Hydrated niobium oxide and hydrated tantalum oxide catalysts, their preparation and a process for preparing N-alkylated anilines using these catalysts
patent, January 1997

Glock, Volker; Pentling, Ursula; Pennemann, Bernd
US Patent Document 5,593,936
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5593936

Durable regenerable sorbent pellets for removal of hydrogen sulfide coal gas
patent, February 1999

Siriwardane, Ranjani V.
US Patent Document 5,866,503
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5866503

Processes an catalyst for upgrading waxy, paraffinic feeds
patent, October 1999

Wittenbrink, Robert J.; Koveal, Russell John; Murphy, William J.
US Patent Document 5,965,475
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5965475

Nickel-cerium oxide-zirconium oxide-silica catalysts for hydrogenation of succinic anhydride to butyrolactone
patent, May 1987

Drake, Charles A.
US Patent Document 4,668,654
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4668654

Porous ceramic matrix
patent, April 2015

Hong, Liang; Chen, Xinwei
US Patent Document 9,000,199
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9000199

Solid solution particle of oxides, a process for producing the same and a catalyst for purifying exhaust gases
patent, September 1999

Suda, Akihiko; Sobukawa, Hideo; Suzuki, Tadashi
US Patent Document 5,958,827
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5958827

Supported nickel-magnesium oxide catalysts and processes for the production of syngas
patent, October 2003

Figueroa, Juan Carlos; Gaffney, Anne Mae; Mattson, Ronald
US Patent Document 6,635,191
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6635191

Ni nano cluster support on MgO—CeO2—ZrO2 catalyst for tri-reforming of methane and a process for preparation thereof
patent, April 2017

Bordoloi, Ankur; Singha, Rajib Kumar; Bal, Rajaram
US Patent Document 9,630,167
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9630167

Reforming catalyst
patent, December 2014

Skjøth-Rasmussen, Martin Skov; Cano Morales, Fernando; Bak Hansen, Jens-Henrik
US Patent Document 8,916,492
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8916492

Nano Ni—CeO2 catalyst for syngas production and its preparation thereof
patent, November 2016

Rajaram, Bal; Rajib Kumar, Singha; Chandrashekar, Pendem
US Patent Document 9,480,974
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9480974

Preparation of extrusions of bulk mixed oxide compounds with high macroporosity and mechanical strength
patent, December 1990

Flytzani-Stephanopoulos, Maria; Jothimurugesan, Kandaswami
US Patent Document 4,977,123
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4977123

Composite oxide, process for producing the same, and exhaust gas reducing co-catalyst
patent, July 2007

Morikawa, Akira; Nagai, Yasutaka; Tanabe, Toshitaka
US Patent Document 7,247,597
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7247597

Catalysts for hydrogen production
patent, November 2010

Idem, Raphael; Kumar, Prashant; Sun, Yanping
US Patent Document 7,824,656
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7824656

Pellets and processes therefor
patent, August 2015

McGoldrick, Fredrick
US Patent Document 9,102,887
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9102887

Systems and methods for producing liquid fuels from landfill gases
patent, June 2018

Kuhn, John Norbert; Joseph, Babu; Walker, Devin
US Patent Document 10,005,963
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/10005963

Proppant composition for gas and oil well fracturing
patent, April 2002

Youngman, Robert A.; Okell, Patrick R.; Akbar, Syed
US Patent Document 6,372,678
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6372678

Nickel catalysts for reforming hydrocarbons
patent, October 2015

Lee, Seung-Jae; Son, In-Hyuk; Roh, Hyun-Seog
US Patent Document 9,168,510
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9168510

Method for production of molded product containing titanium oxide
patent, October 1981

Shimizu, Shinkichi; Nishizaki, Tadao; Tsuda, Masabumi
US Patent Document 4,293,445
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4293445

Similar Records in DOE Patents and OSTI.GOV collections:

Nanostructured mixed metal oxides as catalysts and method of making thereof

Patent Nikolla, Eranda; Wang, Bingwen; Nacy, Ayad

A method of forming a metal oxide material having a rod shape or polyhedral nanostructure includes preparing a first reverse micro-emulsion system comprising an aqueous precipitating agent dispersion and a second reverse micro-emulsion system containing an aqueous metal salt dispersion; combining the micro-emulsions together to initiate a reaction; allowing the reaction to continue to form a product mixture comprising a metal oxide gel and aqueous media; separating the metal oxide gel from the aqueous media; collecting the metal oxide gel; and calcining the metal oxide gel to form the metal oxide material. The metal oxide material corresponds to the chemicalmore » « less
Full Text Available
Preparation of uniform nanoparticles of ultra-high purity metal oxides, mixed metal oxides, metals, and metal alloys

Patent Woodfield, Brian F.; Liu, Shengfeng; Boerio-Goates, Juliana; ...

In preferred embodiments, metal nanoparticles, mixed-metal (alloy) nanoparticles, metal oxide nanoparticles and mixed-metal oxide nanoparticles are provided. According to embodiments, the nanoparticles may possess narrow size distributions and high purities. In certain preferred embodiments, methods of preparing metal nanoparticles, mixed-metal nanoparticles, metal oxide nanoparticles and mixed-metal nanoparticles are provided. These methods may provide tight control of particle size, size distribution, and oxidation state. Other preferred embodiments relate to a precursor material that may be used to form nanoparticles. In addition, products prepared from such nanoparticles are disclosed.
Full Text Available
Catalyst support of mixed cerium zirconium titanium oxide, including use and method of making

Patent Willigan, Rhonda R [Manchester, CT]; Vanderspurt, Thomas Henry [Glastonbury, CT]; Tulyani, Sonia [Manchester, CT]; ...

A durable catalyst support/catalyst is capable of extended water gas shift operation under conditions of high temperature, pressure, and sulfur levels. The support is a homogeneous, nanocrystalline, mixed metal oxide of at least three metals, the first being cerium, the second being Zr, and/or Hf, and the third importantly being Ti, the three metals comprising at least 80% of the metal constituents of the mixed metal oxide and the Ti being present in a range of 5% to 45% by metals-only atomic percent of the mixed metal oxide. The mixed metal oxide has an average crystallite size less than 6more » « less
Full Text Available
Synthesis of metal-metal oxide catalysts and electrocatalysts using a metal cation adsorption/reduction and adatom replacement by more noble ones

Patent Adzic, Radoslav; Vukmirovic, Miomir; Sasaki, Kotaro

The invention relates to platinum-metal oxide composite particles and their use as electrocatalysts in oxygen-reducing cathodes and fuel cells. The invention particularly relates to methods for preventing the oxidation of the platinum electrocatalyst in the cathodes of fuel cells by use of these platinum-metal oxide composite particles. The invention additionally relates to methods for producing electrical energy by supplying such a fuel cell with an oxidant, such as oxygen, and a fuel source, such as hydrogen. The invention also relates to methods of making the metal-metal oxide composites.
Full Text Available
Oxidation catalysts comprising metal exchanged hexaaluminate wherein the metal is Sr, Pd, La, and/or Mn

Patent Wickham, David [Boulder, CO]; Cook, Ronald [Lakewood, CO]

The present invention provides metal-exchanged hexaaluminate catalysts that exhibit good catalytic activity and/or stability at high temperatures for extended periods with retention of activity as combustion catalysts, and more generally as oxidation catalysts, that make them eminently suitable for use in methane combustion, particularly for use in natural gas fired gas turbines. The hexaaluminate catalysts of this invention are of particular interest for methane combustion processes for minimization of the generation of undesired levels (less than about 10 ppm) of NOx species. Metal exchanged hexaaluminate oxidation catalysts are also useful for oxidation of volatile organic compounds (VOC), particularly hydrocarbons. Metalmore » « less
Full Text Available

Similar Records

Title: Mixed metal oxide extrudate catalyst

Abstract

Citation Formats

Ceria-based mixed-metal oxide structure, including method of making and use patent-application, October 2003

Partial oxidation catalyst patent, August 2000

Enteric coating, comprising alginic acid, for an oral preparation patent, September 2002

Promoted nickel-magnesium oxide catalysts and process for producing synthesis gas patent, May 2007

Composition based on cerium oxide or on cerium and zirconium oxides, in the extruded form, process for the preparation thereof and use thereof as catalyst patent, January 2003

Moving bed process for carbothermally synthesizing nonoxide ceramic powders patent, March 1997

Hydrated niobium oxide and hydrated tantalum oxide catalysts, their preparation and a process for preparing N-alkylated anilines using these catalysts patent, January 1997

Durable regenerable sorbent pellets for removal of hydrogen sulfide coal gas patent, February 1999

Processes an catalyst for upgrading waxy, paraffinic feeds patent, October 1999

Nickel-cerium oxide-zirconium oxide-silica catalysts for hydrogenation of succinic anhydride to butyrolactone patent, May 1987

Porous ceramic matrix patent, April 2015

Solid solution particle of oxides, a process for producing the same and a catalyst for purifying exhaust gases patent, September 1999

Supported nickel-magnesium oxide catalysts and processes for the production of syngas patent, October 2003

Ni nano cluster support on MgO—CeO2—ZrO2 catalyst for tri-reforming of methane and a process for preparation thereof patent, April 2017

Reforming catalyst patent, December 2014

Nano Ni—CeO2 catalyst for syngas production and its preparation thereof patent, November 2016

Preparation of extrusions of bulk mixed oxide compounds with high macroporosity and mechanical strength patent, December 1990

Composite oxide, process for producing the same, and exhaust gas reducing co-catalyst patent, July 2007

Catalysts for hydrogen production patent, November 2010

Pellets and processes therefor patent, August 2015

Systems and methods for producing liquid fuels from landfill gases patent, June 2018

Proppant composition for gas and oil well fracturing patent, April 2002

Nickel catalysts for reforming hydrocarbons patent, October 2015

Method for production of molded product containing titanium oxide patent, October 1981

Ceria-based mixed-metal oxide structure, including method of making and use
patent-application, October 2003

Partial oxidation catalyst
patent, August 2000

Enteric coating, comprising alginic acid, for an oral preparation
patent, September 2002

Promoted nickel-magnesium oxide catalysts and process for producing synthesis gas
patent, May 2007

Composition based on cerium oxide or on cerium and zirconium oxides, in the extruded form, process for the preparation thereof and use thereof as catalyst
patent, January 2003

Moving bed process for carbothermally synthesizing nonoxide ceramic powders
patent, March 1997

Hydrated niobium oxide and hydrated tantalum oxide catalysts, their preparation and a process for preparing N-alkylated anilines using these catalysts
patent, January 1997

Durable regenerable sorbent pellets for removal of hydrogen sulfide coal gas
patent, February 1999

Processes an catalyst for upgrading waxy, paraffinic feeds
patent, October 1999

Nickel-cerium oxide-zirconium oxide-silica catalysts for hydrogenation of succinic anhydride to butyrolactone
patent, May 1987

Porous ceramic matrix
patent, April 2015

Solid solution particle of oxides, a process for producing the same and a catalyst for purifying exhaust gases
patent, September 1999

Supported nickel-magnesium oxide catalysts and processes for the production of syngas
patent, October 2003

Ni nano cluster support on MgO—CeO2—ZrO2 catalyst for tri-reforming of methane and a process for preparation thereof
patent, April 2017

Reforming catalyst
patent, December 2014

Nano Ni—CeO2 catalyst for syngas production and its preparation thereof
patent, November 2016

Preparation of extrusions of bulk mixed oxide compounds with high macroporosity and mechanical strength
patent, December 1990

Composite oxide, process for producing the same, and exhaust gas reducing co-catalyst
patent, July 2007

Catalysts for hydrogen production
patent, November 2010

Pellets and processes therefor
patent, August 2015

Systems and methods for producing liquid fuels from landfill gases
patent, June 2018

Proppant composition for gas and oil well fracturing
patent, April 2002

Nickel catalysts for reforming hydrocarbons
patent, October 2015

Method for production of molded product containing titanium oxide
patent, October 1981