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Title: Manufacturing of thick composite electrode using solvent mixtures

Abstract

A method of making an electrode includes the step of dispersing an active electrode material and a conductive additive in a solvent to create a mixed dispersion. The solvent has a surface tension less than 40 mN/m and an ozone forming potential of no more than 1.5 lbs. ozone/lb. solvent. A surface of a current collector is treated to raise the surface energy of the surface to at least the surface tension of the solvent or the mixed dispersion. The dispersed active electrode material and conductive additive are deposited on the current collector. The coated surface is heated to remove solvent from the coating.

Inventors:
; ; ;
Issue Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1637812
Patent Number(s):
10601027
Application Number:
15/965,242
Assignee:
UT-Battelle, LLC (Oak Ridge, TN)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
AC05-00OR22725
Resource Type:
Patent
Resource Relation:
Patent File Date: 04/27/2018
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE

Citation Formats

Du, Zhijia, Daniel, Claus, Li, Jianlin, and Wood, III, David L. Manufacturing of thick composite electrode using solvent mixtures. United States: N. p., 2020. Web.
Du, Zhijia, Daniel, Claus, Li, Jianlin, & Wood, III, David L. Manufacturing of thick composite electrode using solvent mixtures. United States.
Du, Zhijia, Daniel, Claus, Li, Jianlin, and Wood, III, David L. Tue . "Manufacturing of thick composite electrode using solvent mixtures". United States. https://www.osti.gov/servlets/purl/1637812.
@article{osti_1637812,
title = {Manufacturing of thick composite electrode using solvent mixtures},
author = {Du, Zhijia and Daniel, Claus and Li, Jianlin and Wood, III, David L.},
abstractNote = {A method of making an electrode includes the step of dispersing an active electrode material and a conductive additive in a solvent to create a mixed dispersion. The solvent has a surface tension less than 40 mN/m and an ozone forming potential of no more than 1.5 lbs. ozone/lb. solvent. A surface of a current collector is treated to raise the surface energy of the surface to at least the surface tension of the solvent or the mixed dispersion. The dispersed active electrode material and conductive additive are deposited on the current collector. The coated surface is heated to remove solvent from the coating.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Mar 24 00:00:00 EDT 2020},
month = {Tue Mar 24 00:00:00 EDT 2020}
}

Works referenced in this record:

Influence of Electrode Density on the Performance of Li-Ion Batteries: Experimental and Simulation Results
journal, February 2016


Horizontal drying fronts during solvent evaporation from latex films
journal, September 1998


Aqueous processing of composite Lithium ion electrode material
patent-application, May 2013


Optimizing Areal Capacities through Understanding the Limitations of Lithium-Ion Electrodes
journal, November 2015


Prospects for reducing the processing cost of lithium ion batteries
journal, February 2015


Performance of high-power lithium-ion cells under pulse discharge and charge conditions
journal, December 2009


Aqueous processing of composite lithium ion electrode material
patent, June 2017


Direct Measurements of Critical Stresses and Cracking in Thin Films of Colloid Dispersions
journal, May 2008


Cracking in Drying Colloidal Films
journal, May 2007


Dependence of surface tension on composition of binary aqueous-organic solutions
journal, February 1989


Superior Performance of LiFePO 4 Aqueous Dispersions via Corona Treatment and Surface Energy Optimization
journal, January 2012


Performance of LiNi1/3Mn1/3Co1/3O2/graphite batteries based on aqueous binder
journal, February 2014


Energy impact of cathode drying and solvent recovery during lithium-ion battery manufacturing
journal, August 2016


Electron Beam Curing of Composite Positive Electrode for Li-Ion Battery
journal, January 2016


Role of Capillary Stresses in Film Formation
journal, March 2004


Surface Tension of Alcohol Water + Water from 20 to 50 .degree.C
journal, May 1995


Enabling aqueous processing for crack-free thick electrodes
journal, June 2017


Discrete modeling of plastic cement paste subjected to drying
journal, October 2011


Describing soil crack formation using elastic-plastic fracture mechanics
journal, February 2005


Drying of Granular Ceramic Films: I, Effect of Processing Variables on Cracking Behavior
journal, September 1993


Aqueous processing of composite lithium ion electrode material
patent, February 2015


Investigations on cellulose-based high voltage composite cathodes for lithium ion batteries
journal, September 2011


Recent advances in rechargeable battery materials: a chemist’s perspective
journal, January 2009


Internal Stresses during Film Formation of Polymer Latices
journal, October 1999


Simulation of capillary shrinkage cracking in cement-like materials
journal, August 2009


Drying of Granular Ceramic Films: II, Drying Stress and Saturation Uniformity
journal, November 1993


Aging of LiNi1/3Mn1/3Co1/3O2 cathode material upon exposure to H2O
journal, June 2011


Understanding limiting factors in thick electrode performance as applied to high energy density Li-ion batteries
journal, February 2017


Shape Evolution and Stress Development during Latex−Silica Film Formation
journal, June 2002


A Process Model for Latex Film Formation:  Limiting Regimes for Individual Driving Forces
journal, October 1999