Surface-modified cyanide-based transition metal compounds

Motallebi, Shahrokh; Wessells, Colin Deane

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Title: Surface-modified cyanide-based transition metal compounds

Abstract

A system, method, and articles of manufacture for a surface-modified transition metal cyanide coordination compound (TMCCC) composition, an improved electrode including the composition, and a manufacturing method for the composition which may include multiple chelation species (Che_x). The composition, compound, device, and uses thereof according to AxMn(y-k)Mjk[Mnm(CN)(6-p-q)(NC)p(Che_I)rq]z.CHE_GROUP (Vac)(1-z).nH2O, wherein CHE_GROUP includes one or more chelation materials selected from the group consisting of (Che_I)rw, (Che_II)sv, and combinations thereof, and wherein 0 < j≤4, 0≤k≤0.1, 0≤(p+q)≤6, 0 < x≤4, 0 < y≤1, 0 < z≤1, 0 < w≤0.2; −3≤r≤3; 0 < v≤0.2; −3≤s≤3; and 0≤n≤6; wherein x+2(y−k)+jk+(m+(r+1)q−6)z+wr+vs=0.

Inventors:: Motallebi, Shahrokh; Wessells, Colin Deane

Issue Date:: 2020-03-24

Research Org.:: Natron Energy, Inc., Santa Clara, CA (United States)

Sponsoring Org.:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

OSTI Identifier:: 1637787

Patent Number(s):: 10597303

Application Number:: 16/569,216

Assignee:: Natron Energy, Inc. (Santa Clara, CA)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01C - AMMONIA

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01C - AMMONIA
C01C3/11 - Complex cyanides
C01C3/12 - Simple or complex iron cyanides

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G45/006 - {Compounds containing, besides manganese, two or more other elements, with the exception of oxygen or hydrogen

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/05 - Accumulators with non-aqueous electrolyte
H01M10/36 - Accumulators not provided for in groups H01M10/05-H01M10/34
H01M4/58 - of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M4/60 - of organic compounds

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: AR000300

Resource Type:: Patent

Resource Relation:: Patent File Date: 09/12/2019

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats


                    Motallebi, Shahrokh, and Wessells, Colin Deane. Surface-modified cyanide-based transition metal compounds.  United States: N. p., 2020. 
        Web.

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                    Motallebi, Shahrokh, & Wessells, Colin Deane. Surface-modified cyanide-based transition metal compounds.  United States.

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                    Motallebi, Shahrokh, and Wessells, Colin Deane. Tue .  
        "Surface-modified cyanide-based transition metal compounds".  United States.  https://www.osti.gov/servlets/purl/1637787.

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@article{osti_1637787,

  title        = {Surface-modified cyanide-based transition metal compounds},

  author       = {Motallebi, Shahrokh and Wessells, Colin Deane},

  abstractNote = {A system, method, and articles of manufacture for a surface-modified transition metal cyanide coordination compound (TMCCC) composition, an improved electrode including the composition, and a manufacturing method for the composition which may include multiple chelation species (Che_x). The composition, compound, device, and uses thereof according to AxMn(y-k)Mjk[Mnm(CN)(6-p-q)(NC)p(Che_I)rq]z.CHE_GROUP (Vac)(1-z).nH2O, wherein CHE_GROUP includes one or more chelation materials selected from the group consisting of (Che_I)rw, (Che_II)sv, and combinations thereof, and wherein 0 < j≤4, 0≤k≤0.1, 0≤(p+q)≤6, 0 < x≤4, 0 < y≤1, 0 < z≤1, 0 < w≤0.2; −3≤r≤3; 0 < v≤0.2; −3≤s≤3; and 0≤n≤6; wherein x+2(y−k)+jk+(m+(r+1)q−6)z+wr+vs=0.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {3}

}

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