Alkali ion conducting plastic crystals

Angell, C. Austen; Klein, Iolanda Santana; Tucker, Telpriore Greg

Title: Alkali ion conducting plastic crystals

Abstract

Inorganic plastic crystal electrolytes, also referred to herein as inorganic plastic crystal conductors or single ion conductors including [ABx-yCy]y−[M]y+, where A is a tetravalent to hexavalent atom; B is a monovalent ligand; C is an oxyanion; M is an alkali metal; x is 4 when A is tetravalent, x is 5 when A is pentavalent, and x is 6 when A is hexavalent; y is an integer from 1 to x−1 inclusive. [ABx-yCy]y−[M]y+ is rotationally disordered and ionically conductive.

Inventors:: Angell, C. Austen; Klein, Iolanda Santana; Tucker, Telpriore Greg

Issue Date:: 2019-11-26

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1600335

Patent Number(s):: 10490847

Application Number:: 14/775,215

Assignee:: Arizona Board of Regents, a Body Corporate of the State of Arizona Acting for and on Behalf of Arizona State University (Scottsdale, AZ)

Patent Classifications (CPCs):: Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

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Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0562 - Solid materials
H01M10/056 - characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes {
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M2300/0091 - in the form of mixtures
H01M10/0561 - the electrolyte being constituted of inorganic materials only
H01M2300/0071 - Oxides

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DOE Contract Number:: AC02-05CH11231

Resource Type:: Patent

Resource Relation:: Patent File Date: 03/14/2014

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Angell, C. Austen, Klein, Iolanda Santana, and Tucker, Telpriore Greg. Alkali ion conducting plastic crystals.  United States: N. p., 2019. 
        Web.

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                    Angell, C. Austen, Klein, Iolanda Santana, & Tucker, Telpriore Greg. Alkali ion conducting plastic crystals.  United States.

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                    Angell, C. Austen, Klein, Iolanda Santana, and Tucker, Telpriore Greg. Tue .  
        "Alkali ion conducting plastic crystals".  United States.  https://www.osti.gov/servlets/purl/1600335.

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@article{osti_1600335,

  title        = {Alkali ion conducting plastic crystals},

  author       = {Angell, C. Austen and Klein, Iolanda Santana and Tucker, Telpriore Greg},

  abstractNote = {Inorganic plastic crystal electrolytes, also referred to herein as inorganic plastic crystal conductors or single ion conductors including [ABx-yCy]y−[M]y+, where A is a tetravalent to hexavalent atom; B is a monovalent ligand; C is an oxyanion; M is an alkali metal; x is 4 when A is tetravalent, x is 5 when A is pentavalent, and x is 6 when A is hexavalent; y is an integer from 1 to x−1 inclusive. [ABx-yCy]y−[M]y+ is rotationally disordered and ionically conductive.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2019},

  month        = {11}

}

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Title: Alkali ion conducting plastic crystals

Abstract

Citation Formats

Substituted lithium orthosilicates and solid electrolytes therefrom patent, August 1977

Method of synthesizing electrochemically active materials from a slurry of precursors patent, July 2005

Non-aqueous electrolyte secondary battery and method for producing active material substance used for anode thereof patent-application, March 2004

Non-aqueous electrolyte secondary cell and, deterioration-preventing agent for non-aqueous electrolyte secondary cell and additive for non-aqueous electrolyte secondary cell for use therein patent, October 2005

Lithium ion conducting ionic electrolytes patent, January 1996

Method of producing silicon tetrachloride-based and organically modified aerogels patent, November 2002

Composite particle for electrode and method for producing same, electrode and method for producing same, and electrochemical device and method for producing same patent-application, January 2007

Electrochemical cell comprising ionically conductive membrane and porous multiphase electrode patent, December 2012

Thin film battery synthesis by directed vapor deposition patent, July 2014

Lithium-containing silicon/phosphates, method of preparation, and uses thereof including as electrodes for a battery patent, October 2000

Substituted lithium orthosilicates and solid electrolytes therefrom
patent, August 1977

Method of synthesizing electrochemically active materials from a slurry of precursors
patent, July 2005

Non-aqueous electrolyte secondary battery and method for producing active material substance used for anode thereof
patent-application, March 2004

Non-aqueous electrolyte secondary cell and, deterioration-preventing agent for non-aqueous electrolyte secondary cell and additive for non-aqueous electrolyte secondary cell for use therein
patent, October 2005

Lithium ion conducting ionic electrolytes
patent, January 1996

Method of producing silicon tetrachloride-based and organically modified aerogels
patent, November 2002

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patent-application, January 2007

Electrochemical cell comprising ionically conductive membrane and porous multiphase electrode
patent, December 2012

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patent, July 2014

Lithium-containing silicon/phosphates, method of preparation, and uses thereof including as electrodes for a battery
patent, October 2000