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Title: Macrocyclic ligands and their complexes for bifunctional molecular catalysis

Abstract

Disclosed herein are embodiments of chiral and achiral macrocyclic polydentate ligands and methods of preparing the same. Disclosed herein are also embodiments of metal coordination complexes derived from these macrocyclic polydentate ligands and methods of preparing the same. The metal coordination complexes described herein, can be used for a variety of catalytic reactions, including hydrogenation and transfer hydrogenation of unsaturated organic compounds, dehydrogenation of alcohols and boranes, an asymmetric Michael-type addition reaction, or an aerobic oxidative kinetic resolution of an organic compound, dehydrogenative couplings and other catalytic transformations.

Inventors:
; ; ; ;
Issue Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1600319
Patent Number(s):
10487100
Application Number:
15/944,503
Assignee:
Triad National Security, LLC (Los Alamos, NM)
Patent Classifications (CPCs):
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
DOE Contract Number:  
AC52-06NA25396
Resource Type:
Patent
Resource Relation:
Patent File Date: 04/03/2018
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Dub, Pavel, Gordon, John C., Schmidt, Jurgen G., Minko, Yury, and Williams, Robert F. Macrocyclic ligands and their complexes for bifunctional molecular catalysis. United States: N. p., 2019. Web.
Dub, Pavel, Gordon, John C., Schmidt, Jurgen G., Minko, Yury, & Williams, Robert F. Macrocyclic ligands and their complexes for bifunctional molecular catalysis. United States.
Dub, Pavel, Gordon, John C., Schmidt, Jurgen G., Minko, Yury, and Williams, Robert F. Tue . "Macrocyclic ligands and their complexes for bifunctional molecular catalysis". United States. https://www.osti.gov/servlets/purl/1600319.
@article{osti_1600319,
title = {Macrocyclic ligands and their complexes for bifunctional molecular catalysis},
author = {Dub, Pavel and Gordon, John C. and Schmidt, Jurgen G. and Minko, Yury and Williams, Robert F.},
abstractNote = {Disclosed herein are embodiments of chiral and achiral macrocyclic polydentate ligands and methods of preparing the same. Disclosed herein are also embodiments of metal coordination complexes derived from these macrocyclic polydentate ligands and methods of preparing the same. The metal coordination complexes described herein, can be used for a variety of catalytic reactions, including hydrogenation and transfer hydrogenation of unsaturated organic compounds, dehydrogenation of alcohols and boranes, an asymmetric Michael-type addition reaction, or an aerobic oxidative kinetic resolution of an organic compound, dehydrogenative couplings and other catalytic transformations.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {11}
}

Patent:

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